The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis

Pichon, Delphine; Soleilhavoup, Michele; Morvan, Jennifer; Junor, Glen P.; Vives, Thomas; Crévisy, Christophe; Lavallo, Vincent; Campagne, Jean-Marc; Mauduit, Marc; Jazzar, Rodolphe; Bertrand, Guy

doi:10.1039/C9SC02810B

The debut of chiral cyclic (alkyl)(amino)carbenes (CAACs) in enantioselective catalysis

Journal Article · Wed Aug 21 00:00:00 EDT 2019 · Chemical Science

DOI:https://doi.org/10.1039/C9SC02810B· OSTI ID:1544593

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Ecole Nationale Supérieure de Chimie de Rennes, Univ Rennes, CNRS, F-35000 Rennes, France
UCSD–CNRS Joint Research Chemistry Laboratory (UMI 3555), University of California San Diego, La Jolla, USA
Institut Charles Gerhardt, UMR 5253 CNRS-UM2-UM1-ENSCM, 34296 Montpellier, France

Cyclic (alkyl)(amino)carbene (CAAC) metal complexes can also engage in asymmetric transformations, thereby expanding the toolbox of available chiral carbene ligands.

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Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); Alfred P. Sloan Foundation's University Centre for Exemplary Mentoring; National Science Foundation Graduate Research Fellowship Program; National Science Foundation

Grant/Contract Number:: SC0009376

OSTI ID:: 1544593

Journal Information:: Chemical Science, Journal Name: Chemical Science Journal Issue: 33 Vol. 10; ISSN 2041-6520; ISSN CSHCBM

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United Kingdom

Language:: English

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