skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Phase Identification of the Layered Perovskite CexSr2–xMnO4 and Application for Solar Thermochemical Water Splitting

Journal Article · · Inorganic Chemistry
 [1];  [1];  [2]; ORCiD logo [1]; ORCiD logo [3];  [4]; ORCiD logo [2];  [1];  [1]
  1. Metallurgical and Materials Engineering Department, Colorado School of Mines, Golden, Colorado, United States
  2. Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois, United States
  3. Department of Materials Science and Engineering, Clemson University, Clemson, South Carolina, United States
  4. Sandia National Laboratory, Livermore, California, United States

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - BASIC ENERGY SCIENCES
OSTI ID:
1545874
Journal Information:
Inorganic Chemistry, Vol. 58, Issue 12; ISSN 0020-1669
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
ENGLISH

References (52)

Recent advances in Perovskite-type materials for solid oxide fuel cell cathodes journal March 2001
Giant negative magnetoresistance in perovskitelike La 2 / 3 Ba 1 / 3 MnO x ferromagnetic films journal October 1993
A review on all-perovskite multiferroic tunnel junctions journal December 2017
Progress in oxygen carrier development of methane-based chemical-looping reforming: A review journal August 2015
Perovskite oxides – a review on a versatile material class for solar-to-fuel conversion processes journal January 2017
Predictions of new AB O 3 perovskite compounds by combining machine learning and density functional theory journal April 2018
High-Throughput Computational Screening of Perovskites for Thermochemical Water Splitting Applications journal July 2016
High-throughput DFT calculations of formation energy, stability and oxygen vacancy formation energy of ABO3 perovskites journal October 2017
Modeling Thermochemical Solar-to-Fuel Conversion: CALPHAD for Thermodynamic Assessment Studies of Perovskites, Exemplified for (La,Sr)MnO 3 journal September 2016
The crystal chemistry of AM2O4 oxometallates journal February 2003
A thermodynamic and electrical conductivity study of nonstoichiometric cerium dioxide journal April 1993
Sr- and Mn-doped LaAlO3−δ for solar thermochemical H2 and CO production journal January 2013
Tunable Oxygen Vacancy Formation Energetics in the Complex Perovskite Oxide Sr x La 1– x Mn y Al 1– y O 3 journal November 2014
First-principles thermodynamic framework for the evaluation of thermochemical H 2 O - or CO 2 -splitting materials journal December 2009
Considerations in the Design of Materials for Solar-Driven Fuel Production Using Metal-Oxide Thermochemical Cycles journal October 2013
Intrinsic Material Properties Dictating Oxygen Vacancy Formation Energetics in Metal Oxides journal May 2015
BaCe 0.25 Mn 0.75 O 3−δ —a promising perovskite-type oxide for solar thermochemical hydrogen production journal January 2018
The compound Sr 3 Ti 2 O 7 and its structure journal January 1958
Hyperstoichiometric La1.9Sr0.1NiO4+δ Mixed Conductor as Novel Cathode for Intermediate Temperature Solid Oxide Fuel Cells journal June 2006
Synthesis, structural analysis and electrochemical performance of low-copper content La2Ni1−xCuxO4+δ materials as new cathodes for solid oxide fuel cells journal November 2009
Oxygen transport in La2-x Sr x NiO4+δ: membrane permeation and defect chemical modelling journal February 2007
Enhanced High-Temperature Electronic Transport Properties in Nanostructured Epitaxial Thin Films of the La n +1 Ni n O 3 n +1 Ruddlesden−Popper Series ( n = 1, 2, 3, ∞) journal August 2007
Composition and electrical conductivity of some cobaltates of the type La2−xSrxCoO4.5−x/2±δ journal December 2000
Enhancement of Ionic Transport in Complex Oxides through Soft Lattice Modes and Epitaxial Strain journal March 2015
Controlling Oxygen Mobility in Ruddlesden–Popper Oxides journal March 2017
Investigation of Perovskite Structures as Oxygen-Exchange Redox Materials for Hydrogen Production from Thermochemical Two-Step Water-Splitting Cycles journal June 2014
A novel wet-chemistry method for the synthesis of multicomponent nanoparticles: A case study of BaCe0.7Zr0.1Y0.1Yb0.1O3−δ journal February 2013
Synthesis, characterization and catalytic activity for NO–CO reaction of Pd–(La, Sr)2MnO4 system journal January 2007
Superiority of nitrate decomposition method for synthesis of K2NiF4-type LaxSr2−xMnO4 catalysts journal August 2007
GSAS-II : the genesis of a modern open-source all purpose crystallography software package journal March 2013
CRISP: crystallographic image processing on a personal computer journal April 1992
Three-dimensional reconstruction of the ν-AlCrFe phase by electron crystallography journal October 2003
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal July 1996
From ultrasoft pseudopotentials to the projector augmented-wave method journal January 1999
Generalized Gradient Approximation Made Simple journal October 1996
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study journal January 1998
Oxidation energies of transition metal oxides within the GGA + U framework journal May 2006
The Open Quantum Materials Database (OQMD): assessing the accuracy of DFT formation energies journal December 2015
Correcting density functional theory for accurate predictions of compound enthalpies of formation: Fitted elemental-phase reference energies journal March 2012
Formation enthalpies by mixing GGA and GGA + U calculations journal July 2011
Special quasirandom structures journal July 1990
The alloy theoretic automated toolkit: A user guide journal December 2002
Hydrogen Production via Chemical Looping Redox Cycles Using Atomic Layer Deposition-Synthesized Iron Oxide and Cobalt Ferrites journal April 2011
Nonstoichiometric Perovskite Oxides for Solar Thermochemical H2 and CO Production journal January 2014
Novel rare-earth-containing manganites Ba4REMn3O12 (RE=Ce, Pr) with 12R structure journal March 2004
IR-spectroscopic behaviour of AA′BO4 oxides belonging to the K2NiF4 structural type journal April 2004
Enthalpies of Oxidation of CaMnO 3-δ , Ca 2 MnO 4-δ and SrMnO 3-δ Deduced Redox Properties journal November 2001
Corner- versus face-sharing octahedra in A Mn O 3 perovskites ( A = Ca , Sr, and Ba) journal May 2007
VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal October 2011
Influence of oxygen mobility on catalytic activity of La–Sr–Mn–O composites in the reaction of high temperature N2O decomposition journal October 2009
Insights into the Reactivity of La1−x Sr x MnO3 (x = 0 ÷ 0.7) in High Temperature N2O Decomposition journal November 2010