Au-Doped Stable L1 0 Structured Platinum Cobalt Ordered Intermetallic Nanoparticle Catalysts for Enhanced Electrocatalysis

Kuttiyiel, Kurian A.; Kattel, Shyam; Cheng, Shaobo; Lee, Ji Hoon; Wu, Lijun; Zhu, Yimei; Park, Gu-Gon; Liu, Ping; Sasaki, Kotaro; Chen, Jingguang G.; Adzic, Radoslav R.

doi:10.1021/acsaem.8b00555

Title: Au-Doped Stable L1 ₀ Structured Platinum Cobalt Ordered Intermetallic Nanoparticle Catalysts for Enhanced Electrocatalysis

Journal Article · Wed Aug 01 00:00:00 EDT 2018 · ACS Applied Energy Materials

DOI:https://doi.org/10.1021/acsaem.8b00555· OSTI ID:1544237

Kuttiyiel, Kurian A. ^[1]; Kattel, Shyam ^[2]; Cheng, Shaobo ^[3]; Lee, Ji Hoon ^[4]; Wu, Lijun ^[4]; Zhu, Yimei ^[3];

^[5];

^[4];

^[4]; Chen, Jingguang G. ^[6]; Adzic, Radoslav R. ^[4]

Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Columbia Univ., New York, NY (United States). Dept. of Chemical Engineering
Columbia Univ., New York, NY (United States). Dept. of Chemical Engineering
Brookhaven National Lab. (BNL), Dept. of Condensed Matter Physics and Materials Science
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Korean Inst. of Energy Research, Daejeon (South Korea). Fuel Cell Lab.
Brookhaven National Lab. (BNL), Upton, NY (United States). Chemistry Dept.; Columbia Univ., New York , NY (United States). Dept. of Chemical Engineering

Bimetallic Pt₃Co alloys are the commercial electrocatalysts for the oxygen reduction reaction in a fuel cell, but their high Pt loading and durability are a concern. Working toward the goal of reducing the amount of Pt and simultaneously increasing the activity and stability of the catalyst, we describe two new structures of ordered intermetallics consisting of Pt₄Co₅ nanocatalyst protected by Au atoms. Varying the temperature for the formation of the intermetallics, two distinct PtCo structural characteristics were observed in the nanoparticles: one with a simple intermetallic structure and the other with an intermetallic structure core protected by a shell of Pt atoms. Finally, the improved electrocatalytic activity and durability are attributed to the atomically ordered structure of PtCo nanoparticles along with protective surface Au atoms as confirmed by density functional theory (DFT) calculations and experimental results.

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Research Organization:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: 20158520030830; SC0012704; FG02-13ER16381; AC02-05CH11231

OSTI ID:: 1544237

Journal Information:: ACS Applied Energy Materials, Vol. 1, Issue 8; ISSN 2574-0962

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 15 works

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References (41)

Materials for fuel-cell technologies Steele, Brian C. H.; Heinzel, Angelika Nature, Vol. 414, Issue 6861, p. 345-352 https://doi.org/10.1038/35104620	journal	November 2001
Just a Dream—or Future Reality? Gasteiger, Hubert A.; Marković, Nenad M Science, Vol. 324, Issue 5923, p. 48-49 https://doi.org/10.1126/science.1172083	journal	April 2009
Electrocatalyst approaches and challenges for automotive fuel cells Debe, Mark K. Nature, Vol. 486, Issue 7401 https://doi.org/10.1038/nature11115	journal	June 2012
A Polymer Electrolyte-Based Rechargeable Lithium/Oxygen Battery Abraham, K. M.; Jiang, Z. Journal of The Electrochemical Society, Vol. 143, Issue 1, p. 1-5 https://doi.org/10.1149/1.1836378	journal	January 1996
Building better batteries Armand, M.; Tarascon, J.-M. Nature, Vol. 451, Issue 7179, p. 652-657 https://doi.org/10.1038/451652a	journal	February 2008
Improved Oxygen Reduction Activity on Pt₃Ni(111) via Increased Surface Site Availability Stamenkovic, V. R.; Fowler, B.; Mun, B. S. Science, Vol. 315, Issue 5811, p. 493-497 https://doi.org/10.1126/science.1135941	journal	January 2007
Platinum Monolayer Electrocatalysts: Tunable Activity, Stability, and Self-Healing Properties Adzic, Radoslav R. Electrocatalysis, Vol. 3, Issue 3-4 https://doi.org/10.1007/s12678-012-0112-3	journal	September 2012
Lattice-strain control of the activity in dealloyed core–shell fuel cell catalysts Strasser, Peter; Koh, Shirlaine; Anniyev, Toyli Nature Chemistry, Vol. 2, Issue 6 https://doi.org/10.1038/nchem.623	journal	April 2010
Recent advances in platinum monolayer electrocatalysts for oxygen reduction reaction: Scale-up synthesis, structure and activity of Pt shells on Pd cores Sasaki, K.; Wang, J. X.; Naohara, H. Electrochimica Acta, Vol. 55, Issue 8 https://doi.org/10.1016/j.electacta.2009.11.106	journal	March 2010
Size-Dependent Morphology of Dealloyed Bimetallic Catalysts: Linking the Nano to the Macro Scale Oezaslan, Mehtap; Heggen, Marc; Strasser, Peter Journal of the American Chemical Society, Vol. 134, Issue 1 https://doi.org/10.1021/ja2088162	journal	December 2011
Platinum-based nanocages with subnanometer-thick walls and well-defined, controllable facets Zhang, L.; Roling, L. T.; Wang, X. Science, Vol. 349, Issue 6246 https://doi.org/10.1126/science.aab0801	journal	July 2015
Octahedral Pd@Pt _1.8 Ni Core–Shell Nanocrystals with Ultrathin PtNi Alloy Shells as Active Catalysts for Oxygen Reduction Reaction Zhao, Xu; Chen, Sheng; Fang, Zhicheng Journal of the American Chemical Society, Vol. 137, Issue 8 https://doi.org/10.1021/ja511596c	journal	February 2015
Supported Core@Shell Electrocatalysts for Fuel Cells: Close Encounter with Reality Hwang, Seung Jun; Yoo, Sung Jong; Shin, Jungho Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep01309	journal	February 2013
Structurally Ordered Pt ₃ Cr as Oxygen Reduction Electrocatalyst: Ordering Control and Origin of Enhanced Stability Cui, Zhiming; Chen, Hao; Zhou, Weidong Chemistry of Materials, Vol. 27, Issue 21 https://doi.org/10.1021/acs.chemmater.5b03912	journal	October 2015
Morphology and Activity Tuning of Cu ₃ Pt/C Ordered Intermetallic Nanoparticles by Selective Electrochemical Dealloying Wang, Deli; Yu, Yingchao; Zhu, Jing Nano Letters, Vol. 15, Issue 2 https://doi.org/10.1021/nl504597j	journal	January 2015
Structurally ordered intermetallic platinum–cobalt core–shell nanoparticles with enhanced activity and stability as oxygen reduction electrocatalysts Wang, Deli; Xin, Huolin L.; Hovden, Robert Nature Materials, Vol. 12, Issue 1, p. 81-87 https://doi.org/10.1038/nmat3458	journal	October 2012
Activity–stability relationships of ordered and disordered alloy phases of Pt3Co electrocatalysts for the oxygen reduction reaction (ORR) Koh, Shirlaine; Toney, Michael F.; Strasser, Peter Electrochimica Acta, Vol. 52, Issue 8 https://doi.org/10.1016/j.electacta.2006.08.039	journal	February 2007
The stability of Pt–M (M=first row transition metal) alloy catalysts and its effect on the activity in low temperature fuel cells Antolini, Ermete; Salgado, Jose R. C.; Gonzalez, Ernesto R. Journal of Power Sources, Vol. 160, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.03.006	journal	October 2006
Temperature Dependence of Oxygen Reduction Activity at Carbon-Supported Pt _X Co ( X = 1, 2, and 3) Alloy Catalysts Prepared by the Nanocapsule Method Yano, Hiroshi; Song, Jung Min; Uchida, Hiroyuki The Journal of Physical Chemistry C, Vol. 112, Issue 22 https://doi.org/10.1021/jp712025q	journal	May 2008
High-performance transition metal-doped Pt3Ni octahedra for oxygen reduction reaction Huang, X.; Zhao, Z.; Cao, L. Science, Vol. 348, Issue 6240 https://doi.org/10.1126/science.aaa8765	journal	June 2015
Combinatorial Density Functional Theory-Based Screening of Surface Alloys for the Oxygen Reduction Reaction Greeley, Jeff; Nørskov, Jens K. The Journal of Physical Chemistry C, Vol. 113, Issue 12 https://doi.org/10.1021/jp808945y	journal	March 2009
Enhancement of the oxygen reduction on nitride stabilized pt-M (M=Fe, Co, and Ni) core–shell nanoparticle electrocatalysts Kuttiyiel, Kurian A.; Choi, YongMan; Hwang, Sun-Mi Nano Energy, Vol. 13 https://doi.org/10.1016/j.nanoen.2015.03.007	journal	April 2015
Controlling the Catalytic Activity of Platinum-Monolayer Electrocatalysts for Oxygen Reduction with Different Substrates Zhang, Junliang; Vukmirovic, Miomir B.; Xu, Ye Angewandte Chemie International Edition, Vol. 44, Issue 14, p. 2132-2135 https://doi.org/10.1002/anie.200462335	journal	March 2005
Platinum-Based Electrocatalysts with Core-Shell Nanostructures Yang, Hong Angewandte Chemie International Edition, Vol. 50, Issue 12 https://doi.org/10.1002/anie.201005868	journal	February 2011
Gold-promoted structurally ordered intermetallic palladium cobalt nanoparticles for the oxygen reduction reaction Kuttiyiel, Kurian A.; Sasaki, Kotaro; Su, Dong Nature Communications, Vol. 5, Article No. 5185 https://doi.org/10.1038/ncomms6185	journal	November 2014
Recent Advances in Electrocatalysts for Oxygen Reduction Reaction Shao, Minhua; Chang, Qiaowan; Dodelet, Jean-Pol Chemical Reviews, Vol. 116, Issue 6 https://doi.org/10.1021/acs.chemrev.5b00462	journal	February 2016
Effect of the chemical order on the electrocatalytic activity of model PtCo electrodes in the oxygen reduction reaction Lebedeva, Marina V.; Pierron-Bohnes, Veronique; Goyhenex, Christine Electrochimica Acta, Vol. 108 https://doi.org/10.1016/j.electacta.2013.07.038	journal	October 2013
Self-Organized Superlattices of Nanoparticles Weller, Horst Angewandte Chemie International Edition in English, Vol. 35, Issue 10 https://doi.org/10.1002/anie.199610791	journal	June 1996
Influence of atomic ordering on the electrocatalytic activity of Pt–Co alloys in alkaline electrolyte and proton exchange membrane fuel cells Xiong, Liufeng; Manthiram, Arumugam J. Mater. Chem., Vol. 14, Issue 9 https://doi.org/10.1039/B400968C	journal	January 2004
X-Ray absorption spectroscopic and electrochemical analyses of Pt–Cu–Fe ternary alloy electrocatalysts supported on carbon Cho, Jihoon; Roh, Whanjin; Kim, Dong-Kuk Journal of the Chemical Society, Faraday Transactions, Vol. 94, Issue 18 https://doi.org/10.1039/a802042f	journal	January 1998
Design and Synthesis of Bimetallic Electrocatalyst with Multilayered Pt-Skin Surfaces Wang, Chao; Chi, Miaofang; Li, Dongguo Journal of the American Chemical Society, Vol. 133, Issue 36, p. 14396-14403 https://doi.org/10.1021/ja2047655	journal	September 2011
How a gold substrate can increase the reactivity of a Pt overlayer Pedersen, M. Ø.; Helveg, S.; Ruban, A. Surface Science, Vol. 426, Issue 3 https://doi.org/10.1016/S0039-6028(99)00385-4	journal	May 1999
The origin of high activity of Pt–Au surfaces in the formic acid oxidation Obradović, Maja D.; Tripković, Amalija V.; Gojković, Snežana Lj. Electrochimica Acta, Vol. 55, Issue 1 https://doi.org/10.1016/j.electacta.2009.08.038	journal	December 2009
Electrooxidation of Carbon Monoxide and Methanol on Platinum-Overlayer-Coated Gold Nanoparticles: Effects of Film Thickness Kumar, Sachin; Zou, Shouzhong Langmuir, Vol. 23, Issue 13 https://doi.org/10.1021/la0637216	journal	June 2007
Stabilization of Platinum Oxygen-Reduction Electrocatalysts Using Gold Clusters Zhang, J.; Sasaki, K.; Sutter, E. Science, Vol. 315, Issue 5809, p. 220-222 https://doi.org/10.1126/science.1134569	journal	January 2007
Unifying Kinetic and Thermodynamic Analysis of 2 e ^– and 4 e ^– Reduction of Oxygen on Metal Surfaces Hansen, Heine A.; Viswanathan, Venkatasubramanian; Nørskov, Jens K. The Journal of Physical Chemistry C, Vol. 118, Issue 13 https://doi.org/10.1021/jp4100608	journal	March 2014
Alloys of platinum and early transition metals as oxygen reduction electrocatalysts Greeley, J.; Stephens, I. E. L.; Bondarenko, A. S. Nature Chemistry, Vol. 1, Issue 7, p. 552-556 https://doi.org/10.1038/nchem.367	journal	September 2009
Optimum nanoparticles for electrocatalytic oxygen reduction: the size, shape and new design Wei, Guang-Feng; Liu, Zhi-Pan Physical Chemistry Chemical Physics, Vol. 15, Issue 42 https://doi.org/10.1039/c3cp53758g	journal	January 2013
Rationalization of Au Concentration and Distribution in AuNi@Pt Core–Shell Nanoparticles for Oxygen Reduction Reaction An, Wei; Liu, Ping ACS Catalysis, Vol. 5, Issue 11 https://doi.org/10.1021/acscatal.5b01656	journal	September 2015
Pt monolayer on Au-stabilized PdNi core–shell nanoparticles for oxygen reduction reaction Kuttiyiel, Kurian A.; Sasaki, Kotaro; Su, Dong Electrochimica Acta, Vol. 110 https://doi.org/10.1016/j.electacta.2013.04.037	journal	November 2013
Highly stable Pt monolayer on PdAu nanoparticle electrocatalysts for the oxygen reduction reaction Sasaki, Kotaro; Naohara, Hideo; Choi, YongMan Nature Communications, Vol. 3, Issue 1 https://doi.org/10.1038/ncomms2124	journal	January 2012

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Title: Au-Doped Stable L1 0 Structured Platinum Cobalt Ordered Intermetallic Nanoparticle Catalysts for Enhanced Electrocatalysis

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