High Voltage Operation of Ni-Rich NMC Cathodes Enabled by Stable Electrode/Electrolyte Interphases

Zhao, Wengao; Zheng, Jianming; Zou, Lianfeng; Jia, Haiping; Liu, Bin; Engelhard, Mark H.; Wang, Chongmin; Xu, Wu; Yang, Yong; Zhang, Jiguang

doi:10.1002/aenm.201800297

Title: High Voltage Operation of Ni-Rich NMC Cathodes Enabled by Stable Electrode/Electrolyte Interphases

Journal Article · Thu Jul 05 00:00:00 EDT 2018 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201800297· OSTI ID:1557726

Zhao, Wengao ^[1];

^[1]; Zou, Lianfeng ^[1]; Jia, Haiping ^[1];

^[1];

^[1]; Yang, Yong ^[2];

^[1]

BATTELLE (PACIFIC NW LAB)
Xiamen University

Lithium (Li) metal battery (LMB) is one of the most promising candidates for the next generation energy storage systems. However, it is still a significant challenge to operate LMBs with high voltage cathode under high rate conditions. In this work, a LMB using nickel-rich layered cathode of LiNi0.76Mn0.14Co0.10O2 (NMC76) and an optimized electrolyte (0.6 M LiTFSI + 0.4 M LiBOB + 0.05 M LiPF6 dissolved in EC: EMC (4:6 by weight)) demonstrate excellent stability under a high charge cutoff voltage of 4.5 V. Remarkably, these Li||NMC76 cells can deliver a high discharge capacity of > 220 mAh g-1 (846 Wh kg-1) and retain more than 80% capacity after 1000 cycles under a high charge/discharge current rates of 2C/2C (1C = 200 mA g-1). These excellent electrochemical performances can be attributed to the highly enhanced structural/interfacial stability of both Ni-rich NMC76 cathode materials and Li metal anode using the optimized electrolyte.

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Research Organization:: Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: AC05-76RL01830

OSTI ID:: 1557726

Report Number(s):: PNNL-SA-131810

Journal Information:: Advanced Energy Materials, Vol. 8, Issue 19

Country of Publication:: United States

Language:: English

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