A ruthenium water oxidation catalyst containing a bipyridine glycoluril ligand
- Department of chemistry; Savitribai Phule Pune University; Pune-411007; India
- Department of Chemistry; University of Houston; Texas-77204-5003; USA
A mononuclear ruthenium complex [Ru(tpy)(bpg)H2O]2+bearing a bipyridine glycoluril ligand (bpg) = 4b,5,7,7a-tetrahydro-4b,7a-nepiminomethan-oimino-6H-imidazo[4,5-f][1,10]phenanthroline-6,13-dione acts as a robust water oxidation catalyst (WOC) at pH = 1 using Ce(iv) as a sacrificial oxidant.
- Research Organization:
- Univ. of Houston, TX (United States)
- Sponsoring Organization:
- USDOE Office of Science (SC)
- DOE Contract Number:
- FG02-07ER15888
- OSTI ID:
- 1539912
- Journal Information:
- Dalton Transactions, Vol. 46, Issue 38; ISSN 1477-9226
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
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