Strongly Coupled Phenazine–Porphyrin Dyads: Light-Harvesting Molecular Assemblies with Broad Absorption Coverage

Lee, Shin Hee; Matula, Adam J.; Hu, Gongfang; Troiano, Jennifer L.; Karpovich, Christopher J.; Crabtree, Robert H.; Batista, Victor S.; Brudvig, Gary W.

doi:10.1021/acsami.8b20996

Title: Strongly Coupled Phenazine–Porphyrin Dyads: Light-Harvesting Molecular Assemblies with Broad Absorption Coverage

Journal Article · Wed Jan 30 00:00:00 EST 2019 · ACS Applied Materials and Interfaces

DOI:https://doi.org/10.1021/acsami.8b20996· OSTI ID:1542274

Lee, Shin Hee ^[1];

^[1];

^[1]; Troiano, Jennifer L. ^[1]; Karpovich, Christopher J. ^[1];

^[1];

^[1]

Yale Univ., New Haven, CT (United States). Dept. of Chemistry and Yale Energy Sciences Inst.

The development of light-harvesting architectures with broad absorption coverage in the visible region continues to be an important research area in the field of artificial photosynthesis. In this work, we introduce a new class of ethynyl-linked panchromatic dyads composed of dibenzophenazines coupled ortho and meta to tetrapyrroles with an anchoring group that can be grafted onto metal oxide surfaces. Quantum chemical calculations and photophysical measurements of the synthesized materials reveal that both of the dibenzophenazine dyads absorb broadly from 300 to 636 nm and exhibit absorption bands different from those of the constituent chromophore units. Moreover, the different points of attachment of dibenzophenazines to tetrapyrroles give different absorption profiles which computations suggest result from differences in the planarity of the two dyads. Applicability of the dyads in artificial photosynthesis systems was assessed by their incorporation and characterization of their performance in dye-sensitized solar cells.

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Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States). National Energy Research Scientific Computing Center (NERSC)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: FG02-07ER15909

OSTI ID:: 1542274

Journal Information:: ACS Applied Materials and Interfaces, Vol. 11, Issue 8; ISSN 1944-8244

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 28 works

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36 MATERIALS SCIENCE
panchromatic dyes
dyads
phenazines
porphyrins
artificial photosynthesis

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