Anchoring carbon nanotubes and post-hydroxylation treatment enhanced Ni nanofiber catalysts towards efficient hydrous hydrazine decomposition for effective hydrogen generation

Yang, Pan; Yang, Lijun; Gao, Qiang; Luo, Qiang; Zhao, Xiaochong; Mai, Xianmin; Fu, Qinglong; Dong, Mengyao; Wang, Jingchuan; Hao, Yawei; Yang, Ruizhu; Lai, Xinchun; Wu, Shide; Shao, Qian; Ding, Tao; Lin, Jing; Guo, Zhanhu

doi:10.1039/C9CC04559G

Title: Anchoring carbon nanotubes and post-hydroxylation treatment enhanced Ni nanofiber catalysts towards efficient hydrous hydrazine decomposition for effective hydrogen generation

Journal Article · Thu Jun 27 00:00:00 EDT 2019 · ChemComm

DOI:https://doi.org/10.1039/C9CC04559G· OSTI ID:1546532

Yang, Pan ^[1];

^[1];

^[2]; Luo, Qiang ^[3];

^[1]; Mai, Xianmin ^[4]; Fu, Qinglong ^[1]; Dong, Mengyao ^[5]; Wang, Jingchuan ^[1]; Hao, Yawei ^[1]; Yang, Ruizhu ^[1]; Lai, Xinchun ^[1]; Wu, Shide ^[6]; Shao, Qian ^[7]; Ding, Tao ^[8]; Lin, Jing ^[9];

^[10]

Chinese Academy of Engineering Physics, Jiangyou (China)
Max Planck Inst. for Chemical Energy Conversion, Mülheim (Germany)
Hainan Univ., Haikou (China); Univ. of Tennessee, Knoxville, TN (United States)
Southwest Minzu Univ., Chengdu (China)
Univ. of Tennessee, Knoxville, TN (United States); Zhengzhou Univ., Zhengzhou (China)
Zhengzhou Univ. of Light Industry, Zhengzhou (China)
Shandong Univ. of Science and Technology, Qingdao (China)
Henan Univ., Kaifeng (China)
Guangzhou Univ., Guangzhou (China)
Univ. of Tennessee, Knoxville, TN (United States)

For effective hydrogen generation with remarkable durability, carbon nanotubes (CNTs) grown on Ni nanofibers and their post hydroxylation treatment engendered active Ni nanofiber catalysts an efficient decomposition of hydrous hydrazine with a turnover frequency (TOF) of 19.4 h^-1 and an activation energy down to 51.05 KJ mol^-1.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE; National Natural Science Foundation of China (NSFC)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1546532

Journal Information:: ChemComm, Vol. 55, Issue 61; ISSN 1359-7345

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 98 works

Citation information provided by
Web of Science

References (42)

High capacity hydrogenstorage materials: attributes for automotive applications and techniques for materials discovery Yang, Jun; Sudik, Andrea; Wolverton, Christopher Chem. Soc. Rev., Vol. 39, Issue 2 https://doi.org/10.1039/B802882F	journal	January 2010
Microwave Popped Co(II)-Graphene Oxide Hybrid: Bifunctional Catalyst for Hydrogen Evolution Reaction and Hydrogen Storage Wei, Lin; Lozano, Karen; Mao, Yuanbing Engineered Science https://doi.org/10.30919/es8d723	journal	June 2018
Facile Preparation of 1T/2H‐Mo(S _1‐x Se _x ) ₂ Nanoparticles for Boosting Hydrogen Evolution Reaction Lin, Zhiping; Lin, Bo; Wang, Zongpeng ChemCatChem, Vol. 11, Issue 8 https://doi.org/10.1002/cctc.201900095	journal	March 2019
Hydrogen carriers He, Teng; Pachfule, Pradip; Wu, Hui Nature Reviews Materials, Vol. 1, Issue 12 https://doi.org/10.1038/natrevmats.2016.59	journal	October 2016
Preparation and hydrogen storage of Pd/MIL-101 nanocomposites Zhao, Yanliang; Liu, Fei; Tan, Junhua Journal of Alloys and Compounds, Vol. 772 https://doi.org/10.1016/j.jallcom.2018.09.045	journal	January 2019
Energy storage applications of activated carbons: supercapacitors and hydrogen storage Sevilla, Marta; Mokaya, Robert Energy Environ. Sci., Vol. 7, Issue 4 https://doi.org/10.1039/C3EE43525C	journal	January 2014
Liquid organic and inorganic chemical hydrides for high-capacity hydrogen storage Zhu, Qi-Long; Xu, Qiang Energy & Environmental Science, Vol. 8, Issue 2 https://doi.org/10.1039/C4EE03690E	journal	January 2015
A comparative overview of hydrogen production processes Nikolaidis, Pavlos; Poullikkas, Andreas Renewable and Sustainable Energy Reviews, Vol. 67 https://doi.org/10.1016/j.rser.2016.09.044	journal	January 2017
A noble-metal-free nanocatalyst for highly efficient and complete hydrogen evolution from N ₂ H ₄ BH ₃ Yao, Qilu; Lu, Zhang-Hui; Zhang, Rui Journal of Materials Chemistry A, Vol. 6, Issue 10 https://doi.org/10.1039/C7TA10886A	journal	January 2018
Complete Conversion of Hydrous Hydrazine to Hydrogen at Room Temperature for Chemical Hydrogen Storage Singh, Sanjay Kumar; Xu, Qiang Journal of the American Chemical Society, Vol. 131, Issue 50 https://doi.org/10.1021/ja908037t	journal	December 2009
Noble-Metal-Free Bimetallic Nanoparticle-Catalyzed Selective Hydrogen Generation from Hydrous Hydrazine for Chemical Hydrogen Storage Singh, Sanjay Kumar; Singh, Ashish Kumar; Aranishi, Kengo Journal of the American Chemical Society, Vol. 133, Issue 49 https://doi.org/10.1021/ja208475y	journal	December 2011
Hydrogen generation from hydrous hydrazine over Ni/CeO2 catalysts prepared by solution combustion synthesis Kang, Wooram; Varma, Arvind Applied Catalysis B: Environmental, Vol. 220 https://doi.org/10.1016/j.apcatb.2017.08.053	journal	January 2018
Nitrogen-doped graphene hydrogel-supported NiPt-CeO x nanocomposites and their superior catalysis for hydrogen generation from hydrazine at room temperature Du, Xiaoqiong; Liu, Chao; Du, Cheng Nano Research, Vol. 10, Issue 8 https://doi.org/10.1007/s12274-017-1494-6	journal	May 2017
Selective Breaking of Hydrogen Bonds of Layered Carbon Nitride for Visible Light Photocatalysis Kang, Yuyang; Yang, Yongqiang; Yin, Li-Chang Advanced Materials, Vol. 28, Issue 30 https://doi.org/10.1002/adma.201601567	journal	May 2016
Ni–C–N Nanosheets as Catalyst for Hydrogen Evolution Reaction Yin, Jie; Fan, Qiaohui; Li, Yuxuan Journal of the American Chemical Society, Vol. 138, Issue 44 https://doi.org/10.1021/jacs.6b09351	journal	October 2016
Anchoring and Upgrading Ultrafine NiPd on Room-Temperature-Synthesized Bifunctional NH ₂ -N-rGO toward Low-Cost and Highly Efficient Catalysts for Selective Formic Acid Dehydrogenation Yan, Jun-Min; Li, Si-Jia; Yi, Sha-Sha Advanced Materials, Vol. 30, Issue 12 https://doi.org/10.1002/adma.201703038	journal	February 2018
Low temperature decomposition of hydrous hydrazine over FeNi/Cu nanoparticles Manukyan, Khachatur V.; Cross, Allison; Rouvimov, Sergei Applied Catalysis A: General, Vol. 476 https://doi.org/10.1016/j.apcata.2014.02.012	journal	April 2014
Ni–Pt nanoparticles growing on metal organic frameworks (MIL-96) with enhanced catalytic activity for hydrogen generation from hydrazine at room temperature Wen, Lan; Du, Xiaoqiong; Su, Jun Dalton Transactions, Vol. 44, Issue 13 https://doi.org/10.1039/C5DT00493D	journal	January 2015
A study of degradation phenomenon of Ni–Pt/CeO2 catalyst towards hydrogen generation from hydrous hydrazine Dai, Hao; Qiu, Yu-Ping; Dai, Hong-Bin International Journal of Hydrogen Energy, Vol. 42, Issue 26 https://doi.org/10.1016/j.ijhydene.2017.05.086	journal	June 2017
Controlled Synthesis of MOF-Encapsulated NiPt Nanoparticles toward Efficient and Complete Hydrogen Evolution from Hydrazine Borane and Hydrazine Zhang, Zhujun; Zhang, Shiliang; Yao, Qilu Inorganic Chemistry, Vol. 56, Issue 19 https://doi.org/10.1021/acs.inorgchem.7b01910	journal	September 2017
Supported nickel–iron nanocomposites as a bifunctional catalyst towards hydrogen generation from N2H4·H2O Gao, Wa; Li, Changming; Chen, Hao Green Chemistry, Vol. 16, Issue 3 https://doi.org/10.1039/c3gc41939h	journal	January 2014
A Noble-Metal-Free Catalyst Derived from Ni-Al Hydrotalcite for Hydrogen Generation from N2H4⋅H2O Decomposition He, Lei; Huang, Yanqiang; Wang, Aiqin Angewandte Chemie International Edition, Vol. 51, Issue 25 https://doi.org/10.1002/anie.201201737	journal	May 2012
Yolk–Satellite–Shell Structured Ni–Yolk@Ni@SiO ₂ Nanocomposite: Superb Catalyst toward Methane CO ₂ Reforming Reaction Li, Ziwei; Mo, Liuye; Kathiraser, Yasotha ACS Catalysis, Vol. 4, Issue 5 https://doi.org/10.1021/cs401027p	journal	April 2014
Hollow nickel-coated silica microspheres containing rhodium nanoparticles for highly selective production of hydrogen from hydrous hydrazine Yoo, Jung Bo; Kim, Han Sol; Kang, Seung Hee J. Mater. Chem. A, Vol. 2, Issue 44 https://doi.org/10.1039/C4TA03550J	journal	January 2014
In situ synthesis of Ni nanofibers via vacuum thermal reduction and their efficient catalytic properties for hydrogen generation Fu, Qinglong; Yang, Pan; Wang, Jingchuan Journal of Materials Chemistry A, Vol. 6, Issue 24 https://doi.org/10.1039/C8TA03464H	journal	January 2018
Construction of bimetallic nanoparticles immobilized by porous functionalized metal-organic frameworks toward remarkably enhanced catalytic activity for the room-temperature complete conversion of hydrous hydrazine into hydrogen Liu, Penglong; Gu, Xiaojun; Wu, Yanyan International Journal of Hydrogen Energy, Vol. 42, Issue 30 https://doi.org/10.1016/j.ijhydene.2017.06.191	journal	July 2017
Hydrophilic mesoporous poly(ionic liquid)-supported Au–Pd alloy nanoparticles towards aerobic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid under mild conditions Wang, Qian; Hou, Wei; Li, Shuai Green Chemistry, Vol. 19, Issue 16 https://doi.org/10.1039/C7GC01116D	journal	January 2017
Ultrafine bimetallic Pt–Ni nanoparticles immobilized on 3-dimensional N-doped graphene networks: a highly efficient catalyst for dehydrogenation of hydrous hydrazine Kumar, Amit; Yang, Xinchun; Xu, Qiang Journal of Materials Chemistry A, Vol. 7, Issue 1 https://doi.org/10.1039/C8TA09003C	journal	January 2019
Catalyst surfaces with tunable hydrophilicity and hydrophobicity: metal–organic frameworks toward controllable catalytic selectivity Chen, Xinyi; Qian, Panpan; Zhang, Tao Chemical Communications, Vol. 54, Issue 32 https://doi.org/10.1039/C8CC00318A	journal	January 2018
Importance of Zeolite Wettability for Selective Hydrogenation of Furfural over Pd@Zeolite Catalysts Wang, Chengtao; Liu, Zhiqiang; Wang, Liang ACS Catalysis, Vol. 8, Issue 1 https://doi.org/10.1021/acscatal.7b03443	journal	December 2017
Growing a hydrophilic nanoporous shell on a hydrophobic catalyst interface for aqueous reactions with high reaction efficiency and in situ catalyst recycling Hao, Yajuan; Jiao, Xuan; Zou, Houbing Journal of Materials Chemistry A, Vol. 5, Issue 31 https://doi.org/10.1039/C6TA11124F	journal	January 2017
Chemical reactions confined within carbon nanotubes Miners, Scott A.; Rance, Graham A.; Khlobystov, Andrei N. Chemical Society Reviews, Vol. 45, Issue 17 https://doi.org/10.1039/C6CS00090H	journal	January 2016
Horizontally aligned carbon nanotube arrays: growth mechanism, controlled synthesis, characterization, properties and applications Zhang, Rufan; Zhang, Yingying; Wei, Fei Chemical Society Reviews, Vol. 46, Issue 12 https://doi.org/10.1039/C7CS00104E	journal	January 2017
Low-Temperature in Situ Growth of Graphene on Metallic Substrates and Its Application in Anticorrosion Zhu, Minmin; Du, Zehui; Yin, Zongyou ACS Applied Materials & Interfaces, Vol. 8, Issue 1 https://doi.org/10.1021/acsami.5b09453	journal	December 2015
Three dimensional hybrid multi-layered graphene–CNT catalyst supports via rapid thermal annealing of nickel acetate Samuels, Thomas O. M.; Robertson, Alex W.; Kim, Heeyeon Journal of Materials Chemistry A, Vol. 5, Issue 21 https://doi.org/10.1039/C7TA01852E	journal	January 2017
Porous hierarchical nickel nanostructures and their application as a magnetically separable catalyst Xiong, Jingfang; Shen, Hu; Mao, Junxian Journal of Materials Chemistry, Vol. 22, Issue 24 https://doi.org/10.1039/c2jm30361b	journal	January 2012
Thermal decomposition of nickel acetate tetrahydrate: an integrated study by TGA, QMS and XPS techniques De Jesus, Juan C.; González, Ismael; Quevedo, Angel Journal of Molecular Catalysis A: Chemical, Vol. 228, Issue 1-2 https://doi.org/10.1016/j.molcata.2004.09.065	journal	March 2005
A RhNiP/rGO hybrid for efficient catalytic hydrogen generation from an alkaline solution of hydrazine Du, Xiaoqiong; Tan, Shiyi; Cai, Ping Journal of Materials Chemistry A, Vol. 4, Issue 38 https://doi.org/10.1039/C6TA05917A	journal	January 2016
CeOx-modified NiFe nanodendrits grown on rGO for efficient catalytic hydrogen generation from alkaline solution of hydrazine Men, Yana; Du, Xiaoqiong; Cheng, Gongzhen International Journal of Hydrogen Energy, Vol. 42, Issue 44 https://doi.org/10.1016/j.ijhydene.2017.08.214	journal	November 2017
Complete dehydrogenation of hydrazine borane and hydrazine catalyzed by MIL-101 supported NiFePd nanoparticles Yang, Kun; Yang, Kangkang; Zhang, Shiliang Journal of Alloys and Compounds, Vol. 732 https://doi.org/10.1016/j.jallcom.2017.10.241	journal	January 2018
Highly efficient hydrogen generation from hydrous hydrazine over amorphous Ni0.9Pt0.1/Ce2O3 nanocatalyst at room temperature Wang, Hong-Li; Yan, Jun-Min; Wang, Zhi-Li Journal of Materials Chemistry A, Vol. 1, Issue 47 https://doi.org/10.1039/c3ta13259e	journal	January 2013
A Noble-Metal-Free Catalyst Derived from Ni-Al Hydrotalcite for Hydrogen Generation from N2H4⋅H2O Decomposition He, Lei; Huang, Yanqiang; Wang, Aiqin Angewandte Chemie, Vol. 124, Issue 25 https://doi.org/10.1002/ange.201201737	journal	May 2012

Cited By (24)

Edge Dislocations Induce Improved Photocatalytic Efficiency of Colored TiO ₂ Ren, Peng; Song, Miao; Lee, Jaewon Advanced Materials Interfaces, Vol. 6, Issue 17 https://doi.org/10.1002/admi.201901121	journal	July 2019
Fluorescent Carbon‐ and Oxygen‐Doped Hexagonal Boron Nitride Powders as Printing Ink for Anticounterfeit Applications Liu, Feng; Nattestad, Andrew; Naficy, Sina Advanced Optical Materials, Vol. 7, Issue 24 https://doi.org/10.1002/adom.201901380	journal	September 2019
Simultaneously reinforcing and toughening poly(lactic acid) by incorporating reactive melt‐functionalized silica nanoparticles Wang, Bo; Zhang, Xin; Zhang, Lutong Journal of Applied Polymer Science, Vol. 137, Issue 26 https://doi.org/10.1002/app.48834	journal	July 2020
Multifunctions of Polymer Nanocomposites: Environmental Remediation, Electromagnetic Interference Shielding, And Sensing Applications Wei, Huige; Wang, Hui; Li, Ang ChemNanoMat, Vol. 6, Issue 2 https://doi.org/10.1002/cnma.201900588	journal	January 2020
Alternating Multilayer Structural Epoxy Composite Coating for Corrosion Protection of Steel Zhang, Jiaoxia; Zhang, Weirui; Wei, Liping Macromolecular Materials and Engineering, Vol. 304, Issue 12 https://doi.org/10.1002/mame.201900374	journal	September 2019
Research Progress in the Field of Adsorption and Catalytic Degradation of Sewage by Hydrotalcite‐Derived Materials Pan, Duo; Ge, Shengsong; Tian, Jiangyang The Chemical Record, Vol. 20, Issue 4 https://doi.org/10.1002/tcr.201900046	journal	April 2020
Advances in Template Prepared Nano‐Oxides and their Applications: Polluted Water Treatment, Energy, Sensing and Biomedical Drug Delivery Zhao, Junkai; Shao, Qian; Ge, Shengsong The Chemical Record, Vol. 20, Issue 7 https://doi.org/10.1002/tcr.201900093	journal	January 2020
2D/2D WO3·H2O/g-C3N4 heterostructured assemblies for enhanced photocatalytic water decontamination via strong interfacial contact Li, Longfei; Jiang, Daixun; Wu, Xilu Journal of Materials Science, Vol. 55, Issue 10 https://doi.org/10.1007/s10853-019-04264-3	journal	December 2019
Preparation of Chitosan, Sodium Alginate, Gelatin and Collagen Biodegradable Sponge Composites and their Application in Wound Healing and Curcumin Delivery Naghshineh, Negar; Tahvildari, Kambiz; Nozari, Maryam Journal of Polymers and the Environment, Vol. 27, Issue 12 https://doi.org/10.1007/s10924-019-01559-z	journal	September 2019
Reversibly switching water droplets wettability on hierarchical structured Cu2S mesh for efficient oil/water separation Xu, Shanya; Sheng, Rui; Cao, Yali Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-48952-1	journal	August 2019
Selective synthesis of 1,3-propanediol from glycidol over a carbon film encapsulated Co catalyst Sun, Yanyan; Cai, Zhongshun; Li, Xuewen Catalysis Science & Technology, Vol. 9, Issue 18 https://doi.org/10.1039/c9cy01162e	journal	January 2019
Theoretical screening of efficient single-atom catalysts for nitrogen fixation based on a defective BN monolayer Ma, Zuju; Cui, Zhitao; Xiao, Chengwei Nanoscale, Vol. 12, Issue 3 https://doi.org/10.1039/c9nr08969a	journal	January 2020
Sandwich structured WO ₃ nanoplatelets for highly efficient photoelectrochemical water splitting Zheng, Guangwei; Wang, Jinshu; Zu, Guannan Journal of Materials Chemistry A, Vol. 7, Issue 45 https://doi.org/10.1039/c9ta09188b	journal	January 2019
An overview of stretchable strain sensors from conductive polymer nanocomposites Chen, Jianwen; Yu, Qunli; Cui, Xihua Journal of Materials Chemistry C, Vol. 7, Issue 38 https://doi.org/10.1039/c9tc03655e	journal	January 2019
Carbon dot-sensitized urchin-like Ti ³⁺ self-doped TiO ₂ photocatalysts with enhanced photoredox ability for highly efficient removal of Cr ⁶⁺ and RhB Shi, Cai; Qi, Houjuan; Sun, Zhe Journal of Materials Chemistry C, Vol. 8, Issue 7 https://doi.org/10.1039/c9tc05513d	journal	January 2020
Supramolecular self-assembly of oleylamide into organogels and hydrogels: a simple approach in phase selective gelation of oil spills Eftekhari-Sis, Bagher; Bagheri, Azam; Younesi Araghi, Hessamaddin Soft Materials, Vol. 18, Issue 1 https://doi.org/10.1080/1539445x.2019.1684948	journal	November 2019
An overview of photocatalysis facilitated by 2D heterojunctions Su, Tongming; Qin, Zuzeng; Ji, Hongbing Nanotechnology, Vol. 30, Issue 50 https://doi.org/10.1088/1361-6528/ab3f15	journal	September 2019
Hydrogen bonding derived self-healing polymer composites reinforced with amidation carbon fibers Wang, Ying; Jiang, Dawei; Zhang, Lu Nanotechnology, Vol. 31, Issue 2 https://doi.org/10.1088/1361-6528/ab4743	journal	October 2019
Interaction between Graphene Oxide and the Mycelia of Morchella sextelata Tan, Renhao; Li, Jiwei; Zhou, Li Nano, Vol. 15, Issue 03 https://doi.org/10.1142/s1793292020500356	journal	March 2020
MnO ₂ Nanoparticle Improved Cyclic Stability of Carbon Fiber Cloth Supported NiO Battery-Type Supercapacitor Materials by Microwave Solid-State Method Zheng, Yayun; Zhang, Xiaodong; Tian, Yunrui Journal of The Electrochemical Society, Vol. 166, Issue 16 https://doi.org/10.1149/2.0201916jes	journal	January 2019
3-Dimensional graphene/Cu/Fe ₃ O ₄ composites: Immobilized laccase electrodes for detecting bisphenol A Lou, Congqiang; Jing, Tao; Tian, Jingzhi Journal of Materials Research, Vol. 34, Issue 17 https://doi.org/10.1557/jmr.2019.248	journal	September 2019
Alternating Multilayer Structural Epoxy Composite Coating for Corrosion Protection of Steel Zhang, Jiaoxia; Zhang, Weirui; Wei, Liping Macromolecular Materials and Engineering, Vol. 304, Issue 12 https://doi.org/10.1002/mame.201970035	journal	October 2019
Supramolecular self-assembly of oleylamide into organogels and hydrogels: a simple approach in phase selective gelation of oil spills Eftekhari-Sis, Bagher; Bagheri, Azam; Araghi, Hessamaddin Younesi Taylor & Francis https://doi.org/10.6084/m9.figshare.10119329	text	January 2019
Supramolecular self-assembly of oleylamide into organogels and hydrogels: a simple approach in phase selective gelation of oil spills Eftekhari-Sis, Bagher; Bagheri, Azam; Araghi, Hessamaddin Younesi Taylor & Francis https://doi.org/10.6084/m9.figshare.10119329.v1	text	January 2019