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Title: Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids

Abstract

Mesogeometric anatomy – 2D inter-material surfaces and 1D skeletons – extracted from triply-periodic, double-gyroid network assembled from triblock copolymers.

Authors:
 [1];  [2];  [3];  [4]; ORCiD logo [5]
  1. Department of Chemical Engineering; University of Massachusetts; Amherst; USA
  2. Institute of Multidisciplinary Research for Advanced Materials (IMRAM); Tohoku University; Sendai; Japan
  3. Department of Chemical Engineering; National Tsing Hua University; Hsinchu 30013; Taiwan
  4. Department of Material Science and Nano Engineering; Rice University; Houston; USA
  5. Department of Polymer Science and Engineering; University of Massachusetts; Amherst; USA
Publication Date:
Research Org.:
Univ. of Massachusetts, Amherst, MA (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1540080
DOE Contract Number:  
SC0014549
Resource Type:
Journal Article
Journal Name:
Soft Matter
Additional Journal Information:
Journal Volume: 14; Journal Issue: 18; Journal ID: ISSN 1744-683X
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Materials Science; Physics; Polymer Science

Citation Formats

Prasad, Ishan, Jinnai, Hiroshi, Ho, Rong-Ming, Thomas, Edwin L., and Grason, Gregory M. Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids. United States: N. p., 2018. Web. doi:10.1039/c8sm00078f.
Prasad, Ishan, Jinnai, Hiroshi, Ho, Rong-Ming, Thomas, Edwin L., & Grason, Gregory M. Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids. United States. doi:10.1039/c8sm00078f.
Prasad, Ishan, Jinnai, Hiroshi, Ho, Rong-Ming, Thomas, Edwin L., and Grason, Gregory M. Mon . "Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids". United States. doi:10.1039/c8sm00078f.
@article{osti_1540080,
title = {Anatomy of triply-periodic network assemblies: characterizing skeletal and inter-domain surface geometry of block copolymer gyroids},
author = {Prasad, Ishan and Jinnai, Hiroshi and Ho, Rong-Ming and Thomas, Edwin L. and Grason, Gregory M.},
abstractNote = {Mesogeometric anatomy – 2D inter-material surfaces and 1D skeletons – extracted from triply-periodic, double-gyroid network assembled from triblock copolymers.},
doi = {10.1039/c8sm00078f},
journal = {Soft Matter},
issn = {1744-683X},
number = 18,
volume = 14,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

Structure of the Cubic Phases of Lipid–Water Systems
journal, November 1968

  • Luzzati, Vittorio; Tardieu, A.; Gulik-Krzywicki, T.
  • Nature, Vol. 220, Issue 5166
  • DOI: 10.1038/220485a0

Equilibrium bicontinuous structure
journal, September 1976


A triple-network tricontinuous cubicliquid crystal
journal, June 2005

  • Zeng, Xiangbing; Ungar, Goran; Impéror-Clerc, Marianne
  • Nature Materials, Vol. 4, Issue 7
  • DOI: 10.1038/nmat1413

Geometry of interfaces: topological complexity in biology and materials
journal, February 2012


Network Phases in ABC Triblock Copolymers
journal, September 2004

  • Epps, Thomas H.; Cochran, Eric W.; Hardy, Cordell M.
  • Macromolecules, Vol. 37, Issue 19
  • DOI: 10.1021/ma0493426

Unusually Stable Aqueous Lyotropic Gyroid Phases from Gemini Dicarboxylate Surfactants
journal, September 2011

  • Sorenson, Gregory P.; Coppage, Keiva L.; Mahanthappa, Mahesh K.
  • Journal of the American Chemical Society, Vol. 133, Issue 38
  • DOI: 10.1021/ja2063555

Polycontinuous geometries for inverse lipid phases with more than two aqueous network domains
journal, January 2013

  • Schröder-Turk, Gerd E.; de Campo, Liliana; Evans, Myfanwy E.
  • Faraday Discuss., Vol. 161
  • DOI: 10.1039/C2FD20112G

Development of Aromatic Polymer Electrolyte Membrane with High Conductivity and Durability for Fuel Cell
journal, January 2009


Photonic properties of bicontinuous cubic microphases
journal, April 2002


Bicontinuous Cubic Block Copolymer Photonic Crystals
journal, December 2002


Photonic band gaps in materials with triply periodic surfaces and related tubular structures
journal, September 2003


Structure, function, and self-assembly of single network gyroid (I4132) photonic crystals in butterfly wing scales
journal, June 2010

  • Saranathan, V.; Osuji, C. O.; Mochrie, S. G. J.
  • Proceedings of the National Academy of Sciences, Vol. 107, Issue 26
  • DOI: 10.1073/pnas.0909616107

A 3D Optical Metamaterial Made by Self-Assembly
journal, October 2011

  • Vignolini, Silvia; Yufa, Nataliya A.; Cunha, Pedro S.
  • Advanced Materials, Vol. 24, Issue 10
  • DOI: 10.1002/adma.201103610

Tunable 3D Extended Self-Assembled Gold Metamaterials with Enhanced Light Transmission
journal, April 2013

  • Salvatore, Stefano; Demetriadou, Angela; Vignolini, Silvia
  • Advanced Materials, Vol. 25, Issue 19
  • DOI: 10.1002/adma.201300193

Circular Dichroism in Biological Photonic Crystals and Cubic Chiral Nets
journal, March 2011


On the Origin of Chirality in Nanoplasmonic Gyroid Metamaterials
journal, October 2012

  • Oh, Sang Soon; Demetriadou, Angela; Wuestner, Sebastian
  • Advanced Materials, Vol. 25, Issue 4
  • DOI: 10.1002/adma.201202788

Chiral metamaterials: enhancement and control of optical activity and circular dichroism
journal, November 2015


Three-Dimensionally Isotropic Negative Refractive Index Materials from Block Copolymer Self-Assembled Chiral Gyroid Networks
journal, October 2011

  • Hur, Kahyun; Francescato, Yan; Giannini, Vincenzo
  • Angewandte Chemie International Edition, Vol. 50, Issue 50
  • DOI: 10.1002/anie.201104888

25th Anniversary Article: Ordered Polymer Structures for the Engineering of Photons and Phonons
journal, December 2013

  • Lee, Jae-Hwang; Koh, Cheong Yang; Singer, Jonathan P.
  • Advanced Materials, Vol. 26, Issue 4
  • DOI: 10.1002/adma.201303456

Optical Properties of Gyroid Structured Materials: From Photonic Crystals to Metamaterials
journal, November 2014

  • Dolan, James A.; Wilts, Bodo D.; Vignolini, Silvia
  • Advanced Optical Materials, Vol. 3, Issue 1
  • DOI: 10.1002/adom.201400333

Direct Measurement of Interfacial Curvature Distributions in a Bicontinuous Block Copolymer Morphology
journal, January 2000

  • Jinnai, Hiroshi; Nishikawa, Yukihiro; Spontak, Richard J.
  • Physical Review Letters, Vol. 84, Issue 3
  • DOI: 10.1103/PhysRevLett.84.518

Network Phases in Block Copolymer Melts
journal, July 2005


The Gyroid: A New Equilibrium Morphology in Weakly Segregated Diblock Copolymers
journal, July 1994

  • Hajduk, Damian A.; Harper, Paul E.; Gruner, Sol M.
  • Macromolecules, Vol. 27, Issue 15
  • DOI: 10.1021/ma00093a006

Cubic phases in surfactant and surfactant-like lipid systems
journal, March 1990


Novel surfactant mesostructural topologies: between lamellae and columnar (hexagonal) forms
journal, March 2003


Giant surfactants provide a versatile platform for sub-10-nm nanostructure engineering
journal, May 2013

  • Yu, X.; Yue, K.; Hsieh, I. -F.
  • Proceedings of the National Academy of Sciences, Vol. 110, Issue 25
  • DOI: 10.1073/pnas.1302606110

The chiral structure of porous chitin within the wing-scales of Callophrys rubi
journal, May 2011

  • Schröder-Turk, G. E.; Wickham, S.; Averdunk, H.
  • Journal of Structural Biology, Vol. 174, Issue 2
  • DOI: 10.1016/j.jsb.2011.01.004

Gyroid cuticular structures in butterfly wing scales: biological photonic crystals
journal, June 2007

  • Michielsen, K.; Stavenga, D. G.
  • Journal of The Royal Society Interface, Vol. 5, Issue 18
  • DOI: 10.1098/rsif.2007.1065

Triply periodic minimal and constant mean curvature surfaces
journal, February 2012


Periodic area-minimizing surfaces in block copolymers
journal, August 1988

  • Thomas, Edwin L.; Anderson, David M.; Henkee, Chris S.
  • Nature, Vol. 334, Issue 6183
  • DOI: 10.1038/334598a0

Quantifying Packing Frustration Energy in Inverse Lyotropic Mesophases
journal, January 1997

  • Duesing, P. M.; Templer, R. H.; Seddon, J. M.
  • Langmuir, Vol. 13, Issue 2
  • DOI: 10.1021/la960602p

Medial surfaces of hyperbolic structures
journal, October 2003

  • Schr�der, G. E.; Ramsden, S. J.; Christy, A. G.
  • The European Physical Journal B - Condensed Matter, Vol. 35, Issue 4
  • DOI: 10.1140/epjb/e2003-00308-y

Absence of Circular Polarisation in Reflections of Butterfly Wing Scales with Chiral Gyroid Structure
journal, January 2014


Coexistence of both gyroid chiralities in individual butterfly wing scales of Callophrys rubi
journal, October 2015

  • Winter, Benjamin; Butz, Benjamin; Dieker, Christel
  • Proceedings of the National Academy of Sciences, Vol. 112, Issue 42
  • DOI: 10.1073/pnas.1511354112

Two-dimensional superconductivity at the interface of a Bi2Te3/FeTe heterostructure
journal, June 2014

  • He, Qing Lin; Liu, Hongchao; He, Mingquan
  • Nature Communications, Vol. 5, Issue 1
  • DOI: 10.1038/ncomms5247

Broadly Accessible Self-Consistent Field Theory for Block Polymer Materials Discovery
journal, June 2016


Transmission electron microtomography in polymer research
journal, February 2009


Phase Behavior of Ordered Diblock Copolymer Blends:  Effect of Compositional Heterogeneity
journal, January 1996

  • Spontak, Richard J.; Fung, Jennifer C.; Braunfeld, Michael B.
  • Macromolecules, Vol. 29, Issue 13
  • DOI: 10.1021/ma9515689

Toward Fully Automated High-Resolution Electron Tomography
journal, January 1996

  • Fung, Jennifer C.; Liu, Weiping; de Ruijter, W. J.
  • Journal of Structural Biology, Vol. 116, Issue 1
  • DOI: 10.1006/jsbi.1996.0029

Gyroids of Constant Mean Curvature
journal, January 1997


On Gyroid Interfaces
journal, March 1997

  • Grosse-Brauckmann, Karsten
  • Journal of Colloid and Interface Science, Vol. 187, Issue 2
  • DOI: 10.1006/jcis.1996.4720

Phase contrast imaging of styrene-isoprene and styrene-butadiene block copolymers
journal, September 1983


Volume Organization of Polymer and Hybrid Solar Cells as Revealed by Electron Tomography
journal, September 2010

  • van Bavel, Svetlana S.; Loos, Joachim
  • Advanced Functional Materials, Vol. 20, Issue 19
  • DOI: 10.1002/adfm.201000745

Molecular chirality and chiral parameters
journal, October 1999


Block copolymer microstructures in the intermediate-segregation regime
journal, February 1997

  • Matsen, M. W.; Bates, F. S.
  • The Journal of Chemical Physics, Vol. 106, Issue 6
  • DOI: 10.1063/1.473153

On swelling and structure of composite materials. Some theory and applications of lyotropic mesophases
journal, October 1995


Curvature Determination of Spinodal Interface in a Condensed Matter System
journal, March 1997


3D Architecture of Trabecular Bone in the Pig Mandible and Femur: Inter-Trabecular Angle Distributions
journal, September 2017


Orthorhombic F d d d Network in Triblock and Diblock Copolymer Melts
journal, May 2005


Connectivity and topology of a phase-separating bicontinuous structure in a polymer mixture: Direct measurements of coordination number, inter-junction distances and Euler characteristic
journal, October 2003

  • Jinnai, Hiroshi; Watashiba, Hideyuki; Kajihara, Takashi
  • The Journal of Chemical Physics, Vol. 119, Issue 14
  • DOI: 10.1063/1.1607912