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Title: Structural diversity in Cu( i ) complexes of the PNP ligand: from pincer to binuclear coordination modes and their effects upon the electrochemical and photophysical properties

Journal Article · · Dalton Transactions
DOI:https://doi.org/10.1039/c7dt02244a· OSTI ID:1539910
ORCiD logo [1];  [1];  [1];  [1]; ORCiD logo [2];  [2];  [3]; ORCiD logo [3]; ORCiD logo [1]
  1. Facultad de Química y Biología; Universidad de Santiago de Chile; Santiago; Chile
  2. Department of Chemistry and Biochemistry; University of Notre Dame; Notre Dame; USA
  3. Department of Chemistry and Biochemistry; University of Notre Dame; Notre Dame; USA; Radiation Research Building
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The versatility of PNP ligand in coordinating to Cu(i) resulted in the formation of emissive complexes with notable structural differences.

Research Organization:
Univ. of Notre Dame, IN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FC02-04ER15533
OSTI ID:
1539910
Journal Information:
Dalton Transactions, Vol. 46, Issue 39; ISSN 1477-9226
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (26)

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Modularly Designed Transition Metal PNP and PCP Pincer Complexes based on Aminophosphines: Synthesis and Catalytic Applications journal February 2008
A new class of PN3-pincer ligands for metal–ligand cooperative catalysis journal June 2015
Platinum Group Organometallics Based on “Pincer” Complexes: Sensors, Switches, and Catalysts journal October 2001
Cu(I) and Cu(II) complexes of a pyridine-based pincer ligand journal March 2002
Cu I Complexes with a Noninnocent PNP Ligand: Selective Dearomatization and Electrophilic Addition Reactivity journal August 2009
Diphosphinine Derivatives of Terpyridine: A New Class of Neutral π-Accepting PNP-Pincer Ligands journal August 2008
Synthesis, Structures, and Catalytic Properties of Late-Transition-Metal 2,6-Bis(2-phosphaethenyl)pyridine Complexes journal October 2007
Coinage metal complexes supported by a “PN 3 P” scaffold journal January 2015
Synthesis and reactivity of copper(i) complexes containing a bis(imidazolin-2-imine) pincer ligand journal January 2007
Copper(I) and Gold(I) Complexes withN,N′-Bis(diphenylphosphino)-2,6-diaminopyridine as Ligand: Synthesis and Molecular Structures journal April 2006
Copper(I) Complexes of Pyridine-Bridged Phosphaalkene-Oxazoline Pincer Ligands journal June 2016
Darstellung, Eigenschaften und Molek�lstrukturen von Komplexen des versteiften dreiz�hnigen Chelatliganden N, N?-Bis(diphenylphosphino)-2, 6-diaminopyridin mit MII - und M0-�bergangsmetallen [MII = Ni, Pd, Pt; M0 = Cr, Mo, W] journal February 1987
Luminescent complexes beyond the platinum group: the d10 avenue journal January 2008
Methanol triggered ligand flip isomerization in a binuclear copper(i) complex and the luminescence response journal January 2011
Dioxygen-Binding Kinetics and Thermodynamics of a Series of Dicopper(I) Complexes with Bis[2-(2-pyridyl)ethyl]amine Tridendate Chelators Forming Side-On Peroxo-Bridged Dicopper(II) Adducts journal December 2000
SHELXT – Integrated space-group and crystal-structure determination journal January 2015
Crystal structure refinement with SHELXL journal January 2015
Structural variation in copper( i ) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ 4 journal January 2007
Unfolding of the [Cu 2 (1,3-bis(9-methyl-1,10-phenanthrolin-2-yl)propane) 2 ] 2+ Helicate. Coupling of the Chlorocarbon Dehalogenation to the Unfolding Process journal May 2010
A Highly Emissive Cu 2 N 2 Diamond Core Complex Supported by a [PNP] - Ligand journal February 2005
Amido-Bridged Cu 2 N 2 Diamond Cores that Minimize Structural Reorganization and Facilitate Reversible Redox Behavior between a Cu 1 Cu 1 and a Class III Delocalized Cu 1.5 Cu 1.5 Species journal March 2004
2,2′:6′,2″-Terpyridine (terpy) acting as a fluxional bidentate ligand. Part 4. cis-[M(C 6 F 5 ) 2 (terpy)](M = Pd or Pt): nuclear magnetic resonance studies of their solution dynamics and crystal structure of cis-[Pd(C 6 F 5 ) 2 (terpy)] journal January 1994
Evaluation of Diimine Ligand Exchange on Cu(I) journal May 2001
Flash photolysis and quenching studies of copper(I) systems in the presence of Lewis bases: inorganic exciplexes? journal September 1987

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