Thermochemical study of tetravalent metal sulfate tetrahydrates: A4+(SO4)2(H2O)4 (A4+ = Zr, Ce, U)

Zhang, Lei; Lobeck, Haylie L.; Dzik, Ewa A.; Sigmon, Ginger E.; Burns, Peter C.

doi:10.1016/j.jssc.2019.04.030

Title: Thermochemical study of tetravalent metal sulfate tetrahydrates: A4+(SO4)2(H2O)4 (A4+ = Zr, Ce, U)

Journal Article · Thu Aug 01 00:00:00 EDT 2019 · Journal of Solid State Chemistry

DOI:https://doi.org/10.1016/j.jssc.2019.04.030· OSTI ID:1547470

Zhang, Lei; Lobeck, Haylie L.; Dzik, Ewa A.; Sigmon, Ginger E.; Burns, Peter C.

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Sponsoring Organization:: USDOE

OSTI ID:: 1547470

Journal Information:: Journal of Solid State Chemistry, Journal Name: Journal of Solid State Chemistry Vol. 276 Journal Issue: C; ISSN 0022-4596

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

References (25)

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Enthalpies of formation of Ce-pyrochlore, Ca0.93Ce1.00Ti2.035O7.00, U-pyrochlore, Ca1.46U4+0.23U6+0.46Ti1.85O7.00 and Gd-pyrochlore, Gd2Ti2O7: three materials relevant to the proposed waste form for excess weapons plutonium Helean, K. B.; Navrotsky, A.; Vance, E. R. Journal of Nuclear Materials, Vol. 303, Issue 2-3 https://doi.org/10.1016/S0022-3115(02)00795-X	journal	June 2002
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Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Structure of thorium sulphate octahydrate, Th(SO4)2.8H2O Habash, J.; Smith, A. J. Acta Crystallographica Section C Crystal Structure Communications, Vol. 39, Issue 4 https://doi.org/10.1107/S010827018300493X	journal	April 1983
The Crystal Structure of U(SO4)2-4H2O. Kierkegaard, Peder; Parck, Curt; Ulfvarson, Ulf Acta Chemica Scandinavica, Vol. 10 https://doi.org/10.3891/acta.chem.scand.10-0599	journal	January 1956
Uranium(IV) Sulfates: Investigating Structural Periodicity in the Tetravalent Actinides Schnaars, David D.; Wilson, Richard E. Inorganic Chemistry, Vol. 51, Issue 17 https://doi.org/10.1021/ic301291w	journal	August 2012
The crystal structures of α - and β -forms of plutonium(IV) sulphate tetrahydrate Jayadevan, N. C.; Mudher, K. D. Singh; Chackraburtty, D. M. Zeitschrift für Kristallographie, Vol. 161, Issue 1-2 https://doi.org/10.1524/zkri.1982.161.1-2.7	journal	January 1982
An Open-Framework Thorium Sulfate Hydrate with 11.5 Å Voids Wilson, Richard E.; Skanthakumar, S.; Knope, Karah E. Inorganic Chemistry, Vol. 47, Issue 20 https://doi.org/10.1021/ic800931f	journal	October 2008
Thermochemistry of rare earth doped uranium oxides LnxU1−xO2−0.5x+y (Ln = La, Y, Nd) Zhang, Lei; Navrotsky, Alexandra Journal of Nuclear Materials, Vol. 465 https://doi.org/10.1016/j.jnucmat.2015.06.059	journal	October 2015
Monoclinic to tetragonal transformations in hafnia and zirconia: A combined calorimetric and density functional study Luo, Xuhui; Zhou, Wei; Ushakov, Sergey V. Physical Review B, Vol. 80, Issue 13 https://doi.org/10.1103/PhysRevB.80.134119	journal	October 2009
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Title: Thermochemical study of tetravalent metal sulfate tetrahydrates: A4+(SO4)2(H2O)4 (A4+ = Zr, Ce, U)