Cobalt-to-vanadium charge transfer in polyoxometalate water oxidation catalysts revealed by 2p3d resonant inelastic X-ray scattering

Liu, Boyang; Glass, Elliot N.; Wang, Ru-Pan; Cui, Yi-Tao; Harada, Yoshihisa; Huang, Di-Jing; Schuppler, Stefan; Hill, Craig L.; de Groot, Frank M.  F.

doi:10.1039/c7cp06786k

Title: Cobalt-to-vanadium charge transfer in polyoxometalate water oxidation catalysts revealed by 2p3d resonant inelastic X-ray scattering

Journal Article · Mon Jan 01 00:00:00 EST 2018 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/c7cp06786k· OSTI ID:1539885

^[1];

^[2]; Wang, Ru-Pan ^[1];

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^[3]; Huang, Di-Jing ^[4]; Schuppler, Stefan ^[5];

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^[1]

Inorganic Chemistry & Catalysis; Debye Institute for Nanomaterials Science; Utrecht University; The Netherlands
Department of Chemistry; Emory University; Atlanta; USA
Institute for Solid State Physics; The University of Tokyo; Chiba 277-8581; Japan
National Synchrotron Radiation Research Center; Hsinchu 30076; Taiwan
Institut fuer Festkorperphysik; Karlsruhe Institute of Technology; Karlsruhe 76021; Germany

2p3d RIXS spectra reveal electronic structures ofCo4V2WOC, which offers insights into its enhanced catalytic activity thanCo4P2WOC.

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Research Organization:: Emory Univ., Atlanta, GA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-07ER15906

OSTI ID:: 1539885

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 20, Issue 6; ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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Title: Cobalt-to-vanadium charge transfer in polyoxometalate water oxidation catalysts revealed by 2p3d resonant inelastic X-ray scattering

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