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Arrested disproportionation in trivalent, mononuclear, and non-metallocene complexes of Zr( iii ) and Hf( iii )

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/c7cc08815a· OSTI ID:1539868
 [1];  [2];  [2];  [1]
  1. Department of Chemistry; University of Pennsylvania; Philadelphia; USA
  2. Inorganic Chemistry; Department of Chemistry and Pharmacy; Friedrich-Alexander University Erlangen-Nürnberg (FAU); 91058 Erlangen; Germany
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Reduction of [(PN)2MCl2] (M = Zr (1), and Hf (2)) both readily prepared by transmetallation of 2 LiPN with [MCl4(THF)2], with a slight excess of KC8, resulted in the isolation of the trivalent complexes [(PN)2MCl] (M = Zr (3), and Hf (4)).

Research Organization:
Indiana Univ., Bloomington, IN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FG02-07ER15893
OSTI ID:
1539868
Journal Information:
ChemComm, Vol. 54, Issue 16; ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

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Mixed-sandwich complexes of zirconium(III) and hafnium(III): Potential analogues of [U(η-C8H6{SiiPr3-1,4}2)(η-Cp∗)] for cyclooligomerisation of CO December 2010
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Synthesis, Characterization, and Catalytic Activities for the Polymerization of Olefins Promoted by Zirconium(III) and Titanium(III) Allyl Complexes July 2001
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Catalytic Hydrosilylation of the Carbonyl Functionality via a Transient Nickel Hydride Complex April 2009
Synthesis, structure, and spectroscopic properties of copper( II ) compounds containing nitrogen–sulphur donor ligands; the crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2′-yl)-2,6-dithiaheptane]copper( II ) perchlorate January 1984
Molecular titanium nitrides: nucleophiles unleashed January 2017
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