skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids

Abstract

Mesogeometric anatomy – 2D inter-material surfaces and 1D skeletons – extracted from triply-periodic, double-gyroid network assembled from triblock copolymers.

Authors:
 [1];  [2];  [3];  [4]; ORCiD logo [5]
  1. Department of Chemical Engineering; University of Massachusetts; Amherst; USA
  2. Institute of Multidisciplinary Research for Advanced Materials (IMRAM); Tohoku University; Sendai; Japan
  3. Department of Chemical Engineering; National Tsing Hua University; Hsinchu 30013; Taiwan
  4. Department of Material Science and Nano Engineering; Rice University; Houston; USA
  5. Department of Polymer Science and Engineering; University of Massachusetts; Amherst; USA
Publication Date:
Research Org.:
Univ. of Massachusetts, Amherst, MA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1540080
DOE Contract Number:  
SC0014549
Resource Type:
Journal Article
Journal Name:
Soft Matter
Additional Journal Information:
Journal Volume: 14; Journal Issue: 18; Journal ID: ISSN 1744-683X
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Materials Science; Physics; Polymer Science

Citation Formats

Prasad, Ishan, Jinnai, Hiroshi, Ho, Rong-Ming, Thomas, Edwin L., and Grason, Gregory M. Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids. United States: N. p., 2018. Web. doi:10.1039/c8sm00078f.
Prasad, Ishan, Jinnai, Hiroshi, Ho, Rong-Ming, Thomas, Edwin L., & Grason, Gregory M. Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids. United States. https://doi.org/10.1039/c8sm00078f
Prasad, Ishan, Jinnai, Hiroshi, Ho, Rong-Ming, Thomas, Edwin L., and Grason, Gregory M. Mon . "Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids". United States. https://doi.org/10.1039/c8sm00078f.
@article{osti_1540080,
title = {Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids},
author = {Prasad, Ishan and Jinnai, Hiroshi and Ho, Rong-Ming and Thomas, Edwin L. and Grason, Gregory M.},
abstractNote = {Mesogeometric anatomy – 2D inter-material surfaces and 1D skeletons – extracted from triply-periodic, double-gyroid network assembled from triblock copolymers.},
doi = {10.1039/c8sm00078f},
url = {https://www.osti.gov/biblio/1540080}, journal = {Soft Matter},
issn = {1744-683X},
number = 18,
volume = 14,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

Structure of the Cubic Phases of Lipid–Water Systems
journal, November 1968


Equilibrium bicontinuous structure
journal, September 1976


A triple-network tricontinuous cubicliquid crystal
journal, June 2005


Geometry of interfaces: topological complexity in biology and materials
journal, February 2012


Network Phases in ABC Triblock Copolymers
journal, September 2004


Unusually Stable Aqueous Lyotropic Gyroid Phases from Gemini Dicarboxylate Surfactants
journal, September 2011


Polycontinuous geometries for inverse lipid phases with more than two aqueous network domains
journal, January 2013


Development of Aromatic Polymer Electrolyte Membrane with High Conductivity and Durability for Fuel Cell
journal, January 2009


Photonic properties of bicontinuous cubic microphases
journal, April 2002


Bicontinuous Cubic Block Copolymer Photonic Crystals
journal, December 2002


Photonic band gaps in materials with triply periodic surfaces and related tubular structures
journal, September 2003


Structure, function, and self-assembly of single network gyroid (I4132) photonic crystals in butterfly wing scales
journal, June 2010


A 3D Optical Metamaterial Made by Self-Assembly
journal, October 2011


Tunable 3D Extended Self-Assembled Gold Metamaterials with Enhanced Light Transmission
journal, April 2013


Circular Dichroism in Biological Photonic Crystals and Cubic Chiral Nets
journal, March 2011


On the Origin of Chirality in Nanoplasmonic Gyroid Metamaterials
journal, October 2012


Chiral metamaterials: enhancement and control of optical activity and circular dichroism
journal, November 2015


Three-Dimensionally Isotropic Negative Refractive Index Materials from Block Copolymer Self-Assembled Chiral Gyroid Networks
journal, October 2011


25th Anniversary Article: Ordered Polymer Structures for the Engineering of Photons and Phonons
journal, December 2013


Optical Properties of Gyroid Structured Materials: From Photonic Crystals to Metamaterials
journal, November 2014


Direct Measurement of Interfacial Curvature Distributions in a Bicontinuous Block Copolymer Morphology
journal, January 2000


Network Phases in Block Copolymer Melts
journal, July 2005


The Gyroid: A New Equilibrium Morphology in Weakly Segregated Diblock Copolymers
journal, July 1994


Cubic phases in surfactant and surfactant-like lipid systems
journal, March 1990


Novel surfactant mesostructural topologies: between lamellae and columnar (hexagonal) forms
journal, March 2003


Giant surfactants provide a versatile platform for sub-10-nm nanostructure engineering
journal, May 2013


The chiral structure of porous chitin within the wing-scales of Callophrys rubi
journal, May 2011


Gyroid cuticular structures in butterfly wing scales: biological photonic crystals
journal, June 2007


Triply periodic minimal and constant mean curvature surfaces
journal, February 2012


Periodic area-minimizing surfaces in block copolymers
journal, August 1988


Quantifying Packing Frustration Energy in Inverse Lyotropic Mesophases
journal, January 1997


Medial surfaces of hyperbolic structures
journal, October 2003


Absence of Circular Polarisation in Reflections of Butterfly Wing Scales with Chiral Gyroid Structure
journal, January 2014


Coexistence of both gyroid chiralities in individual butterfly wing scales of Callophrys rubi
journal, October 2015


Two-dimensional superconductivity at the interface of a Bi2Te3/FeTe heterostructure
journal, June 2014


Broadly Accessible Self-Consistent Field Theory for Block Polymer Materials Discovery
journal, June 2016


Transmission electron microtomography in polymer research
journal, February 2009


Phase Behavior of Ordered Diblock Copolymer Blends:  Effect of Compositional Heterogeneity
journal, January 1996


Toward Fully Automated High-Resolution Electron Tomography
journal, January 1996


Gyroids of Constant Mean Curvature
journal, January 1997


On Gyroid Interfaces
journal, March 1997


Phase contrast imaging of styrene-isoprene and styrene-butadiene block copolymers
journal, September 1983


Volume Organization of Polymer and Hybrid Solar Cells as Revealed by Electron Tomography
journal, September 2010


Molecular chirality and chiral parameters
journal, October 1999


Block copolymer microstructures in the intermediate-segregation regime
journal, February 1997


On swelling and structure of composite materials. Some theory and applications of lyotropic mesophases
journal, October 1995


Curvature Determination of Spinodal Interface in a Condensed Matter System
journal, March 1997


3D Architecture of Trabecular Bone in the Pig Mandible and Femur: Inter-Trabecular Angle Distributions
journal, September 2017


Orthorhombic F d d d Network in Triblock and Diblock Copolymer Melts
journal, May 2005


    Works referencing / citing this record:

    Seeing mesoatomic distortions in soft-matter crystals of a double-gyroid block copolymer
    journal, October 2019


    Double diamond phase in pear-shaped nanoparticle systems with hard sphere solvent
    journal, October 2018