Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Ignition thresholds of aluminized HMX-based polymer-bonded explosives

Journal Article · · AIP Advances
DOI:https://doi.org/10.1063/1.5052632· OSTI ID:1558557
 [1];  [2];  [3];  [1]
  1. Georgia Inst. of Technology, Atlanta, GA (United States)
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  3. Air Force Research Lab, Eglin AFB, FL (United States)

Here, the ignition of aluminized HMX-based polymer-bonded explosives (PBXs) under shock loading is studied via mesoscale simulations. The conditions analyzed concern loading pulses of 20 nanoseconds to 0.8 microseconds in duration and impact piston velocities on the order of 400-1000 m/s or loading stresses on the order of 3-14 GPa. The sets of samples studied have stochastically similar microstructures consisting of a bimodal distribution of HMX grains, an Estane binder, and aluminum particles 50-100 µm in diameter. The computational model accounts for constituent elasto-viscoplasticity, viscoelasticity, bulk compressibility, fracture, interfacial debonding, internal contact, bulk and frictional heating, and heat conduction. The analysis focuses on the development of hotspots under different material settings and loading conditions. In particular, the ignition thresholds in the forms of the James relation and the Walker-Wasley relation and the corresponding ignition probability are calculated and expressed as functions of the aluminum volume fraction for the PBXs analyzed. Lastly, it is found that the addition of aluminum raises the ignition thresholds, causing the materials to be less sensitive. Dissipation and heating mechanism changes responsible for this trend are delineated.

Research Organization:
Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC05-00OR22725; NA0003864
OSTI ID:
1558557
Journal Information:
AIP Advances, Journal Name: AIP Advances Journal Issue: 4 Vol. 9; ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

References (26)

An Extension to the Critical Energy Criterion used to predict shock initiation thresholds journal February 1996
Investigating the Mechanical Properties of RDX Crystals Using Nano-Indentation journal March 2012
Computational analysis of temperature rises in microstructures of HMX-Estane PBXs journal October 2012
Explosive characteristics of aluminized HMX-based nanocomposites journal March 2008
Cast aluminized explosives (review) journal July 2008
Ignition Desensitization of PBX via Aluminization journal October 2014
Effective elastic modulus and atomic stress concentration of single crystal nano-plate with void journal July 2007
The effect of wax coating, aluminum and ammonium perchlorate on impact sensitivity of HMX journal December 2017
Prediction of shock initiation thresholds and ignition probability of polymer-bonded explosives using mesoscale simulations journal May 2018
A constitutive model for the non-shock ignition and mechanical response of high explosives journal December 1998
Modeling heterogeneous energetic materials at the mesoscale journal February 2002
Critical Conditions for Impact- and Shock-Induced Hot Spots in Solid Explosives journal January 1996
Mechanical Sensitivity and Detonation Parameters of Aluminized Explosives journal July 2004
A molecular dynamics simulation study of elastic properties of HMX journal October 2003
Energy localization in HMX-Estane polymer-bonded explosives during impact loading journal March 2012
Ignition criterion for heterogeneous energetic materials based on hotspot size-temperature threshold journal February 2013
Prediction of probabilistic ignition behavior of polymer-bonded explosives from microstructural stochasticity journal May 2013
Computational prediction of probabilistic ignition threshold of pressed granular octahydro-1,3,5,7-tetranitro-1,2,3,5-tetrazocine (HMX) under shock loading journal September 2016
Quantification of probabilistic ignition thresholds of polymer-bonded explosives with microstructure defects journal October 2018
A Lagrangian framework for analyzing microstructural level response of polymer-bonded explosives journal June 2011
Eulerian finite-element simulations of experimentally acquired HMX microstructures journal January 1999
Modeling pore collapse and chemical reactions in shock-loaded HMX crystals journal May 2014
Microstructural effects on the ignition behavior of HMX journal May 2014
Microstructural level response of HMX–Estane polymer-bonded explosive under effects of transient stress waves journal June 2012
Determination of Fracture Toughness for Metal/Polymer Interfaces journal December 1999
Influence of Aluminium on Performance of HTPB-based Aluminised PBXs journal October 2004

Cited By (1)

Prediction of Probabilistic Detonation Threshold via Millimeter‐Scale Microstructure‐Explicit and Void‐Explicit Simulations journal November 2019

Similar Records

Energy dissipation in polymer-bonded explosives with various levels of constituent plasticity and internal friction
Journal Article · Tue Dec 11 23:00:00 EST 2018 · Computational Materials Science · OSTI ID:1558558

Computational study of ignition behavior and hotspot dynamics of a potential class of aluminized explosives
Journal Article · Wed Oct 24 00:00:00 EDT 2018 · Modelling and Simulation in Materials Science and Engineering · OSTI ID:1560512

Prediction of shock initiation thresholds and ignition probability of polymer-bonded explosives using mesoscale simulations
Journal Article · Tue Feb 20 23:00:00 EST 2018 · Journal of the Mechanics and Physics of Solids · OSTI ID:1474710