Anion-adaptive crystalline cationic material for 99TcO4- trapping

Mei, Lei; Li, Fei-ze; Lan, Jian-hui; Wang, Cong-zhi; Xu, Chao; Deng, Hao; Wu, Qun-yan; Hu, Kong-qiu; Wang, Lin; Chai, Zhi-fang; Chen, Jing; Gibson, John K.; Shi, Wei-qun

doi:10.1038/s41467-019-09504-3

Anion-adaptive crystalline cationic material for ⁹⁹TcO₄^- trapping

Journal Article · Thu Apr 04 00:00:00 EDT 2019 · Nature Communications

DOI:https://doi.org/10.1038/s41467-019-09504-3· OSTI ID:1546668

^[1]; Li, Fei-ze ^[1]; Lan, Jian-hui ^[1]; Wang, Cong-zhi ^[1]; Xu, Chao ^[2]; Deng, Hao ^[1]; Wu, Qun-yan ^[1]; Hu, Kong-qiu ^[1]; ^[1]; Chai, Zhi-fang ^[3]; Chen, Jing ^[2]; Gibson, John K. ^[4]; Shi, Wei-qun ^[1]

Chinese Academy of Sciences (CAS), Beijing (China)
Tsinghua Univ., Beijing (China)
Chinese Academy of Sciences (CAS), Beijing (China); Chinese Academy of Sciences, Ningbo, Zhejiang (China)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Efficient anion recognition is of great significance for radioactive ⁹⁹TcO₄^- decontamination, but it remains a challenge for traditional sorbents. Herein, we put forward a tactic using soft crystalline cationic material with anion-adaptive dynamics for ⁹⁹TcO₄^- sequestration. A cucurbit[8]uril-based supramolecular metal-organic material is produced through a multi-component assembly strategy and used as a sorbent for effective trapping of TcO₄^-. Excellent separation of TcO₄^-/ReO₄^- is demonstrated by fast removal kinetics, good sorption capacity and high distribution coefficient. Remarkably, the most superior selectivity among metal-organic materials reported so far, together with good hydrolytic stability, indicates potential for efficient TcO₄^- removal. The structure incorporating ReO₄^- reveals that the supramolecular framework undergoes adaptive reconstruction facilitating the effective accommodation of TcO₄^-/ReO₄^-. The results highlight opportunities for development of soft anion-adaptive sorbents for highly selective anion decontamination.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Actinide Science & Technology (CAST); Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Chemical Sciences, Geosciences & Biosciences Division

Grant/Contract Number:: AC02-05CH11231; SC0016568

OSTI ID:: 1546668

Journal Information:: Nature Communications, Journal Name: Nature Communications Journal Issue: 1 Vol. 10; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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