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Refractive index of lithium fluoride to 900 gigapascal and implications for dynamic equation of state measurements

Journal Article · · Journal of Applied Physics
DOI:https://doi.org/10.1063/1.5091722· OSTI ID:1545328

Lithium fluoride (LiF) is a unique crystal possessing the largest reported bandgap of any material and is predicted to remain transparent to visible light under stresses in excess of 1000 GPa. Dynamic compression experiments often utilize LiF as a window material to maintain stress on a sample while enabling direct measurements of interface velocity. However, typical velocimetry diagnostics measure changes in the optical path length; therefore, an accurate understanding of LiF’s equation of state and refractive index is needed. Here, we present a measurement of the LiF refractive index up to 900 GPa from a low-temperature ramp-compression experiment at the National Ignition Facility. To demonstrate propagation of optical uncertainty from this work to equation of state measurements, simulations in which a tin–LiF interface reaches a peak stress of 825 GPa show that the principal isentrope of tin can be determined up to 1450 GPa with a 1.2% uncertainty in density while considering uncertainties in the optical response of LiF.

Research Organization:
Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
Grant/Contract Number:
AC52-07NA27344
OSTI ID:
1545328
Alternate ID(s):
OSTI ID: 1510158
OSTI ID: 1557060
Report Number(s):
LLNL-JRNL-767294; IM #957376
Journal Information:
Journal of Applied Physics, Journal Name: Journal of Applied Physics Journal Issue: 17 Vol. 125; ISSN 0021-8979
Publisher:
American Institute of Physics (AIP)Copyright Statement
Country of Publication:
United States
Language:
English

References (41)

Survey of diagnostic tools used in hypervelocity impact studies journal January 1987
Survey of diagnostic tools used in hypervelocity impact studies journal January 1987
Pyrite: Shock compression, isentropic release, and composition of the Earth's core journal September 1987
Equations of state and crystal structures of high-pressure phases of shocked silicates and oxides journal January 1969
Pyrite: Shock compression, isentropic release, and composition of the Earth's core journal September 1987
Equations of state and crystal structures of high-pressure phases of shocked silicates and oxides journal January 1969
Conventional superconductivity at 203 kelvin at high pressures in the sulfur hydride system journal August 2015
Impact vaporization of planetesimal cores in the late stages of planet formation journal March 2015
Equation of state of iron under core conditions of large rocky exoplanets journal April 2018
Characteristics analysis of Isentropic Compression Experiments (ICE) journal July 2006
Unsteady compression waves in interferometer windows journal June 2001
Shock‐Wave Studies of PMMA, Fused Silica, and Sapphire journal September 1970
Determination of Constitutive Relationships with Multiple Gauges in Nondivergent Waves journal January 1971
Laser interferometer for measuring high velocities of any reflecting surface journal November 1972
A Characteristics Code for Analysis of Isentropic Compression Experiments
  • Maw, J. R.
  • SHOCK COMPRESSION OF CONDENSED MATTER - 2003: Proceedings of the Conference of the American Physical Society Topical Group on Shock Compression of Condensed Matter, AIP Conference Proceedings https://doi.org/10.1063/1.1780457
conference January 2004
Compact system for high-speed velocimetry using heterodyne techniques journal August 2006
Accuracy limits and window corrections for photon Doppler velocimetry journal January 2007
Velocity correction and refractive index changes for [100] lithium fluoride optical windows under shock compression, recompression, and unloading journal May 2008
Strength of lithium fluoride under shockless compression to 114 GPa journal November 2009
Refractive index of lithium fluoride ramp compressed to 800 GPa journal June 2011
Determining the refractive index of shocked [100] lithium fluoride to the limit of transmissibility journal July 2014
Mechanical and optical response of [100] lithium fluoride to multi-megabar dynamic pressures journal October 2016
The National Ignition Facility: enabling fusion ignition for the 21st century journal November 2004
The National Ignition Facility: enabling fusion ignition for the 21st century journal November 2004
Electron correlation in semiconductors and insulators: Band gaps and quasiparticle energies journal October 1986
Electron-hole excitations and optical spectra from first principles journal August 2000
Ab initio calculations of the thermodynamic properties of LiF crystal journal January 2011
Influence of bonding on superconductivity in high-pressure hydrides journal August 2015
Ab initio many-body Green's function calculations of optical properties of LiF at high pressures journal December 2015
Melting of LiF and NaCl to 1 Mbar: Systematics of Ionic Solids at Extreme Conditions journal June 1997
Electron correlation in semiconductors and insulators: Band gaps and quasiparticle energies journal October 1986
Electron-hole excitations and optical spectra from first principles journal August 2000
Ab initio calculations of the thermodynamic properties of LiF crystal journal January 2011
Influence of bonding on superconductivity in high-pressure hydrides journal August 2015
Ab initio many-body Green's function calculations of optical properties of LiF at high pressures journal December 2015
Melting of LiF and NaCl to 1 Mbar: Systematics of Ionic Solids at Extreme Conditions journal June 1997
Dynamic Compression of Earth Materials journal March 1980
Insulator-metal transition in dense fluid deuterium journal August 2018
The Need for the National Ignition Facility journal December 1996
The Need for the National Ignition Facility journal December 1996
Influence of bonding on superconductivity in high-pressure hydrides text January 2015

Cited By (2)

Coordination changes in liquid tin under shock compression determined using in situ femtosecond x-ray diffraction journal December 2019
Path integral Monte Carlo and density functional molecular dynamics simulations of warm dense MgSiO 3 journal January 2020

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