In-Situ 27Al NMR Spectroscopy of Aluminate in Sodium Hydroxide Solutions Above and Below Saturation with Respect to Gibbsite

Journal Article · Mon Oct 01 00:00:00 EDT 2018 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.8b00617· OSTI ID:1558646

Graham, Trenton R. ^[1]; Dembowski, Mateusz  ^[2]; Martinez Baez, Ernesto ^[1]; Zhang, Xin ^[2]; Jaegers, Nicholas R. ^[2]; Hu, Jian Z.  ^[2]; Gruszkiewicz, Miroslaw S. ^[3]; Wang, Hsiu-Wen ^[4]; Stack, Andrew G. ^[3]; Bowden, Mark E. ^[2]; Delegard, Calvin H.  ^[5]; Schenter, Gregory K.  ^[2]; Clark, Aurora E. ^[1]; Clark, Sue B. ^[2]; Felmy, Andrew R. ^[1]; Rosso, Kevin M.  ^[2]; Pearce, Carolyn I. ^[2]

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1. WASHINGTON STATE UNIV
2. BATTELLE (PACIFIC NW LAB)
3. Oak Ridge National Laboratory
4. OAK RIDGE NATIONAL LAB
5. TRADEWIND SERVICES LLC

Aluminum hydroxide (Al(OH)3, gibbsite) dissolution and precipitation processes in alkaline environments play a commanding role in aluminum refining and nuclear waste processing, yet mechanistic aspects underlying sluggish kinetics during crystallization have remained obscured due to a lack of in situ probes capable of isolating incipient ion pairs. At a molecular level Al is cycling between tetrahedral (Td) coordination in solution to octahedral (Oh) in the solid. We explored dissolution of Al(OH)3 that prepared variably saturated aluminate (Al(OH)4 -)-containing solutions under alkaline conditions (pH > 13) with in-situ 27Al magic angle spinning (MAS)-nuclear magnetic resonance (NMR) spectroscopy, and interrogated the results with ab initio molecular dynamics (AIMD) simulations complemented with chemical shift calculations based on high level theory. The collective results highlight the overall stability of the solvation structure for Td Al in the Al(OH)4 - oxyanion as a function of both temperature and Al concentration. The observed chemical shift did not change significantly even when the Al concentration in solution became supersaturated upon cooling and limited precipitation of the octahedral Al(OH)3 phase occurred. However, subtle changes in Al(OH)4 - speciation correlated with the dissolution/precipitation reaction were found. AIMDinformed chemical shift calculations indicate that measurable perturbations should begin when the Al(OH)4 -?Na+ distance is less than 6 Å, increasing dramatically at shorter distances, coinciding with appreciable changes to the electrostatic interaction and reorganization of the Al(OH)4 - solvation shell. The integrated findings thus suggest that, at conditions incipient to and concurrent with gibbsite crystallization, nominally expected contact ion pairs are insignificant and instead medium-range (4 – 6 Å) solvent-separated Al(OH)4 -?Na+ pairs predominate. Moreover, the fact that these medium-range interactions bear directly on resulting gibbsite characteristics was demonstrated by detailed microscopic and X-ray diffraction analysis, and by progressive changes in the FWHM of the Oh resonance, as measured by in-situ NMR. Sluggish gibbsite crystallization may arise from the activation energy associated with disrupting this robust medium-range ion pair interaction.

• Research Organization: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Oak Ridge Leadership Computing Facility (OLCF); Energy Frontier Research Centers (EFRC) (United States). Interfacial Dynamics in Radioactive Environments and Materials (IDREAM); Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
• Sponsoring Organization: USDOE Office of Science (SC)
• DOE Contract Number: AC05-76RL01830
• OSTI ID: 1558646
• Report Number(s): PNNL-SA-132754
• Journal Information: Inorganic Chemistry, Vol. 57, Issue 19
• Country of Publication: United States
• Language: English