Using Mixed Salt Electrolytes to Stabilize Silicon Anodes for Lithium-Ion Batteries via in Situ Formation of Li–M–Si Ternaries (M = Mg, Zn, Al, Ca)

Han, Binghong; Liao, Chen; Dogan, Fulya; Trask, Stephen E.; Lapidus, Saul H.; Vaughey, John T.; Key, Baris

doi:10.1021/acsami.9b07270

Using Mixed Salt Electrolytes to Stabilize Silicon Anodes for Lithium-Ion Batteries via in Situ Formation of Li–M–Si Ternaries (M = Mg, Zn, Al, Ca)

Journal Article · Thu Jul 18 04:00:00 EDT 2019 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.9b07270· OSTI ID:1558122

Han, Binghong; Liao, Chen; ; ; Lapidus, Saul H.; ;

Not Available

View Journal Article

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1558122

Alternate ID(s):: OSTI ID: 1558232

Journal Information:: ACS Applied Materials and Interfaces, Journal Name: ACS Applied Materials and Interfaces Journal Issue: 33 Vol. 11; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

References (44)

Insertion Electrode Materials for Rechargeable Lithium Batteries Winter, Martin; Besenhard, Jürgen O.; Spahr, Michael E. Advanced Materials, Vol. 10, Issue 10 https://doi.org/10.1002/(SICI)1521-4095(199807)10:10<725::AID-ADMA725>3.0.CO;2-Z	journal	July 1998
Silicon-Based Nanomaterials for Lithium-Ion Batteries: A Review Su, Xin; Wu, Qingliu; Li, Juchuan Advanced Energy Materials, Vol. 4, Issue 1 https://doi.org/10.1002/aenm.201300882	journal	October 2013
A Highly Cross-Linked Polymeric Binder for High-Performance Silicon Negative Electrodes in Lithium Ion Batteries Koo, Bonjae; Kim, Hyunjung; Cho, Younghyun Angewandte Chemie International Edition, Vol. 51, Issue 35 https://doi.org/10.1002/anie.201201568	journal	July 2012
Li12Si7, eine Verbindung mit trigonal-planaren Si4-Clustern und isometrischen Si5-Ringen Nesper, Reinhard; von Schnering, Hans Georg; Curda, Jan Chemische Berichte, Vol. 119, Issue 12 https://doi.org/10.1002/cber.19861191207	journal	December 1986
Substitution of Lithium for Magnesium, Zinc, and Aluminum in Li ₁₅ Si ₄ : Crystal Structures, Thermodynamic Properties, as well as ⁶ Li and ⁷ Li NMR Spectroscopy of Li ₁₅ Si ₄ and Li _{15− x} M _x Si ₄ (M=Mg, Zn, and Al) Baran, Volodymyr; van Wüllen, Leo; Fässler, Thomas F. Chemistry - A European Journal, Vol. 22, Issue 19 https://doi.org/10.1002/chem.201505145	journal	March 2016
NMR investigations on the lithiation and delithiation of nanosilicon-based anodes for Li-ion batteries Trill, Jan-Henning; Tao, Chuangqi; Winter, Martin Journal of Solid State Electrochemistry, Vol. 15, Issue 2 https://doi.org/10.1007/s10008-010-1260-0	journal	December 2010
Si-Based Anode Materials for Li-Ion Batteries: A Mini Review Ma, Delong; Cao, Zhanyi; Hu, Anming Nano-Micro Letters, Vol. 6, Issue 4 https://doi.org/10.1007/s40820-014-0008-2	journal	September 2014
Li8MgSi6, a novel Zintl compound containing quasi-aromatic Si5 rings Nesper, R.; Curda, J.; Von Schnering, H. G. Journal of Solid State Chemistry, Vol. 62, Issue 2 https://doi.org/10.1016/0022-4596(86)90232-X	journal	April 1986
Li21Si5, a Zintl phase as well as a Hume-Rothery phase Nesper, Reinhard; von Schnering, Hans Georg Journal of Solid State Chemistry, Vol. 70, Issue 1 https://doi.org/10.1016/0022-4596(87)90176-9	journal	September 1987
Structure and chemical bonding in zintl-phases containing lithium Nesper, Reinhard Progress in Solid State Chemistry, Vol. 20, Issue 1 https://doi.org/10.1016/0079-6786(90)90006-2	journal	January 1990
Electrochemical lithiation of tin and tin-based intermetallics and composites Winter, Martin; Besenhard, Jürgen O. Electrochimica Acta, Vol. 45, Issue 1-2, p. 31-50 https://doi.org/10.1016/S0013-4686(99)00191-7	journal	September 1999
Structural, electronic, and hydriding properties of Li2MgSi Herbst, J. F.; Meyer, M. S. Journal of Alloys and Compounds, Vol. 492, Issue 1-2 https://doi.org/10.1016/j.jallcom.2009.12.032	journal	March 2010
Nano- and bulk-silicon-based insertion anodes for lithium-ion secondary cells Kasavajjula, Uday; Wang, Chunsheng; Appleby, A. John Journal of Power Sources, Vol. 163, Issue 2, p. 1003-1039 https://doi.org/10.1016/j.jpowsour.2006.09.084	journal	January 2007
Effect of vinylene carbonate (VC) as electrolyte additive on electrochemical performance of Si film anode for lithium ion batteries Chen, Libao; Wang, Ke; Xie, Xiaohua Journal of Power Sources, Vol. 174, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.149	journal	December 2007
Surface layer formed on silicon thin-film electrode in lithium bis(oxalato) borate-based electrolyte Choi, Nam-Soon; Yew, Kyoung Han; Kim, Ho Journal of Power Sources, Vol. 172, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.07.058	journal	October 2007
Decomposition of ethylene carbonate on electrodeposited metal thin film anode Bridel, Jean-Sebastien; Grugeon, Sylvie; Laruelle, Stephane Journal of Power Sources, Vol. 195, Issue 7 https://doi.org/10.1016/j.jpowsour.2009.10.038	journal	April 2010
Effect of succinic anhydride as an electrolyte additive on electrochemical characteristics of silicon thin-film electrode Han, Gi-Beom; Ryou, Myung-Hyun; Cho, Kuk Young Journal of Power Sources, Vol. 195, Issue 11 https://doi.org/10.1016/j.jpowsour.2009.11.142	journal	June 2010
Effect of polyimide binder on electrochemical characteristics of surface-modified silicon anode for lithium ion batteries Kim, Jung Sub; Choi, Wonchang; Cho, Kyu Young Journal of Power Sources, Vol. 244 https://doi.org/10.1016/j.jpowsour.2013.02.049	journal	December 2013
Li-ion battery materials: present and future Nitta, Naoki; Wu, Feixiang; Lee, Jung Tae Materials Today, Vol. 18, Issue 5 https://doi.org/10.1016/j.mattod.2014.10.040	journal	June 2015
Designing nanostructured Si anodes for high energy lithium ion batteries Wu, Hui; Cui, Yi Nano Today, Vol. 7, Issue 5 https://doi.org/10.1016/j.nantod.2012.08.004	journal	October 2012
Voltage Dependent Solid Electrolyte Interphase Formation in Silicon Electrodes: Monitoring the Formation of Organic Decomposition Products Michan, Alison L.; Leskes, Michal; Grey, Clare P. Chemistry of Materials, Vol. 28, Issue 1 https://doi.org/10.1021/acs.chemmater.5b04408	journal	December 2015
ZnAl _x Co _{2– x} O ₄ Spinels as Cathode Materials for Non-Aqueous Zn Batteries with an Open Circuit Voltage of ≤2 V Pan, Chengsi; Nuzzo, Ralph G.; Gewirth, Andrew A. Chemistry of Materials, Vol. 29, Issue 21 https://doi.org/10.1021/acs.chemmater.7b03340	journal	November 2017
Silicon Nanoparticles: Stability in Aqueous Slurries and the Optimization of the Oxide Layer Thickness for Optimal Electrochemical Performance Zhang, Linghong; Liu, Yuzi; Key, Baris ACS Applied Materials & Interfaces, Vol. 9, Issue 38 https://doi.org/10.1021/acsami.7b09149	journal	September 2017
Fluoroethylene Carbonate as an Important Component for the Formation of an Effective Solid Electrolyte Interphase on Anodes and Cathodes for Advanced Li-Ion Batteries Markevich, Elena; Salitra, Gregory; Aurbach, Doron ACS Energy Letters, Vol. 2, Issue 6 https://doi.org/10.1021/acsenergylett.7b00163	journal	May 2017
Toward Efficient Binders for Li-Ion Battery Si-Based Anodes: Polyacrylic Acid Magasinski, Alexandre; Zdyrko, Bogdan; Kovalenko, Igor ACS Applied Materials & Interfaces, Vol. 2, Issue 11 https://doi.org/10.1021/am100871y	journal	October 2010
Stabilizing the Phase Li ₁₅ Si ₄ through Lithium–Aluminum Substitution in Li _{15– x} Al _x Si ₄ (0.4 < x < 0.8)—Single Crystal X-ray Structure Determination of Li ₁₅ Si ₄ and Li _14.37 Al _0.63 Si ₄ Zeilinger, Michael; Baran, Volodymyr; van Wüllen, Leo Chemistry of Materials, Vol. 25, Issue 20 https://doi.org/10.1021/cm402721n	journal	October 2013
Alloy Negative Electrodes for Li-Ion Batteries Obrovac, M. N.; Chevrier, V. L. Chemical Reviews, Vol. 114, Issue 23 https://doi.org/10.1021/cr500207g	journal	October 2014
Pair Distribution Function Analysis and Solid State NMR Studies of Silicon Electrodes for Lithium Ion Batteries: Understanding the (De)lithiation Mechanisms Key, Baris; Morcrette, Mathieu; Tarascon, Jean-Marie Journal of the American Chemical Society, Vol. 133, Issue 3 https://doi.org/10.1021/ja108085d	journal	January 2011
Real-Time NMR Investigations of Structural Changes in Silicon Electrodes for Lithium-Ion Batteries Key, Baris; Bhattacharyya, Rangeet; Morcrette, Mathieu Journal of the American Chemical Society, Vol. 131, Issue 26 https://doi.org/10.1021/ja8086278	journal	July 2009
Effect of Fluoroethylene Carbonate (FEC) on the Performance and Surface Chemistry of Si-Nanowire Li-Ion Battery Anodes Etacheri, Vinodkumar; Haik, Ortal; Goffer, Yossi Langmuir, Vol. 28, Issue 1 https://doi.org/10.1021/la203712s	journal	December 2011
An ultrafast rechargeable aluminium-ion battery Lin, Meng-Chang; Gong, Ming; Lu, Bingan Nature, Vol. 520, Issue 7547 https://doi.org/10.1038/nature14340	journal	April 2015
Pathways for practical high-energy long-cycling lithium metal batteries Liu, Jun; Bao, Zhenan; Cui, Yi Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0338-x	journal	February 2019
The Insertion Mechanism of Lithium into Mg[sub 2]Si Anode Material for Li-Ion Batteries Kim, Hansu Journal of The Electrochemical Society, Vol. 146, Issue 12 https://doi.org/10.1149/1.1392650	journal	January 1999
Carbon-Coated Si as a Lithium-Ion Battery Anode Material Yoshio, Masaki; Wang, Hongyu; Fukuda, Kenji Journal of The Electrochemical Society, Vol. 149, Issue 12 https://doi.org/10.1149/1.1518988	journal	January 2002
High Capacity, Reversible Silicon Thin-Film Anodes for Lithium-Ion Batteries Maranchi, J. P.; Hepp, A. F.; Kumta, P. N. Electrochemical and Solid-State Letters, Vol. 6, Issue 9 https://doi.org/10.1149/1.1596918	journal	January 2003
In Situ XRD and Electrochemical Study of the Reaction of Lithium with Amorphous Silicon Hatchard, T. D.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 151, Issue 6 https://doi.org/10.1149/1.1739217	journal	January 2004
Silicon/Graphite Composite Electrodes for High-Capacity Anodes: Influence of Binder Chemistry on Cycling Stability Hochgatterer, N. S.; Schweiger, M. R.; Koller, S. Electrochemical and Solid-State Letters, Vol. 11, Issue 5 https://doi.org/10.1149/1.2888173	journal	January 2008
Al–Si Thin-Film Negative Electrodes for Li-Ion Batteries Fleischauer, M. D.; Obrovac, M. N.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 155, Issue 11 https://doi.org/10.1149/1.2977971	journal	January 2008
Formation of MgO during Chemical Magnesiation of Mg-Ion Battery Materials Wang, H.; Senguttuvan, P.; Proffit, D. L. ECS Electrochemistry Letters, Vol. 4, Issue 8 https://doi.org/10.1149/2.0051508eel	journal	January 2015
A Guide to Ethylene Carbonate-Free Electrolyte Making for Li-Ion Cells Ma, Lin; Glazier, S. L.; Petibon, R. Journal of The Electrochemical Society, Vol. 164, Issue 1 https://doi.org/10.1149/2.0191701jes	journal	November 2016
Performance Enhancing Electrolyte Additives for Lithium Ion Batteries with Silicon Anodes Dalavi, Swapnil; Guduru, Pradeep; Lucht, Brett L. Journal of The Electrochemical Society, Vol. 159, Issue 5 https://doi.org/10.1149/2.076205jes	journal	January 2012
Solid State NMR Studies of Li ₂ MnO ₃ and Li-Rich Cathode Materials: Proton Insertion, Local Structure, and Voltage Fade Dogan, Fulya; Croy, Jason R.; Balasubramanian, Mahalingam Journal of The Electrochemical Society, Vol. 162, Issue 1 https://doi.org/10.1149/2.1041501jes	journal	November 2014
Assessment of Li-Inventory in Cycled Si-Graphite Anodes Using LiFePO ₄ as a Diagnostic Cathode Dose, Wesley M.; Maroni, Victor A.; Piernas-Muñoz, Maria Jose Journal of The Electrochemical Society, Vol. 165, Issue 10 https://doi.org/10.1149/2.1271810jes	journal	January 2018
Effect of porosity on electrochemical and mechanical properties of composite Li-ion anodes Antartis, Dimitrios; Dillon, Shen; Chasiotis, Ioannis Journal of Composite Materials, Vol. 49, Issue 15 https://doi.org/10.1177/0021998314568653	journal	January 2015

Similar Records

Investigating Ternary Li–Mg–Si Zintl Phase Formation and Evolution for Si Anodes in Li-Ion Batteries with Mg(TFSI)₂ Electrolyte Additive

Journal Article · Thu Jun 17 00:00:00 EDT 2021 · Chemistry of Materials · OSTI ID:1831743

Advanced electrolyte/additive for lithium-ion batteries with silicon anode

Journal Article · Mon Aug 01 00:00:00 EDT 2016 · Current Opinion in Chemical Engineering · OSTI ID:1398023

Related Subjects

25 ENERGY STORAGE

Using Mixed Salt Electrolytes to Stabilize Silicon Anodes for Lithium-Ion Batteries via in Situ Formation of Li–M–Si Ternaries (M = Mg, Zn, Al, Ca)

Citation Formats

References (44)

Similar Records

Related Subjects