Arrested disproportionation in trivalent, mononuclear, and non-metallocene complexes of Zr( iii ) and Hf( iii )

Grant, Lauren N.; Miehlich, Matthias E.; Meyer, Karsten; Mindiola, Daniel J.

doi:10.1039/c7cc08815a

Arrested disproportionation in trivalent, mononuclear, and non-metallocene complexes of Zr( iii ) and Hf( iii )

Journal Article · Mon Jan 01 04:00:00 EST 2018 · ChemComm

DOI:https://doi.org/10.1039/c7cc08815a· OSTI ID:1539868

^[1]; Miehlich, Matthias E. ^[2]; ^[2]; ^[3]

Department of Chemistry; University of Pennsylvania; Philadelphia; USA; DOE/OSTI
Inorganic Chemistry; Department of Chemistry and Pharmacy; Friedrich-Alexander University Erlangen-Nürnberg (FAU); 91058 Erlangen; Germany
Department of Chemistry; University of Pennsylvania; Philadelphia; USA

Reduction of [(PN)₂MCl₂] (M = Zr (1), and Hf (2)) both readily prepared by transmetallation of 2 LiPN with [MCl₄(THF)₂], with a slight excess of KC₈, resulted in the isolation of the trivalent complexes [(PN)₂MCl] (M = Zr (3), and Hf (4)).

Research Organization:: Indiana Univ., Bloomington, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-07ER15893

OSTI ID:: 1539868

Journal Information:: ChemComm, Journal Name: ChemComm Journal Issue: 16 Vol. 54; ISSN CHCOFS; ISSN 1359-7345

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

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