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Title: Electrode–electrolyte interfaces in lithium-based batteries

Abstract

This review presents the research progress and future perspectives for understanding/manipulating the electrode–electrolyte interfaces in Li-based batteries.

Authors:
 [1]; ORCiD logo [1]
  1. Materials Science & Engineering Program and Texas Materials Institute; The University of Texas at Austin; Austin; USA
Publication Date:
Research Org.:
Univ. of Texas, Austin, TX (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1539928
DOE Contract Number:  
SC0005397
Resource Type:
Journal Article
Journal Name:
Energy & Environmental Science
Additional Journal Information:
Journal Volume: 11; Journal Issue: 3; Journal ID: ISSN 1754-5692
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Energy & Fuels; Engineering; Environmental Sciences & Ecology

Citation Formats

Yu, Xingwen, and Manthiram, Arumugam. Electrode–electrolyte interfaces in lithium-based batteries. United States: N. p., 2018. Web. doi:10.1039/c7ee02555f.
Yu, Xingwen, & Manthiram, Arumugam. Electrode–electrolyte interfaces in lithium-based batteries. United States. doi:10.1039/c7ee02555f.
Yu, Xingwen, and Manthiram, Arumugam. Mon . "Electrode–electrolyte interfaces in lithium-based batteries". United States. doi:10.1039/c7ee02555f.
@article{osti_1539928,
title = {Electrode–electrolyte interfaces in lithium-based batteries},
author = {Yu, Xingwen and Manthiram, Arumugam},
abstractNote = {This review presents the research progress and future perspectives for understanding/manipulating the electrode–electrolyte interfaces in Li-based batteries.},
doi = {10.1039/c7ee02555f},
journal = {Energy & Environmental Science},
issn = {1754-5692},
number = 3,
volume = 11,
place = {United States},
year = {2018},
month = {1}
}

Works referenced in this record:

Electrical Energy Storage and Intercalation Chemistry
journal, June 1976


Chemistry of intercalation compounds: Metal guests in chalcogenide hosts
journal, January 1978


Solid State Electrodes for High Energy Batteries
journal, August 1979


Lithium insertion into manganese spinels
journal, April 1983

  • Thackeray, M. M.; David, W. I. F.; Bruce, P. G.
  • Materials Research Bulletin, Vol. 18, Issue 4, p. 461-472
  • DOI: 10.1016/0025-5408(83)90138-1

LixCoO2 (0<x<-1): A new cathode material for batteries of high energy density
journal, June 1980


A Cyclable Lithium Organic Electrolyte Cell Based on Two Intercalation Electrodes
journal, January 1980

  • Lazzari, M.
  • Journal of The Electrochemical Society, Vol. 127, Issue 3
  • DOI: 10.1149/1.2129753

Preparation of a new crystal form of manganese dioxide: λ-MnO2
journal, September 1981


Building better batteries
journal, February 2008

  • Armand, M.; Tarascon, J.-M.
  • Nature, Vol. 451, Issue 7179, p. 652-657
  • DOI: 10.1038/451652a

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

  • Goodenough, John B.; Park, Kyu-Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3091438

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

A perspective on the high-voltage LiMn1.5Ni0.5O4 spinel cathode for lithium-ion batteries
journal, January 2014

  • Manthiram, Arumugam; Chemelewski, Katharine; Lee, Eun-Sung
  • Energy & Environmental Science, Vol. 7, Issue 4
  • DOI: 10.1039/c3ee42981d

Materials Challenges and Opportunities of Lithium Ion Batteries
journal, January 2011

  • Manthiram, Arumugam
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 3
  • DOI: 10.1021/jz1015422

Electrical energy storage: Materials challenges and prospects
journal, August 2016


Li-ion batteries: basics, progress, and challenges
journal, September 2015

  • Deng, Da
  • Energy Science & Engineering, Vol. 3, Issue 5
  • DOI: 10.1002/ese3.95

Synthesis and structural characterization of the normal spinel Li[Ni2]O4
journal, October 1985


Theoretical Studies To Understand Surface Chemistry on Carbon Anodes for Lithium-Ion Batteries:  Reduction Mechanisms of Ethylene Carbonate
journal, November 2001

  • Wang, Yixuan; Nakamura, Shinichiro; Ue, Makoto
  • Journal of the American Chemical Society, Vol. 123, Issue 47
  • DOI: 10.1021/ja0164529

Lithium Batteries and Cathode Materials
journal, October 2004

  • Whittingham, M. Stanley
  • Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
  • DOI: 10.1021/cr020731c

Insertion Electrode Materials for Rechargeable Lithium Batteries
journal, July 1998


Issues and challenges facing rechargeable lithium batteries
journal, November 2001

  • Tarascon, J.-M.; Armand, M.
  • Nature, Vol. 414, Issue 6861, p. 359-367
  • DOI: 10.1038/35104644

Electrode–Electrolyte Interface in Li-Ion Batteries: Current Understanding and New Insights
journal, October 2015

  • Gauthier, Magali; Carney, Thomas J.; Grimaud, Alexis
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 22
  • DOI: 10.1021/acs.jpclett.5b01727

A Review of Solid Electrolyte Interphases on Lithium Metal Anode
journal, November 2015


Review—Solid Electrolytes in Rechargeable Electrochemical Cells
journal, January 2015

  • Goodenough, John B.; Singh, Preetam
  • Journal of The Electrochemical Society, Vol. 162, Issue 14
  • DOI: 10.1149/2.0021514jes

The electrode/electrolyte interface - a status report
journal, July 1993

  • Bard, Allen J.; Abruna, Hector D.; Chidsey, Chris E.
  • The Journal of Physical Chemistry, Vol. 97, Issue 28
  • DOI: 10.1021/j100130a007

Nanostructured materials for advanced energy conversion and storage devices
journal, May 2005

  • Aricò, Antonino Salvatore; Bruce, Peter; Scrosati, Bruno
  • Nature Materials, Vol. 4, Issue 5, p. 366-377
  • DOI: 10.1038/nmat1368

Lithium metal anodes for rechargeable batteries
journal, January 2014

  • Xu, Wu; Wang, Jiulin; Ding, Fei
  • Energy Environ. Sci., Vol. 7, Issue 2
  • DOI: 10.1039/C3EE40795K

Prospects for Dendrite-Free Cycling of Li Metal Batteries
journal, January 2015

  • Chen, Qing; Geng, Ke; Sieradzki, K.
  • Journal of The Electrochemical Society, Vol. 162, Issue 10
  • DOI: 10.1149/2.0261510jes

The role of the anions in the growth speed of fractal electrodeposits
journal, September 1990

  • Fleury, V.; Chazalviel, J. -N.; Rosso, M.
  • Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 290, Issue 1-2
  • DOI: 10.1016/0022-0728(90)87434-L

Electrochemical aspects of the generation of ramified metallic electrodeposits
journal, December 1990


In situ study of dendritic growth inlithium/PEO-salt/lithium cells
journal, April 1998


Onset of dendritic growth in lithium/polymer cells
journal, July 2001


Dendrite-free lithium metal anodes: stable solid electrolyte interphases for high-efficiency batteries
journal, January 2015

  • Cheng, Xin-Bing; Zhang, Qiang
  • Journal of Materials Chemistry A, Vol. 3, Issue 14
  • DOI: 10.1039/C5TA00689A

Role of the solid electrolyte interphase on a Li metal anode in a dimethylsulfoxide-based electrolyte for a lithium–oxygen battery
journal, October 2015


Rechargeable Lithium Batteries with Aqueous Electrolytes
journal, May 1994


Poly(ethylene oxide) - LiCF3SO3 - polystyrene electrolyte systems
journal, January 1986


Complexes of alkali metal ions with poly(ethylene oxide)
journal, November 1973


NMR, DSC, and conductivity study of a poly(ethylene oxide) complex electrolyte : PEO(LiClO4)x
journal, January 1986


Poly(ethylene oxide) electrolytes for operation at near room temperature
journal, January 1985


Preparation and characterization of poly(vinyl sulfone)- and poly(vinylidene fluoride)-based electrolytes
journal, October 1995


Li+-Conductive Solid Polymer Electrolytes with Liquid-Like Conductivity
journal, January 1990

  • Abraham, K. M.
  • Journal of The Electrochemical Society, Vol. 137, Issue 5
  • DOI: 10.1149/1.2086749

Investigation of the position of Li+ ions in a polyacrylonitrile-based electrolyte by Raman and infrared spectroscopy
journal, June 1996


Kinetics and stability of the lithium electrode in poly(methylmethacrylate)-based gel electrolytes
journal, June 1995


Novel preparation of nanocomposite polymer electrolyte and its application to lithium polymer batteries
journal, November 2004


Microporous poly(acrylonitrile-methyl methacrylate) membrane as a separator of rechargeable lithium battery
journal, August 2004


Sputtering of lithium compounds for preparation of electrolyte thin films
journal, July 1992


Electrical properties of amorphous lithium electrolyte thin films
journal, July 1992


Fast Na+-ion transport in skeleton structures
journal, February 1976


Lithium ion conductors in the system AB(IV)2(PO4)3 (B = Ti, Zr and Hf)
journal, January 1986


Series of rare earth garnets Ln3+3M2Li+3O12 (M=Te, W)
journal, April 1969


High ionic conductivity in lithium lanthanum titanate
journal, June 1993

  • Inaguma, Yoshiyuki; Liquan, Chen; Itoh, Mitsuru
  • Solid State Communications, Vol. 86, Issue 10, p. 689-693
  • DOI: 10.1016/0038-1098(93)90841-A

Remarks on a ternary phase in the La2O3Me2O5Li2O system (Me=Nb, Ta)
journal, November 1988


Preparation and conductivity measurements of SiS2Li2S glasses doped with LiBr and LiCl
journal, January 1986


A Highly Conductive Li+-Glass System: (1−x) (0.4SiS[sub 2]-0.6Li[sub 2]S)-xLil
journal, January 1986

  • Kennedy, John H.
  • Journal of The Electrochemical Society, Vol. 133, Issue 11
  • DOI: 10.1149/1.2108425

Mechanical characterization of LiPON films using nanoindentation
journal, October 2011


Interface-Engineered All-Solid-State Li-Ion Batteries Based on Garnet-Type Fast Li + Conductors
journal, July 2016

  • van den Broek, Jan; Afyon, Semih; Rupp, Jennifer L. M.
  • Advanced Energy Materials, Vol. 6, Issue 19
  • DOI: 10.1002/aenm.201600736

Investigating the all-solid-state batteries based on lithium garnets and a high potential cathode – LiMn 1.5 Ni 0.5 O 4
journal, January 2016

  • Hänsel, Christian; Afyon, Semih; Rupp, Jennifer L. M.
  • Nanoscale, Vol. 8, Issue 43
  • DOI: 10.1039/C6NR06955J

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014


Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004


High-voltage positive electrode materials for lithium-ion batteries
journal, January 2017

  • Li, Wangda; Song, Bohang; Manthiram, Arumugam
  • Chemical Society Reviews, Vol. 46, Issue 10
  • DOI: 10.1039/C6CS00875E

Precision Measurements of the Coulombic Efficiency of Lithium-Ion Batteries and of Electrode Materials for Lithium-Ion Batteries
journal, January 2010

  • Smith, A. J.; Burns, J. C.; Trussler, S.
  • Journal of The Electrochemical Society, Vol. 157, Issue 2
  • DOI: 10.1149/1.3268129

Artificial solid-electrolyte interphase (SEI) for improved cycleability and safety of lithium–ion cells for EV applications
journal, September 2009


Film forming reaction at the lithium/electrolyte interface
journal, January 1983


Composition of Surface Layers on Li Electrodes in PC, LiClO[sub 4] of Very Low Water Content
journal, January 1985

  • Nazri, Gholamabbas
  • Journal of The Electrochemical Society, Vol. 132, Issue 9
  • DOI: 10.1149/1.2114288

In Situ X-Ray Diffraction of Surface Layers on Lithium in Nonaqueous Electrolyte
journal, January 1985

  • Nazri, Gholamabbas
  • Journal of The Electrochemical Society, Vol. 132, Issue 6
  • DOI: 10.1149/1.2114128

Identification of Surface Films Formed on Lithium in Propylene Carbonate Solutions
journal, January 1987

  • Aurbach, D.
  • Journal of The Electrochemical Society, Vol. 134, Issue 7
  • DOI: 10.1149/1.2100722

XPS analysis of a lithium surface immersed in propylene carbonate solution containing various salts
journal, July 1992

  • Kanamura, Kiyoshi; Tamura, Hiroshi; Takehara, Zen-ichiro
  • Journal of Electroanalytical Chemistry, Vol. 333, Issue 1-2
  • DOI: 10.1016/0022-0728(92)80386-I

Morphology and chemical compositions of surface films of lithium deposited on a Ni substrate in nonaqueous electrolytes
journal, September 1995

  • Kanamura, K.; Tamura, Hiroshi; Shiraishi, Soshi
  • Journal of Electroanalytical Chemistry, Vol. 394, Issue 1-2
  • DOI: 10.1016/0022-0728(95)03972-J

Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes
journal, January 1997

  • Peled, E.
  • Journal of The Electrochemical Society, Vol. 144, Issue 8
  • DOI: 10.1149/1.1837858

Impedance Spectroscopy of Li Electrodes. 4. A General Simple Model of the Li−Solution Interphase in Polar Aprotic Systems
journal, January 1996

  • Zaban, Arie; Zinigrad, Ella; Aurbach, Doron
  • The Journal of Physical Chemistry, Vol. 100, Issue 8
  • DOI: 10.1021/jp9514279

Recent studies of the lithium-liquid electrolyte interface Electrochemical, morphological and spectral studies of a few important systems
journal, March 1995


Electrochemical and spectroscopic studies of carbon electrodes in lithium battery electrolyte systems
journal, March 1993


An Advanced Tool for the Selection of Electrolyte Components for Rechargeable Lithium Batteries
journal, January 1998

  • Peled, E.
  • Journal of The Electrochemical Society, Vol. 145, Issue 10
  • DOI: 10.1149/1.1838831

The behaviour of lithium electrodes in propylene and ethylene carbonate: Te major factors that influence Li cycling efficiency
journal, November 1992

  • Aurbach, Doron; Gofer, Yosef; Ben-Zion, Moshe
  • Journal of Electroanalytical Chemistry, Vol. 339, Issue 1-2
  • DOI: 10.1016/0022-0728(92)80467-I

Lithium Ethylene Dicarbonate Identified as the Primary Product of Chemical and Electrochemical Reduction of EC in 1.2 M LiPF 6 /EC:EMC Electrolyte
journal, September 2005

  • Zhuang, Guorong V.; Xu, Kang; Yang, Hui
  • The Journal of Physical Chemistry B, Vol. 109, Issue 37
  • DOI: 10.1021/jp052474w

Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells
journal, January 1990

  • Fong, Rosamaría
  • Journal of The Electrochemical Society, Vol. 137, Issue 7
  • DOI: 10.1149/1.2086855

The Solid Electrolyte Interphase – The Most Important and the Least Understood Solid Electrolyte in Rechargeable Li Batteries
journal, December 2009


A new look at the solid electrolyte interphase on graphite anodes in Li-ion batteries
journal, February 2006


Composition, depth profiles and lateral distribution of materials in the SEI built on HOPG-TOF SIMS and XPS studies
journal, July 2001


XPS analysis of the SEI formed on carbonaceous materials
journal, May 2004


The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries
journal, January 1995

  • Aurbach, Doron
  • Journal of The Electrochemical Society, Vol. 142, Issue 9
  • DOI: 10.1149/1.2048659

On the correlation between surface chemistry and performance of graphite negative electrodes for Li ion batteries
journal, September 1999


The dependence of the performance of Li-C intercalation anodes for Li-ion secondary batteries on the electrolyte solution composition
journal, December 1994


In situ visualization of Li-ion intercalation and formation of the solid electrolyte interphase on TiO2 based paste electrodes using scanning electrochemical microscopy
journal, January 2013

  • Zampardi, Giorgia; Ventosa, Edgar; La Mantia, Fabio
  • Chemical Communications, Vol. 49, Issue 81
  • DOI: 10.1039/c3cc44576c

Spatiotemporal Changes of the Solid Electrolyte Interphase in Lithium-Ion Batteries Detected by Scanning Electrochemical Microscopy
journal, July 2014

  • Bülter, Heinz; Peters, Fabian; Schwenzel, Julian
  • Angewandte Chemie International Edition, Vol. 53, Issue 39
  • DOI: 10.1002/anie.201403935

Determination of the formation and range of stability of the SEI on glassy carbon by local electrochemistry
journal, January 2015

  • Zampardi, Giorgia; La Mantia, Fabio; Schuhmann, Wolfgang
  • RSC Advances, Vol. 5, Issue 39
  • DOI: 10.1039/C5RA02940F

In-operando evaluation of the effect of vinylene carbonate on the insulating character of the solid electrolyte interphase
journal, September 2015


Surface Film Formation on Graphite Negative Electrode in Lithium-Ion Batteries: AFM Study in an Ethylene Carbonate-Based Solution
journal, January 2001

  • Jeong, Soon-Ki; Inaba, Minoru; Abe, Takeshi
  • Journal of The Electrochemical Society, Vol. 148, Issue 9
  • DOI: 10.1149/1.1387981

Failure and Stabilization Mechanisms of Graphite Electrodes
journal, March 1997

  • Aurbach, Doron; Levi, Mikhail D.; Levi, Elena
  • The Journal of Physical Chemistry B, Vol. 101, Issue 12
  • DOI: 10.1021/jp962815t

A Study of Highly Oriented Pyrolytic Graphite as a Model for the Graphite Anode in Li-Ion Batteries
journal, January 1999

  • Bar-Tow, D.
  • Journal of The Electrochemical Society, Vol. 146, Issue 3
  • DOI: 10.1149/1.1391688

Dendrite-Free Lithium Deposition with Self-Aligned Nanorod Structure
journal, November 2014

  • Zhang, Yaohui; Qian, Jiangfeng; Xu, Wu
  • Nano Letters, Vol. 14, Issue 12
  • DOI: 10.1021/nl5039117

Solid electrolyte interphase on graphite Li-ion battery anodes studied by soft X-ray spectroscopy
journal, January 2004

  • Augustsson, A.; Herstedt, M.; Guo, J. -H.
  • Phys. Chem. Chem. Phys., Vol. 6, Issue 16
  • DOI: 10.1039/B313434B

13C Solid State NMR Suggests Unusual Breakdown Products in SEI Formation on Lithium Ion Electrodes
journal, January 2011

  • Leifer, N.; Smart, M. C.; Prakash, G. K. S.
  • Journal of The Electrochemical Society, Vol. 158, Issue 5
  • DOI: 10.1149/1.3559551

Chemistry, Impedance, and Morphology Evolution in Solid Electrolyte Interphase Films during Formation in Lithium Ion Batteries
journal, December 2013

  • Lu, Peng; Li, Chen; Schneider, Eric W.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 2
  • DOI: 10.1021/jp4111019

A.c. impedance analysis of electrochemical lithium intercalation into highly oriented pyrolytic graphite
journal, October 1997


XRD evidence for the electrochemical formation of Li+(PC)yCn- in PC-based electrolytes
journal, September 2005


Solvation Sheath of Li + in Nonaqueous Electrolytes and Its Implication of Graphite/Electrolyte Interface Chemistry
journal, May 2007

  • Xu, Kang; Lam, Yiufai; Zhang, Sheng S.
  • The Journal of Physical Chemistry C, Vol. 111, Issue 20
  • DOI: 10.1021/jp068691u

Reduction of Carbonate Electrolytes and the Formation of Solid-Electrolyte Interface (SEI) in Lithium-Ion Batteries. 2. Radiolytically Induced Polymerization of Ethylene Carbonate
journal, September 2013

  • Shkrob, Ilya A.; Zhu, Ye; Marin, Timothy W.
  • The Journal of Physical Chemistry C, Vol. 117, Issue 38, p. 19270-19279
  • DOI: 10.1021/jp406273p

Effects of redox system structure on electron-transfer kinetics at ordered graphite and glassy carbon electrodes
journal, November 1992

  • Kneten, Kristin R.; McCreery, Richard L.
  • Analytical Chemistry, Vol. 64, Issue 21
  • DOI: 10.1021/ac00045a011

Reactions of Singly-Reduced Ethylene Carbonate in Lithium Battery Electrolytes: A Molecular Dynamics Simulation Study Using the ReaxFF
journal, December 2011

  • Bedrov, Dmitry; Smith, Grant D.; van Duin, Adri C. T.
  • The Journal of Physical Chemistry A, Vol. 116, Issue 11
  • DOI: 10.1021/jp210345b

Syntheses and Characterization of Lithium Alkyl Mono- and Dicarbonates as Components of Surface Films in Li-Ion Batteries
journal, March 2006

  • Xu, Kang; Zhuang, Guorong V.; Allen, Jan L.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 15
  • DOI: 10.1021/jp0601522

Chemical Reactivity of PF[sub 5] and LiPF[sub 6] in Ethylene Carbonate/Dimethyl Carbonate Solutions
journal, January 2001

  • Sloop, S. E.; Pugh, J. K.; Wang, S.
  • Electrochemical and Solid-State Letters, Vol. 4, Issue 4
  • DOI: 10.1149/1.1353158

Advanced Carbon Electrode Materials for Molecular Electrochemistry
journal, July 2008

  • McCreery, Richard L.
  • Chemical Reviews, Vol. 108, Issue 7, p. 2646-2687
  • DOI: 10.1021/cr068076m

Theoretical Studies To Understand Surface Chemistry on Carbon Anodes for Lithium-Ion Batteries:  How Does Vinylene Carbonate Play Its Role as an Electrolyte Additive?
journal, April 2002

  • Wang, Yixuan; Nakamura, Shinichiro; Tasaki, Ken
  • Journal of the American Chemical Society, Vol. 124, Issue 16
  • DOI: 10.1021/ja017073i

Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction
journal, December 2012

  • Pinson, Matthew B.; Bazant, Martin Z.
  • Journal of The Electrochemical Society, Vol. 160, Issue 2
  • DOI: 10.1149/2.044302jes

Review—SEI: Past, Present and Future
journal, January 2017

  • Peled, E.; Menkin, S.
  • Journal of The Electrochemical Society, Vol. 164, Issue 7
  • DOI: 10.1149/2.1441707jes

On Electrolyte-Dependent Formation of Solid Electrolyte Interphase Film in Lithium-Ion Batteries: Strong Sensitivity to Small Structural Difference of Electrolyte Molecules
journal, May 2014

  • Takenaka, Norio; Suzuki, Yuichi; Sakai, Hirofumi
  • The Journal of Physical Chemistry C, Vol. 118, Issue 20
  • DOI: 10.1021/jp5018696

Direct Calculation of Li-Ion Transport in the Solid Electrolyte Interphase
journal, September 2012

  • Shi, Siqi; Lu, Peng; Liu, Zhongyi
  • Journal of the American Chemical Society, Vol. 134, Issue 37
  • DOI: 10.1021/ja305366r

High rate and stable cycling of lithium metal anode
journal, February 2015

  • Qian, Jiangfeng; Henderson, Wesley A.; Xu, Wu
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7362

In Situ Formation of Protective Coatings on Sulfur Cathodes in Lithium Batteries with LiFSI-Based Organic Electrolytes
journal, December 2014

  • Kim, Hyea; Wu, Feixiang; Lee, Jung Tae
  • Advanced Energy Materials, Vol. 5, Issue 6
  • DOI: 10.1002/aenm.201401792

AC Impedance Analysis of Polycrystalline Insertion Electrodes: Application to Li[sub 1−x]CoO[sub 2]
journal, January 1985

  • Thomas, M. G. S. R.
  • Journal of The Electrochemical Society, Vol. 132, Issue 7
  • DOI: 10.1149/1.2114158

The cathode–electrolyte interface in the Li-ion battery
journal, November 2004


Surface film formation on electrodes in a LiCoO2/graphite cell: A step by step XPS study
journal, December 2007


On the capacity fading of LiCoO2 intercalation electrodes:
journal, October 2002


Electrode/Electrolyte Interface Reactivity in High-Voltage Spinel LiMn 1.6 Ni 0.4 O 4 /Li 4 Ti 5 O 12 Lithium-Ion Battery
journal, May 2010

  • Dedryvère, R.; Foix, D.; Franger, S.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 24
  • DOI: 10.1021/jp1026509

Influence of Temperature on the Interface Chemistry of Li x Mn 2 O 4 Electrodes
journal, April 2002

  • Eriksson, T.; Andersson, A. M.; Gejke, C.
  • Langmuir, Vol. 18, Issue 9
  • DOI: 10.1021/la011354m

Probing the Origin of Enhanced Stability of “AlPO4” Nanoparticle Coated LiCoO2 during Cycling to High Voltages: Combined XRD and XPS Studies
journal, October 2009

  • Lu, Yi-Chun; Mansour, Azzam N.; Yabuuchi, Naoaki
  • Chemistry of Materials, Vol. 21, Issue 19, p. 4408-4424
  • DOI: 10.1021/cm900862v

Detailed Studies of a High-Capacity Electrode Material for Rechargeable Batteries, Li 2 MnO 3 −LiCo 1/3 Ni 1/3 Mn 1/3 O 2
journal, March 2011

  • Yabuuchi, Naoaki; Yoshii, Kazuhiro; Myung, Seung-Taek
  • Journal of the American Chemical Society, Vol. 133, Issue 12
  • DOI: 10.1021/ja108588y

Electron Spectroscopy Study of Li[Ni,Co,Mn]O 2 /Electrolyte Interface: Electronic Structure, Interface Composition, and Device Implications
journal, April 2015

  • Cherkashinin, Gennady; Motzko, Markus; Schulz, Natalia
  • Chemistry of Materials, Vol. 27, Issue 8
  • DOI: 10.1021/cm5047534

Studies on electrochemical oxidation of non-aqueous electrolyte on the LiCoO2 thin film electrode
journal, December 1996

  • Kanamura, Kiyoshi; Toriyama, Shigetaka; Shiraishi, Soshi
  • Journal of Electroanalytical Chemistry, Vol. 419, Issue 1
  • DOI: 10.1016/S0022-0728(96)04862-0

The Study of Electrolyte Solutions Based on Ethylene and Diethyl Carbonates for Rechargeable Li Batteries
journal, January 1995

  • Aurbach, Doron
  • Journal of The Electrochemical Society, Vol. 142, Issue 9
  • DOI: 10.1149/1.2048658

Influence of the PVdF binder on the stability of LiCoO2 electrodes
journal, December 2005


First In Situ Observation of the LiCoO 2 Electrode/Electrolyte Interface by Total-Reflection X-ray Absorption Spectroscopy
journal, October 2012

  • Takamatsu, Daiko; Koyama, Yukinori; Orikasa, Yuki
  • Angewandte Chemie International Edition, Vol. 51, Issue 46
  • DOI: 10.1002/anie.201203910

Understanding the Degradation Mechanisms of LiNi 0.5 Co 0.2 Mn 0.3 O 2 Cathode Material in Lithium Ion Batteries
journal, August 2013

  • Jung, Sung-Kyun; Gwon, Hyeokjo; Hong, Jihyun
  • Advanced Energy Materials, Vol. 4, Issue 1
  • DOI: 10.1002/aenm.201300787

Investigation of Changes in the Surface Structure of Li x Ni 0.8 Co 0.15 Al 0.05 O 2 Cathode Materials Induced by the Initial Charge
journal, December 2013

  • Hwang, Sooyeon; Chang, Wonyoung; Kim, Seung Min
  • Chemistry of Materials, Vol. 26, Issue 2
  • DOI: 10.1021/cm403332s

Evolutions of Li 1.2 Mn 0.61 Ni 0.18 Mg 0.01 O 2 during the Initial Charge/Discharge Cycle Studied by Advanced Electron Microscopy
journal, September 2012

  • Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François
  • Chemistry of Materials, Vol. 24, Issue 18
  • DOI: 10.1021/cm301140g

Novel LiCoO2 Cathode Material with Al2O3 Coating for a Li Ion Cell
journal, December 2000

  • Cho, Jaephil; Kim, Yong Jeong; Park, Byungwoo
  • Chemistry of Materials, Vol. 12, Issue 12, p. 3788-3791
  • DOI: 10.1021/cm000511k

Solid‐State Electrochemical Kinetics of Li‐Ion Intercalation into Li1 − xCoO2: Simultaneous Application of Electroanalytical Techniques SSCV, PITT, and EIS
journal, January 1999

  • Levi, M. D.; Salitra, G.; Markovsky, B.
  • Journal of The Electrochemical Society, Vol. 146, Issue 4, p. 1279-1289
  • DOI: 10.1149/1.1391759

Review on electrode–electrolyte solution interactions, related to cathode materials for Li-ion batteries
journal, March 2007


Probing the Basicity of Regular and Defect Sites of Alkaline Earth Metal Oxide Surfaces by BF3 Adsorption: A Theoretical Analysis
journal, May 2004

  • Di Valentin, Cristiana; Locati, Corrado; Pacchioni, Gianfranco
  • ChemPhysChem, Vol. 5, Issue 5
  • DOI: 10.1002/cphc.200400006

Nonrigid Band Behavior of the Electronic Structure of LiCoO 2 Thin Film during Electrochemical Li Deintercalation
journal, June 2014

  • Ensling, D.; Cherkashinin, G.; Schmid, S.
  • Chemistry of Materials, Vol. 26, Issue 13
  • DOI: 10.1021/cm501480b

CO 2 and O 2 Evolution at High Voltage Cathode Materials of Li-Ion Batteries: A Differential Electrochemical Mass Spectrometry Study
journal, June 2014

  • Wang, Hongsen; Rus, Eric; Sakuraba, Takahito
  • Analytical Chemistry, Vol. 86, Issue 13
  • DOI: 10.1021/ac403317d

Critical Role of Oxygen Evolved from Layered Li–Excess Metal Oxides in Lithium Rechargeable Batteries
journal, July 2012

  • Hong, Jihyun; Lim, Hee-Dae; Lee, Minah
  • Chemistry of Materials, Vol. 24, Issue 14
  • DOI: 10.1021/cm3005634

Direct evidence of oxygen evolution from Li1+x (Ni1/3Mn1/3Co1/3)1−x O2 at high potentials
journal, February 2008

  • La Mantia, Fabio; Rosciano, Fabio; Tran, Nicolas
  • Journal of Applied Electrochemistry, Vol. 38, Issue 7
  • DOI: 10.1007/s10800-008-9491-9

Electron paramagnetic resonance imaging for real-time monitoring of Li-ion batteries
journal, February 2015

  • Sathiya, M.; Leriche, J. -B.; Salager, E.
  • Nature Communications, Vol. 6, Issue 1
  • DOI: 10.1038/ncomms7276

Operando X-ray Absorption Study of the Redox Processes Involved upon Cycling of the Li-Rich Layered Oxide Li 1.20 Mn 0.54 Co 0.13 Ni 0.13 O 2 in Li Ion Batteries
journal, March 2014

  • Koga, H.; Croguennec, L.; Ménétrier, M.
  • The Journal of Physical Chemistry C, Vol. 118, Issue 11
  • DOI: 10.1021/jp412197z

Reversible Oxygen Participation to the Redox Processes Revealed for Li 1.20 Mn 0.54 Co 0.13 Ni 0.13 O 2
journal, January 2013

  • Koga, Hideyuki; Croguennec, Laurence; Ménétrier, Michel
  • Journal of The Electrochemical Society, Vol. 160, Issue 6
  • DOI: 10.1149/2.038306jes

Electrochemical Activities in Li[sub 2]MnO[sub 3]
journal, January 2009

  • Yu, Denis Y. W.; Yanagida, Katsunori; Kato, Yoshio
  • Journal of The Electrochemical Society, Vol. 156, Issue 6
  • DOI: 10.1149/1.3110803

Overcharging manganese oxides: Extracting lithium beyond Mn4+
journal, August 2005


Thermal Instability of Cycled Li x Ni 0.5 Mn 0.5 O 2 Electrodes: An in Situ Synchrotron X-ray Powder Diffraction Study
journal, August 2008

  • Yabuuchi, Naoaki; Kim, Yong-Tae; Li, Hayley H.
  • Chemistry of Materials, Vol. 20, Issue 15
  • DOI: 10.1021/cm800314d

Contribution of the oxygen extracted from overlithiated layered oxides at high potential to the formation of the interphase
journal, December 2015


Predicting Solvent Stability in Aprotic Electrolyte Li–Air Batteries: Nucleophilic Substitution by the Superoxide Anion Radical (O 2 •– )
journal, November 2011

  • Bryantsev, Vyacheslav S.; Giordani, Vincent; Walker, Wesley
  • The Journal of Physical Chemistry A, Vol. 115, Issue 44
  • DOI: 10.1021/jp2073914

Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries
journal, April 2017

  • Li, Wangda; Dolocan, Andrei; Oh, Pilgun
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14589

Revealing the electronic character of the positive electrode/electrolyte interface in lithium-ion batteries
journal, January 2017

  • Zampardi, Giorgia; Trocoli, Rafael; Schuhmann, Wolfgang
  • Phys. Chem. Chem. Phys., Vol. 19, Issue 41
  • DOI: 10.1039/C7CP05453J

Electrolyte additives for lithium ion battery electrodes: progress and perspectives
journal, January 2016

  • Haregewoin, Atetegeb Meazah; Wotango, Aselefech Sorsa; Hwang, Bing-Joe
  • Energy Environ. Sci., Vol. 9, Issue 6
  • DOI: 10.1039/C6EE00123H

A review on electrolyte additives for lithium-ion batteries
journal, November 2006


Inorganic electrolyte additives to suppress the degradation of graphite anodes by dissolved Mn(II) for lithium-ion batteries
journal, June 2003


The Role of SO[sub 2] as an Additive to Organic Li-Ion Battery Electrolytes
journal, January 1997

  • Ein-Eli, Y.
  • Journal of The Electrochemical Society, Vol. 144, Issue 4
  • DOI: 10.1149/1.1837566

Theoretical Study of the Reductive Decomposition of Ethylene Sulfite: A Film-Forming Electrolyte Additive in Lithium Ion Batteries
journal, October 2012

  • Leggesse, Ermias Girma; Jiang, Jyh-Chiang
  • The Journal of Physical Chemistry A, Vol. 116, Issue 45
  • DOI: 10.1021/jp3081996

Improvement in High-voltage Performance of Lithium-ion Batteries Using Bismaleimide as an Electrolyte Additive
journal, March 2014


Impedance Reducing Additives and Their Effect on Cell Performance: I. LiN(CF
journal, January 2012

  • Burns, J. C.; Sinha, N. N.; Jain, Gaurav
  • Journal of The Electrochemical Society, Vol. 159, Issue 7
  • DOI: 10.1149/2.077207jes

Role of propane sultone as an additive to improve the performance of a lithium-rich cathode material at a high potential
journal, January 2015

  • Pires, Julie; Timperman, Laure; Castets, Aurore
  • RSC Advances, Vol. 5, Issue 52
  • DOI: 10.1039/C5RA05650K

Effect of Anion Receptor Additives on Electrochemical Performance of Lithium-Ion Batteries
journal, August 2010

  • Qin, Yan; Chen, Zonghai; Lee, H. S.
  • The Journal of Physical Chemistry C, Vol. 114, Issue 35
  • DOI: 10.1021/jp104341t

Improved thermal stability of lithium ion battery by using cresyl diphenyl phosphate as an electrolyte additive
journal, November 2010


Fluorinated phosphazene co-solvents for improved thermal and safety performance in lithium-ion battery electrolytes
journal, October 2014


Bifunctional electrolyte additive for lithium-ion batteries
journal, April 2007


High-Potential Redox Shuttle for Use in Lithium-Ion Batteries
journal, January 2009

  • Moshurchak, L. M.; Lamanna, W. M.; Bulinski, Mike
  • Journal of The Electrochemical Society, Vol. 156, Issue 4, p. A309-A312
  • DOI: 10.1149/1.3077578

The study of lithium electrode reversibility against (PEO)xLiF3CSO3 polymeric electrolytes
journal, December 1983


Determination of the exchange current density of the Li++ e−⇆ Li reaction in polymer electrolytes by galvanostatic linear polarization of symmetrical cells
journal, December 1994

  • Munichandraiah, N.; Scanlon, L. G.; Marsh, R. A.
  • Journal of Electroanalytical Chemistry, Vol. 379, Issue 1-2
  • DOI: 10.1016/0022-0728(94)87174-4

Microelectrode studies of the Li/Li+ couple in low molecular weight liquid polyether electrolytes☆
journal, December 1994


The Li/Li+ couple in propylene carbonate electrolytes and poly(methyl methacrylate) gels
journal, March 1996

  • Christie, A. M.; Vincent, C. A.
  • Journal of Applied Electrochemistry, Vol. 26, Issue 3
  • DOI: 10.1007/BF00242094

Lithium electrode in polymer electrolytes
journal, June 1993


Study of the Poly[oxymethylene oligo-(oxyethylene)]/Lithium Metal Interface
journal, January 1996

  • Sloop, Steven E.
  • Journal of The Electrochemical Society, Vol. 143, Issue 4
  • DOI: 10.1149/1.1836632

Interfacial phenomena in polymer-electrolyte cells: lithium passivation and cycleability
journal, March 1993


The sei model—application to lithium-polymer electrolyte batteries
journal, October 1995


Novel in situ and ex situ techniques for the study of lithium/electrolyte interfaces
journal, March 1995


Studies of the interface between lithium electrodes and polymeric electrolyte systems using in situ FTIR spectroscopy
journal, July 2001


XPS study of lithium surface after contact with lithium-salt doped polymer electrolytes
journal, March 2001


Spectroscopic ellipsometry of lithium/polymer electrolyte interfaces
journal, August 2000


In situ Scanning Electron Microscopy (SEM) observation of interfaces within plastic lithium batteries
journal, November 1998


Characterization of the passivation layer at the polymer electrolyte/lithium electrode interface
journal, November 2000


Characterization of self-assembled molecular layers at the polymer electrolyte/lithium electrode interface
journal, January 2000


Modification of lithium/electrolyte interface by plasma polymerization of 1,1-difluoroethene
journal, April 1993


Interfacial enhancement between lithium electrode and polymer electrolytes
journal, June 2003


The effects of chemical composition of adsorbed molecular layers on lithium electrode/polymer electrolyte interface stabilization
journal, July 2001


Progress and prospective of solid-state lithium batteries
journal, February 2013


Enhancement of the High-Rate Capability of Solid-State Lithium Batteries by Nanoscale Interfacial Modification
journal, September 2006

  • Ohta, N.; Takada, K.; Zhang, L.
  • Advanced Materials, Vol. 18, Issue 17, p. 2226-2229
  • DOI: 10.1002/adma.200502604

Lithium battery chemistries enabled by solid-state electrolytes
journal, February 2017


A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010


Interfacial Observation between LiCoO 2 Electrode and Li 2 S−P 2 S 5 Solid Electrolytes of All-Solid-State Lithium Secondary Batteries Using Transmission Electron Microscopy
journal, February 2010

  • Sakuda, Atsushi; Hayashi, Akitoshi; Tatsumisago, Masahiro
  • Chemistry of Materials, Vol. 22, Issue 3
  • DOI: 10.1021/cm901819c

Novel technique to form electrode–electrolyte nanointerface in all-solid-state rechargeable lithium batteries
journal, December 2008


First Cross-Section Observation of an All Solid-State Lithium-Ion “Nanobattery” by Transmission Electron Microscopy
journal, March 2008

  • Brazier, A.; Dupont, L.; Dantras-Laffont, L.
  • Chemistry of Materials, Vol. 20, Issue 6
  • DOI: 10.1021/cm7033933

In Situ STEM-EELS Observation of Nanoscale Interfacial Phenomena in All-Solid-State Batteries
journal, May 2016


Dynamic Visualization of the Electric Potential in an All-Solid-State Rechargeable Lithium Battery
journal, June 2010

  • Yamamoto, Kazuo; Iriyama, Yasutoshi; Asaka, Toru
  • Angewandte Chemie International Edition, Vol. 49, Issue 26
  • DOI: 10.1002/anie.200907319

Depth-resolved X-ray absorption spectroscopic study on nanoscale observation of the electrode–solid electrolyte interface for all solid state lithium ion batteries
journal, January 2011

  • Okumura, Toyoki; Nakatsutsumi, Takayuki; Ina, Toshiaki
  • Journal of Materials Chemistry, Vol. 21, Issue 27
  • DOI: 10.1039/c0jm04366d

Electronic Network Modeling of Rechargeable Batteries
journal, January 1998

  • Kruijt, W. S.
  • Journal of The Electrochemical Society, Vol. 145, Issue 11
  • DOI: 10.1149/1.1838871

Electronic Network Modeling of Rechargeable Batteries
journal, January 1998

  • Notten, P. H. L.
  • Journal of The Electrochemical Society, Vol. 145, Issue 11
  • DOI: 10.1149/1.1838872

Electronic-network modelling of rechargeable NiCd cells and its application to the design of battery management systems
journal, February 1999


Modeling All-Solid-State Li-Ion Batteries
journal, January 2011

  • Danilov, D.; Niessen, R. A. H.; Notten, P. H. L.
  • Journal of The Electrochemical Society, Vol. 158, Issue 3
  • DOI: 10.1149/1.3521414

High-capacity Li2S–nanocarbon composite electrode for all-solid-state rechargeable lithium batteries
journal, January 2012

  • Nagao, Motohiro; Hayashi, Akitoshi; Tatsumisago, Masahiro
  • Journal of Materials Chemistry, Vol. 22, Issue 19
  • DOI: 10.1039/c2jm16802b

Fabrication of electrode–electrolyte interfaces in all-solid-state rechargeable lithium batteries by using a supercooled liquid state of the glassy electrolytes
journal, January 2011

  • Kitaura, Hirokazu; Hayashi, Akitoshi; Ohtomo, Takamasa
  • J. Mater. Chem., Vol. 21, Issue 1
  • DOI: 10.1039/C0JM01090A

LiCoO[sub 2] Electrode Particles Coated with Li[sub 2]S–P[sub 2]S[sub 5] Solid Electrolyte for All-Solid-State Batteries
journal, January 2010

  • Sakuda, Atsushi; Hayashi, Akitoshi; Ohtomo, Takamasa
  • Electrochemical and Solid-State Letters, Vol. 13, Issue 6
  • DOI: 10.1149/1.3376620

All-Solid-State Lithium Secondary Batteries Using NiS-Carbon Fiber Composite Electrodes Coated with Li 2 S–P 2 S 5 Solid Electrolytes by Pulsed Laser Deposition
journal, January 2013

  • Aso, Keigo; Sakuda, Atsushi; Hayashi, Akitoshi
  • ACS Applied Materials & Interfaces, Vol. 5, Issue 3
  • DOI: 10.1021/am302164e

Recent progress of glass and glass-ceramics as solid electrolytes for lithium secondary batteries
journal, October 2006


All-solid-state lithium secondary batteries using LiCoO2 particles with pulsed laser deposition coatings of Li2S–P2S5 solid electrolytes
journal, August 2011


LiNbO3-coated LiCoO2 as cathode material for all solid-state lithium secondary batteries
journal, July 2007


Interfacial modification for high-power solid-state lithium batteries
journal, September 2008


Modification of Interface Between LiCoO[sub 2] Electrode and Li[sub 2]S–P[sub 2]S[sub 5] Solid Electrolyte Using Li[sub 2]O–SiO[sub 2] Glassy Layers
journal, January 2009

  • Sakuda, Atsushi; Kitaura, Hirokazu; Hayashi, Akitoshi
  • Journal of The Electrochemical Society, Vol. 156, Issue 1
  • DOI: 10.1149/1.3005972

Improvement of High-Rate Performance of All-Solid-State Lithium Secondary Batteries Using LiCoO[sub 2] Coated with Li[sub 2]O–SiO[sub 2] Glasses
journal, January 2008

  • Sakuda, Atsushi; Kitaura, Hirokazu; Hayashi, Akitoshi
  • Electrochemical and Solid-State Letters, Vol. 11, Issue 1
  • DOI: 10.1149/1.2795837

Nanoscale Interface Modification of LiCoO 2 by Al 2 O 3 Atomic Layer Deposition for Solid-State Li Batteries
journal, January 2012

  • Woo, Jae Ha; Trevey, James E.; Cavanagh, Andrew S.
  • Journal of The Electrochemical Society, Vol. 159, Issue 7
  • DOI: 10.1149/2.085207jes

Negating interfacial impedance in garnet-based solid-state Li metal batteries
journal, December 2016

  • Han, Xiaogang; Gong, Yunhui; Fu, Kun (Kelvin)
  • Nature Materials, Vol. 16, Issue 5
  • DOI: 10.1038/nmat4821

In-situ Li7La3Zr2O12/LiCoO2 interface modification for advanced all-solid-state battery
journal, August 2014


Interface Limited Lithium Transport in Solid-State Batteries
journal, December 2013

  • Santhanagopalan, Dhamodaran; Qian, Danna; McGilvray, Thomas
  • The Journal of Physical Chemistry Letters, Vol. 5, Issue 2
  • DOI: 10.1021/jz402467x

Bulk-Type Lithium Metal Secondary Battery with Indium Thin Layer at Interface between Li Electrode and Li2S-P2S5 Solid Electrolyte
journal, January 2012


Stabilizing lithium plating-stripping reaction between a lithium phosphorus oxynitride glass electrolyte and copper thin film by platinum insertion
journal, February 2011


Enhancing utilization of lithium metal electrodes in all-solid-state batteries by interface modification with gold thin films
journal, March 2016


Plating a Dendrite-Free Lithium Anode with a Polymer/Ceramic/Polymer Sandwich Electrolyte
journal, July 2016

  • Zhou, Weidong; Wang, Shaofei; Li, Yutao
  • Journal of the American Chemical Society, Vol. 138, Issue 30
  • DOI: 10.1021/jacs.6b05341

A Battery Made from a Single Material
journal, April 2015