One-Nanometer-Thick Pt3Ni Bimetallic Alloy Nanowires Advanced Oxygen Reduction Reaction: Integrating Multiple Advantages into One Catalyst

Gong, Mingxing; Deng, Zhiping; Xiao, Dongdong; Han, Lili; Zhao, Tonghui; Lu, Yun; Shen, Tao; Liu, Xupo; Lin, Ruoqian; Huang, Ting; Zhou, Guangwen; Xin, Huolin; Wang, Deli

doi:10.1021/acscatal.9b00603

Title: One-Nanometer-Thick Pt₃Ni Bimetallic Alloy Nanowires Advanced Oxygen Reduction Reaction: Integrating Multiple Advantages into One Catalyst

Journal Article · Fri Apr 05 00:00:00 EDT 2019 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.9b00603· OSTI ID:1557715

Gong, Mingxing ^[1]; Deng, Zhiping ^[2]; Xiao, Dongdong ^[3]; Han, Lili ^[4]; Zhao, Tonghui ^[2]; Lu, Yun ^[2]; Shen, Tao ^[2]; Liu, Xupo ^[2];

^[4]; Huang, Ting ^[4];

^[3]; Xin, Huolin ^[5];

^[2]

Huazhong Univ. of Science and Technology, Wuhan (People's Republic of China); Brookhaven National Lab. (BNL), Upton, NY (United States)
Huazhong Univ. of Science and Technology, Wuhan (People's Republic of China)
State Univ. of New York, Binghamton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States); Univ. of California, Irvine, CA (United States)

Developing highly active as well as durable oxygen reduction reaction (ORR) electrocatalysts are still imperative for clean and efficient energy conversion device, such as fuel cells and metal-air battery. For this purpose and maximize the utilization of noble Pt, we present here a facile, yet scalable strategy for the high-precise synthesis of 1-nm-thick Pt₃Ni bimetallic alloy nanowires (Pt₃Ni BANWs). The seed-mediated growth mechanism of Pt₃Ni BANWs was identified subsequently. As expected, the Pt₃Ni BANWs delivered enhanced mass activity (0.546 A mgPt^–1, exceeding the 2020 target of DOE) in comparison to Pt nanowires assembly (Pt NWA, 0.098 A mgPt^–1) and Pt/C (Pt, 0.135 A mgPt^–1), because of the rational integration of multiple compositional and structural advantages. Moreover, the Pt₃Ni BANWs displayed enhanced durability (37% MA retention) than Pt NWA and Pt after 50 000 potential cycles. All these results indicate that the ultrathin Pt₃Ni BANWs are potential candidates for catalyzing ORR with acceptable activity and durability. In conclusion, the present work could not only provide a facile strategy but also a general guidance for the design of superb performance Pt-based nanowire catalysts for ORR.

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Research Organization:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: SC0012704

OSTI ID:: 1557715

Report Number(s):: BNL-211955-2019-JAAM

Journal Information:: ACS Catalysis, Vol. 9, Issue 5; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 99 works

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Title: One-Nanometer-Thick Pt3Ni Bimetallic Alloy Nanowires Advanced Oxygen Reduction Reaction: Integrating Multiple Advantages into One Catalyst

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Title: One-Nanometer-Thick Pt₃Ni Bimetallic Alloy Nanowires Advanced Oxygen Reduction Reaction: Integrating Multiple Advantages into One Catalyst