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Vertical Co 9 S 8 hollow nanowall arrays grown on a Celgard separator as a multifunctional polysulfide barrier for high-performance Li–S batteries

Journal Article · · Energy & Environmental Science
DOI:https://doi.org/10.1039/c8ee00893k· OSTI ID:1540040
 [1];  [2];  [3]
  1. Materials Science and Engineering Program & Texas Materials Institute; The University of Texas at Austin; Austin; USA; State Key Laboratory of Electronic Thin Films and Integrated Devices; DOE/OSTI
  2. State Key Laboratory of Electronic Thin Films and Integrated Devices; University of Electronic Science and Technology of China; Chengdu 610054; P. R. China
  3. Materials Science and Engineering Program & Texas Materials Institute; The University of Texas at Austin; Austin; USA

Lithium–sulfur (Li–S) batteries have been regarded as one of the most promising next-generation energy-storage devices, due to their low cost and high theoretical energy density (2600 W h kg-1).

Research Organization:
Univ. of Texas, Austin, TX (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0005397
OSTI ID:
1540040
Journal Information:
Energy & Environmental Science, Journal Name: Energy & Environmental Science Journal Issue: 9 Vol. 11; ISSN EESNBY; ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

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Metal–organic framework-based separator for lithium–sulfur batteries journal June 2016
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Lithium–sulphur batteries with a microporous carbon paper as a bifunctional interlayer journal January 2012
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Emerging Functional Porous Polymeric and Carbonaceous Materials for Environmental Treatment and Energy Storage journal November 2019
A new high-capacity and safe energy storage system: lithium-ion sulfur batteries journal January 2019
A soluble single atom catalyst promotes lithium polysulfide conversion in lithium sulfur batteries journal January 2019
Metal-based nanostructured materials for advanced lithium–sulfur batteries journal January 2018
Metal‐Organic Framework‐Templated Hollow Co 3 O 4 /C with Controllable Oxygen Vacancies for Efficient Oxygen Evolution Reaction journal October 2019
Boosting High‐Rate Li–S Batteries by an MOF‐Derived Catalytic Electrode with a Layer‐by‐Layer Structure journal June 2019
A Game Changer: Functional Nano/Micromaterials for Smart Rechargeable Batteries journal August 2019
Lithium bis(trifluoromethanesulfonyl)imide assisted dual-functional separator coating materials based on covalent organic frameworks for high-performance lithium–selenium sulfide batteries journal January 2019
Freestanding 1T MoS 2 /graphene heterostructures as a highly efficient electrocatalyst for lithium polysulfides in Li–S batteries journal January 2019
Compactly Coupled Nitrogen‐Doped Carbon Nanosheets/Molybdenum Phosphide Nanocrystal Hollow Nanospheres as Polysulfide Reservoirs for High‐Performance Lithium–Sulfur Chemistry journal August 2019
Nanosized ReS 2 Monolayers Embedded in Nitrogen‐Doped Carbon Nanotubes for High‐Rate Capacitive Lithium Storage journal February 2019
Multifunctional hollow spheres as sulfur hosts for high-performance Li–S batteries journal December 2019
ZnS spheres wrapped by an ultrathin wrinkled carbon film as a multifunctional interlayer for long-life Li–S batteries journal January 2020
Improvement of the electrochemical performance of a nickel rich LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode material by reduced graphene oxide/SiO 2 nanoparticle double-layer coating journal January 2019
Developing A “Polysulfide‐Phobic” Strategy to Restrain Shuttle Effect in Lithium–Sulfur Batteries journal July 2019
MXene-engineered lithium–sulfur batteries journal January 2019
Lignin Nanoparticle-Coated Celgard Separator for High-Performance Lithium–Sulfur Batteries journal November 2019
Strong charge polarization effect enabled by surface oxidized titanium nitride for lithium-sulfur batteries journal June 2019
Single Nickel Atoms on Nitrogen‐Doped Graphene Enabling Enhanced Kinetics of Lithium–Sulfur Batteries journal August 2019
Bifunctional CdS@Co 9 S 8 /Ni 3 S 2 catalyst for efficient electrocatalytic and photo-assisted electrocatalytic overall water splitting journal January 2020
Rational design of NiFe 2 O 4 –rGO by tuning the compositional chemistry and its enhanced performance for a Li-ion battery anode journal January 2019
Flexible and High‐Loading Lithium–Sulfur Batteries Enabled by Integrated Three‐In‐One Fibrous Membranes journal August 2019
Mo 2 C Nanodots Anchored on N-Doped Porous CNT Microspheres as Electrode for Efficient Li-Ion Storage journal October 2018
Battery Separators Functionalized with Edge-Rich MoS2/C Hollow Microspheres for the Uniform Deposition of Li2S in High-Performance Lithium–Sulfur Batteries journal May 2019
Electrocatalysis of polysulfide conversion via sulfur–cobalt CoS2 on a carbon nanotube surface as a cathode for high-performance lithium–sulfur batteries journal June 2019
MnO 2 -Coated Sulfur-Filled Hollow Carbon Nanosphere-Based Cathode Materials for Enhancing Electrochemical Performance of Li-S Cells journal January 2019
Carbon nanotubes/SiC prepared by catalytic chemical vapor deposition as scaffold for improved lithium-sulfur batteries journal May 2019
sp–sp 2 hybrid-conjugated microporous polymer-derived Pd-encapsulated porous carbon materials for lithium–sulfur batteries journal January 2019
Revisiting the positive roles of liquid polysulfides in alkali metal–sulfur electrochemistry: from electrolyte additives to active catholyte journal January 2019
Metal–organic frameworks for lithium–sulfur batteries journal January 2019
Ni 1‐x Co x O y , Ni 1‐x Co x S y and Ni 1‐x Co x P y Catalysts Prepared from Ni 1‐x Co x ‐ZIF‐67 for Hydrogen Production by Electrolysis in Alkaline Media journal September 2019
Developing A “Polysulfide‐Phobic” Strategy to Restrain Shuttle Effect in Lithium–Sulfur Batteries journal July 2019
Simultaneous Cobalt and Phosphorous Doping of MoS 2 for Improved Catalytic Performance on Polysulfide Conversion in Lithium–Sulfur Batteries journal August 2019
Metal Sulfide‐Decorated Carbon Sponge as a Highly Efficient Electrocatalyst and Absorbant for Polysulfide in High‐Loading Li 2 S Batteries journal April 2019
Electrospinning of Metal–Organic Frameworks for Energy and Environmental Applications journal December 2019
Chelation-assisted formation of multi-yolk–shell Co 4 N@carbon nanoboxes for self-discharge-suppressed high-performance Li–SeS 2 batteries journal January 2019
Self-supported hierarchical core–shell Co 9 S 8 @NiCo 2 O 4 hollow nanoneedle arrays for asymmetric supercapacitors journal January 2019
Frogspawn inspired hollow Fe 3 C@N–C as an efficient sulfur host for high-rate lithium–sulfur batteries journal January 2019
Accelerated Li–S chemistry at a cooperative interface built in situ journal January 2019
Sulfur-deficient MoS 2 grown inside hollow mesoporous carbon as a functional polysulfide mediator journal January 2019
Three‐Dimensional Hierarchical Constructs of MOF‐on‐Reduced Graphene Oxide for Lithium–Sulfur Batteries journal July 2019
A Multifunctional Separator Enables Safe and Durable Lithium/Magnesium–Sulfur Batteries under Elevated Temperature journal December 2019
Current Status and Future Prospects of Metal–Sulfur Batteries journal May 2019
Graphene Oxide/Carbon Nanotube Bilayer Flexible Membrane for High‐Performance Li–S Batteries with Superior Physical and Electrochemical Properties journal February 2019
One-pot synthesis and shape control of metal selenides, sulfides and oxides with oxalic acid as the reducing reagent journal January 2019
Rational design of polar/nonpolar mediators toward efficient sulfur fixation and enhanced conductivity journal January 2020
Highly stable lithium–sulfur batteries based on p–n heterojunctions embedded on hollow sheath carbon propelling polysulfides conversion journal January 2019
Separator Modified by Cobalt‐Embedded Carbon Nanosheets Enabling Chemisorption and Catalytic Effects of Polysulfides for High‐Energy‐Density Lithium‐Sulfur Batteries journal July 2019
Efficient Ni 2 Co 4 P 3 Nanowires Catalysts Enhance Ultrahigh‐Loading Lithium–Sulfur Conversion in a Microreactor‐Like Battery journal October 2019
Engineering Oxygen Vacancies in a Polysulfide‐Blocking Layer with Enhanced Catalytic Ability journal January 2020
A 3D porous FeP/rGO modulated separator as a dual-function polysulfide barrier for high-performance lithium sulfur batteries journal January 2020
2 D Materials for Inhibiting the Shuttle Effect in Advanced Lithium–Sulfur Batteries journal March 2020
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Rationalizing Electrocatalysis of Li–S Chemistry by Mediator Design: Progress and Prospects journal July 2019
Synergistic Regulation of Polysulfides Conversion and Deposition by MOF‐Derived Hierarchically Ordered Carbonaceous Composite for High‐Energy Lithium–Sulfur Batteries journal March 2019
Fully integrated hierarchical double-shelled Co 9 S 8 @CNT nanostructures with unprecedented performance for Li–S batteries journal January 2019
Long‐Life, High‐Rate Lithium–Sulfur Cells with a Carbon‐Free VN Host as an Efficient Polysulfide Adsorbent and Lithium Dendrite Inhibitor journal December 2019
Constructing Patch‐Ni‐Shelled Pt@Ni Nanoparticles within Confined Nanoreactors for Catalytic Oxidation of Insoluble Polysulfides in Li‐S Batteries journal June 2019