Iodine immobilization by silver-impregnated granular activated carbon in cementitious systems
- Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Lab. (SRNL)
- Univ. of Georgia, Aiken, SC (United States)
- Texas A & M Univ., Galveston, TX (United States)
Silver (Ag)-based technologies are amongst the most common approaches to removing radioiodine from aqueous waste streams. As a result, a large worldwide inventory of radioactive AgI waste presently exits, which must be stabilized for final disposition. In this work, the efficacy of silver-impregnated granular activated carbon (Ag-GAC) to remove iodide (I-), iodate (IO3-) and organo-iodine (org-I) from cementitious leachate was examined. In addition, cementitious materials containing I-, IO3-, or org-I loaded Ag-GAC were characterized by iodine K-edge XANES and EXAFS to provide insight into iodine stability and speciation in these waste forms. The Ag-GAC was very effective at removing I- and org-I, but ineffective at removing IO3- from slag-free grout leachate under oxic conditions. I- or org-I removal was due to the formation of insoluble AgI(s) or Ag-org-I(s) on the Ag-GAC. When I--loaded Ag-GAC material was cured with slag-free and slag grouts, I- was released from AgI(s) to form a hydrated I- species. Conversely, when org-I loaded Ag-GAC material was cured in the two grout formulations, no change was observed in the iodine speciation, indicating the org-I species remained bound to the Ag. Because little IO3- was bound to the Ag-GAC, it was not detectable in the grout. Thus, grout formulation and I speciation in the waste stream can significantly influence the effectiveness of the long-term disposal of radioiodine associated with Ag-GAC in grout waste forms.
- Research Organization:
- Savannah River Site (SRS), Aiken, SC (United States). Savannah River National Laboratory (SRNL)
- Sponsoring Organization:
- USDOE Office of Environmental Management (EM)
- Grant/Contract Number:
- AC09-08SR22470; LDRD-2017-00005; EM0004381; AC09-96SR18500; AC02-06CH11357; DEFC09-07-SR22506
- OSTI ID:
- 1561205
- Alternate ID(s):
- OSTI ID: 1543052
- Report Number(s):
- SRNL-STI-2019-00137; TRN: US2000602
- Journal Information:
- Journal of Environmental Radioactivity, Vol. 208-209, Issue C; ISSN 0265-931X
- Publisher:
- ElsevierCopyright Statement
- Country of Publication:
- United States
- Language:
- English
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