A ruthenium water oxidation catalyst containing a bipyridine glycoluril ligand

Mane, Vishwanath S.; Kumbhar, Avinash S.; Thummel, Randolph P.

doi:10.1039/c7dt02485a

A ruthenium water oxidation catalyst containing a bipyridine glycoluril ligand

Journal Article · Sun Jan 01 04:00:00 EST 2017 · Dalton Transactions

DOI:https://doi.org/10.1039/c7dt02485a· OSTI ID:1539912

^[1]; ^[2]; Thummel, Randolph P. ^[3]

Department of chemistry; Savitribai Phule Pune University; Pune-411007; India; DOE/OSTI
Department of chemistry; Savitribai Phule Pune University; Pune-411007; India
Department of Chemistry; University of Houston; Texas-77204-5003; USA

A mononuclear ruthenium complex [Ru(tpy)(bpg)H₂O]²⁺bearing a bipyridine glycoluril ligand (bpg) = 4b,5,7,7a-tetrahydro-4b,7a-nepiminomethan-oimino-6H-imidazo[4,5-f][1,10]phenanthroline-6,13-dione acts as a robust water oxidation catalyst (WOC) at pH = 1 using Ce(iv) as a sacrificial oxidant.

Research Organization:: Univ. of Houston, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-07ER15888

OSTI ID:: 1539912

Journal Information:: Dalton Transactions, Journal Name: Dalton Transactions Journal Issue: 38 Vol. 46; ISSN 1477-9226; ISSN ICHBD9

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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