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Molecular structure of W(PMe3)3H6 in the solid state and in solution

Journal Article · · Inorganica Chimica Acta
Not Available
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
FG02-93ER14339
OSTI ID:
1556573
Journal Information:
Inorganica Chimica Acta, Journal Name: Inorganica Chimica Acta Journal Issue: C Vol. 422; ISSN 0020-1693
Publisher:
ElsevierCopyright Statement
Country of Publication:
Switzerland
Language:
English

References (101)

Experimental Electron Densities and Chemical Bonding journal January 1977
Transition Metal Complexation ofσ Bonds journal June 1993
The σ-CAM Mechanism: σ Complexes as the Basis of σ-Bond Metathesis at Late-Transition-Metal Centers journal April 2007
Hydride Fluxionality in Transiton Metal Complexes: An Approach to the Understanding of Mechanistic Features and Structural Diversities journal October 1996
Preparation and Reactions of Molybdenum and Tungsten Hydride Complexes Containing the Tetraphosphane Ligand meso-o-C6H4(PPhCH2CH2PPh2)2 journal November 2010
Transition metal dihydrogen complexes: isotope effects on reactivity and structure journal January 2007
Metal-catalysed hydrogen isotope exchange labelling: a brief overview journal September 2010
Concerning the chemical shifts of the ring protons of toluene as determined by1H NMR spectroscopy of deuterated material journal November 1979
Recent Advances in Alkene Hydroformylation book January 2007
X-ray structural study of tetrahydro-tetrakis (diphenylethylphosphino) tungsten journal January 1980
Crystal and molecular structure of tetrahydridotetrakis (Tri-iso-propylphosphito) tungsten journal January 1980
Photochemical interaction of phosphine hydride complexes of molybdenum and tungsten with benzene and cyclohexane
  • Pivovarov, A. P.; Ioffe, L. M.; Gak, Yu. V.
  • Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 33, Issue 4 https://doi.org/10.1007/BF00947817
journal April 1984
Intramolecular hydrogen transfer from the alkyl substituent of a phosphine ligand to a metal atom upon the irradiation of tungsten phosphine hydride complexes
  • Pivovarov, A. P.; Ioffe, L. M.; Gak, Yu. V.
  • Bulletin of the Academy of Sciences of the USSR Division of Chemical Science, Vol. 36, Issue 5 https://doi.org/10.1007/BF00956338
journal May 1987
Crystallographic studies of transition metal hydride complexes book October 2007
Transition-metal polyhydride complexes journal July 1985
Isotope effects in nuclear shielding journal January 1988
Structures of transition metal hydrides determined by neutron diffraction journal June 1997
Tungsten and molybdenum phosphine hexahydrides: The first examples of nine coordination among mononuclear molybdenum complexes journal November 1982
Metal–dihydrogen and σ-bond coordination: the consummate extension of the Dewar–Chatt–Duncanson model for metal–olefin π bonding journal October 2001
Dehydrocoupling, Redistributive Coupling, and Addition of Main Group 4 Hydrides book January 2004
The NMR Chemical Shift: Insight into Structure and Environment book January 1994
Isotope Effects on Nuclear Shielding book January 1984
Application of NMR Spectroscopy in Isotope Effects Studies book January 2009
Poly(pyrazolyl)hydroborato and poly(pyrazolyl)methane aluminium alkyl derivatives journal January 1990
Dihydrogen, dihydride and in between: NMR and structural properties of iron group complexes journal November 2008
Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view journal July 2011
Hydrogen exchange of rhenium(VII) heptahydridobis(triphenylphosphine) with water, aniline, methanol, and itself journal January 2009
Hydrogen activation on organometallic complexes and H2 production, utilization, and storage for future energy journal August 2009
Crystallographic Investigations on Polyhydride Metal Complexes book June 1978
Coordination chemistry of dihydrogen journal May 1993
Fundamentals of H 2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H 2 Production and Storage journal October 2007
Quantum Mechanical Exchange Coupling in Polyhydride and Dihydrogen Complexes journal September 1998
Transition Metal Polyhydrides:  From Qualitative Ideas to Reliable Computational Studies journal February 2000
Carbon-13 and phosphorus-31 CP/MAS NMR studies of the polytopal ligand rearrangement process of tungsten tris(trimethylphosphine) hexahydride in the solid state journal April 1991
Tungsten(VI) hexahydride complexes supported by chelating triphosphine ligands: protonation to give .eta.2-dihydrogen complexes and catalytic dehydrogenation of cyclooctane to cyclooctene journal April 1993
Classical, nonclassical, and mixed-metal osmium(II) polyhydrides stabilized by the tetraphosphine P(CH2CH2PPh2)3. Hydrogen/deuterium isotope exchange reactions promoted by a strongly bound dihydrogen ligand journal May 1993
Improved synthesis of some molybdenum and tungsten tetrahydrides journal March 1982
X-ray and neutron diffraction single-crystal studies of tris(phenyldiisopropylphosphine)tungsten hexahydride [WH6(PPh-i-Pr2)3] journal November 1984
Strong interaction between an aliphatic carbon-hydrogen bond and a metal atom: the structure of (diethylbis(1-pyrazolyl)borato)allyldicarbonylmolybdenum(II) journal August 1989
Testing the T1 method: a comparison of T1(min) and structural data journal July 1990
Synthesis and Characterization of ReCl(H 2 )(AsMePh 2 ) 4 , a Classical Hydride Complex; Reexamination of ReCl(H 2 )(PMePh 2 ) 4 and Theoretical Calculations on Model Compounds journal July 2001
Structure and Dynamics of a Dihydrogen/Hydride Ansa Molybdenocene Complex journal May 2004
Metal−Hydride and Hydride−Hydride Distances from Measurements of Selective and Nonselective 1 H T 1 Relaxation Times of Hydride Ligands:  Relaxation in NbCp 2 H 3 journal January 1998
.eta.2-Dihydrogen on the brink of homolytic cleavage: trans-[Os(H.cntdot..cntdot..cntdot.H)H(PEt2CH2CH2PEt2)2]+ has spectroscopic and chemical properties between those of the isoelectronic complexes trans-[OsH(PPh2CH2CH2PPh2)2(.eta.2-H2)]+ and ReH3(PPh2CH2CH2PPh2)2 journal April 1991
Assessment of the "T1 criterion" for distinguishing between classical and nonclassical transition-metal hydrides: hydride relaxation rates in tris(triarylphosphine)osmium tetrahydrides and related polyhydrides journal May 1991
Synthetic, structural, and mechanistic studies of the carbon-hydrogen bond activation of phenols by tungsten complexes W(PMe3)6 and W(PMe3)4(.eta.2-CH2PMe2)H journal June 1992
Photolysis of Tp'Rh(CN-neopentyl)(.eta.2-PhN:C:N-neopentyl) in alkanes and arenes: kinetic and thermodynamic selectivity of [Tp'Rh(CN-neopentyl)] for various types of carbon-hydrogen bonds journal January 1993
Facile intermolecular activation of carbon-hydrogen bonds in methane and other hydrocarbons and silicon-hydrogen bonds in silanes with the iridium(III) complex Cp*(PMe3)Ir(CH3)(OTf) journal November 1993
Preparation and Properties of [TpIr(PMe3)(H2)H]BF4: observation of Novel Isotopic Perturbation journal April 1994
Synthesis and structural studies of some new rhenium phosphine heptahydride complexes. Evidence for classical structures in solution journal June 1990
Hexakis(trimethylphosphine)tungsten(0): synthesis, structure, and reactivity journal June 1990
An NMR method for distinguishing classical from nonclassical structures in transition metal polyhydrides journal June 1988
Estimation of the hydrogen-hydrogen distances of .eta.2-dihydrogen ligands in the complexes trans-[M(.eta.2-H2)(H)(PR2CH2CH2PR2)2]+ [M = iron, ruthenium, R = Ph, M = osmium, R = Et] by solution NMR methods journal October 1988
The mechanism and thermodynamics of alkane and arene carbon-hydrogen bond activation in (C5Me5)Rh(PMe3)(R)H journal March 1984
NMR spectroscopic studies on chalcogen compounds. 4. Carbon-13 isotope effect on selenium-77 and tellurium-125 nuclear shielding and its correlation with carbon-selenium bond distances. Tellurium-123 isotope effect on tellurium-125 nuclear shielding journal December 1982
Catalysis of aromatic hydrogen-deuterium exchange by metal hydrides journal August 1970
Hydride derivatives of niobocene and tantalocene journal July 1971
Activation of aromatic carbon-hydrogen bonds by transition metal complexes. II. Substituted benzenes journal December 1972
Stereochemically nonrigid eight-coordinate molybdenum and tungsten tetrahydrides journal March 1973
Synthesis of a tantalum pentahydride complex journal August 1973
Unexpected Selectivities in C−H Activations of Toluene and p -Xylene at Cationic Platinum(II) Diimine Complexes. New Mechanistic Insight into Product-Determining Factors journal July 2001
Molybdenocene Trihydride Complexes:  Influence of a [Me 2 Si] Ansa Bridge on Classical versus Nonclassical Nature, Stability with Respect to Elimination of Dihydrogen, and Acidity journal October 2004
Intermolecular Arene C−H Activation by Nickel(II) journal December 2006
Exploring the Mechanism of Aqueous C−H Activation by Pt(II) through Model Chemistry:  Evidence for the Intermediacy of Alkylhydridoplatinum(IV) and Alkane σ-Adducts journal January 1996
Synthesis and Characterization of Hydrotris(pyrazolyl)borate Dihydrogen/Hydride Complexes of Rhodium and Iridium journal November 1997
Chemical Shift Anisotropy as a Mechanism for Modulating Apparent J Tl - H and J Tl - C Coupling Constants in Tris(pyrazolyl)hydroborato Thallium Complexes journal October 1998
NMR Chemical Shifts of Common Laboratory Solvents as Trace Impurities journal October 1997
Intermolecular activation of carbon-deuterium bonds in benzene-d6 by trans-neopentyl(trifluoromethanesulfonato)bis(trimethylphosphine)platinum(II) journal November 1988
Syntheses of Platinum(IV) Aryl Dihydride Complexes via Arene C−H Bond Activation journal April 2001
Barriers for Arene C−H Bond Activation in Platinum(II) η 2 -Arene Intermediates journal December 2002
Regioselective C−H Activation of Toluene with a 1,2-Bis( N- 7-azaindolyl)benzene Platinum(II) Complex journal June 2005
Perspectives on How Nature Employs the Principles of Organometallic Chemistry in Dihydrogen Activation in Hydrogenases journal November 2010
Thermal C−H Bond Activation of Benzene, Toluene, and Methane with Cationic [M(X)(bipy)] + (M = Ni, Pd, Pt; X = CH 3 , Cl; bipy = 2,2′-bipyridine): A Mechanistic Study journal March 2011
Trimethylphosphine–tungsten chemistry: hydrido, silyl, fluoro, hydroxy, and aquo derivatives: crystal structure of [W(PMe 3 ) 4 H 2 (OH 2 )F]F journal January 1984
Activation of C–H bonds in saturated hydrocarbons. H–D exchange between methane and benzene catalysed by a soluble iridium polyhydride system journal January 1986
Photoinduced insertion of tungsten into aromatic and aliphatic carbon–hydrogen bonds by bis(η-cyclopentadienyl)tungsten derivatives journal January 1979
The chemistry of [W(PMe 3 ) 42 -CH 2 PMe 2 )H]: synthesis of hydroxy-hydrido, fluoro-hydrido, and silyl-hydrido derivatives and the dimerisation of ethylene and propene giving η 4 -diene derivatives. Crystal structure of [W(PMe 3 ) 4 H 2 (OH 2 )F]F journal January 1986
The multifarious world of transition metal hydrides journal January 2003
Tetrahydrido-complexes of molybdenum journal January 1971
The occurrence and representation of three-centre two-electron bonds in covalent inorganic compounds journal January 2012
Group VI tetrahydrides and stereochemical non-rigidity journal January 1972
Synthesis and X-ray crystal structure of tris(phenyldi-isopropylphosphine)-tungsten hexahydride journal January 1980
[IrH2(H2)2L2]+{L = P(C6H11)3}: A non-classical polyhydride complex journal January 1985
Hexahydrido-complexes of tungsten containing dimethylphenylphosphine or diethylphenylphosphine as ligands journal January 1972
Dinitrogen, hydrido-, and carbonyl complexes of tungsten journal January 1972
Reactions of hexamethyltungsten(VI) in the presence of trimethylphosphine. Synthesis of methyl, ethylidyne, hydrido-, alkoxo-, and other tungsten compounds. X-Ray crystal structures of trans-ethylidyne(methyl)tetrakis(trimethylphosphine)tungsten(IV) and trihydrido(phenoxo)tetrakis(trimethylphosphine)tungsten(IV) journal January 1981
Trimethylphosphine polyhydrides of tungsten and rhenium journal January 1985
Hydrido-complexes of rhenium-containing tertiary phosphines journal January 1969
Isotope Shift in the Proton Magnetic Resonance of CH 4 , CH 3 D, CH 2 D 2 , and CHD 3 journal February 1965
Quantum Theory of Molecules and Solids Vol. 4: The Self‐Consistent Field for Molecules and Solids journal December 1974
Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg journal January 1985
Ab initio effective core potentials for molecular calculations. Potentials for main group elements Na to Bi journal January 1985
Ab initio effective core potentials for molecular calculations. Potentials for K to Au including the outermost core orbitals journal January 1985
Density‐functional thermochemistry. III. The role of exact exchange journal April 1993
Dihydrogen complexes as prototypes for the coordination chemistry of saturated molecules journal April 2007
Density-functional exchange-energy approximation with correct asymptotic behavior journal September 1988
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density journal January 1988
A short history of SHELX journal December 2007
Accurate spin-dependent electron liquid correlation energies for local spin density calculations: a critical analysis journal August 1980
Tertiary Phosphine Complexes of Tungsten journal October 1985
Nmr Spin-Lattice Relaxation Approaches to Characterization of Transition Metal Hydride Complexes in Solution. journal July 1998

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