Effects of Cu–Ni Bimetallic Catalyst Composition and Support on Activity, Selectivity, and Stability for Furfural Conversion to 2-Methyfuran

Seemala, Bhogeswararao; Cai, Charles M.; Kumar, Rajeev; Wyman, Charles E.; Christopher, Phillip

doi:10.1021/acssuschemeng.7b03572

Effects of Cu–Ni Bimetallic Catalyst Composition and Support on Activity, Selectivity, and Stability for Furfural Conversion to 2-Methyfuran

Journal Article · Thu Dec 21 04:00:00 EST 2017 · ACS Sustainable Chemistry & Engineering

DOI:https://doi.org/10.1021/acssuschemeng.7b03572· OSTI ID:1539619

Seemala, Bhogeswararao ^[1]; Cai, Charles M. ^[2]; Kumar, Rajeev ^[2]; Wyman, Charles E. ^[2];

Bourns College of Engineering - Center for Environmental and Research Technology (CE-CERT), University of California, Riverside, 1084 Columbia Avenue, Riverside, California 92507, United States; DOE/OSTI
Bourns College of Engineering - Center for Environmental and Research Technology (CE-CERT), University of California, Riverside, 1084 Columbia Avenue, Riverside, California 92507, United States

Not provided.

Research Organization:: Univ. of California, Riverside, CA (United States)

Sponsoring Organization:: USDOE Office of Energy Efficiency and Renewable Energy (EERE)

DOE Contract Number:: EE0007006

OSTI ID:: 1539619

Journal Information:: ACS Sustainable Chemistry & Engineering, Journal Name: ACS Sustainable Chemistry & Engineering Journal Issue: 2 Vol. 6; ISSN 2168-0485

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (49)

Pt–Sn alloy phases and coke mobility over Pt–Sn/Al2O3 and Pt–Sn/ZnAl2O4 catalysts for propane dehydrogenation Vu, Bao Khanh; Song, Myoung Bok; Ahn, In Young Applied Catalysis A: General, Vol. 400, Issue 1-2 https://doi.org/10.1016/j.apcata.2011.03.057	journal	June 2011
Surface segregation energies in transition-metal alloys Ruban, A. V.; Skriver, H. L.; Nørskov, J. K. Physical Review B, Vol. 59, Issue 24 https://doi.org/10.1103/PhysRevB.59.15990	journal	June 1999
The H2 Pressure Dependence of Hydrodeoxygenation Selectivities for Furfural Over Pt/C Catalysts Luo, Jing; Monai, Matteo; Yun, Hongseok Catalysis Letters, Vol. 146, Issue 4 https://doi.org/10.1007/s10562-016-1705-x	journal	February 2016
Nitrogen Dissociation via Reaction with Lithium Alloys Yamaguchi, Shotaro; Ichikawa, Takayuki; Wang, Yongming ACS Omega, Vol. 2, Issue 3 https://doi.org/10.1021/acsomega.6b00498	journal	March 2017
Alloy catalysts: the concepts Ponec, Vladimir Applied Catalysis A: General, Vol. 222, Issue 1-2 https://doi.org/10.1016/S0926-860X(01)00828-6	journal	December 2001
In situ IR spectroscopic studies of Ni surface segregation induced by CO adsorption on Cu–Ni/SiO2 bimetallic catalysts Yao, Yunxi; Goodman, D. Wayne Physical Chemistry Chemical Physics, Vol. 16, Issue 8 https://doi.org/10.1039/c3cp54997f	journal	January 2014
The Composition and Structure of Pd−Au Surfaces Yi, C. -W.; Luo, K.; Wei, T. The Journal of Physical Chemistry B, Vol. 109, Issue 39 https://doi.org/10.1021/jp053515r	journal	October 2005
High-performance Ag–Co alloy catalysts for electrochemical oxygen reduction Holewinski, Adam; Idrobo, Juan-Carlos; Linic, Suljo Nature Chemistry, Vol. 6, Issue 9 https://doi.org/10.1038/nchem.2032	journal	August 2014
Upgrading Furfurals to Drop-in Biofuels: An Overview Bohre, Ashish; Dutta, Saikat; Saha, Basudeb ACS Sustainable Chemistry & Engineering, Vol. 3, Issue 7 https://doi.org/10.1021/acssuschemeng.5b00271	journal	June 2015
XRD and XPS Study of Cu−Ni Interactions on Reduced Copper−Nickel−Aluminum Oxide Solid Solution Catalysts Naghash, A. R.; Etsell, T. H.; Xu, S. Chemistry of Materials, Vol. 18, Issue 10 https://doi.org/10.1021/cm051910o	journal	April 2006
Synthesis of renewable diesel with hydroxyacetone and 2-methyl-furan Li, Guangyi; Li, Ning; Li, Shanshan Chemical Communications, Vol. 49, Issue 51 https://doi.org/10.1039/c3cc42296h	journal	January 2013
Thermal Stability of Furfural Dunlop, A. P.; Peters, Fredus N. Industrial & Engineering Chemistry, Vol. 32, Issue 12 https://doi.org/10.1021/ie50372a027	journal	December 1940
Ethanol steam reforming over Ni-Cu/Al2O3-MyOz (M = Si, La, Mg, and Zn) catalysts Zhang, Lifeng; Liu, Jie; Li, Wei Journal of Natural Gas Chemistry, Vol. 18, Issue 1 https://doi.org/10.1016/S1003-9953(08)60078-X	journal	March 2009
Tackling CO Poisoning with Single-Atom Alloy Catalysts Liu, Jilei; Lucci, Felicia R.; Yang, Ming Journal of the American Chemical Society, Vol. 138, Issue 20 https://doi.org/10.1021/jacs.6b03339	journal	May 2016
Single atom alloy surface analogs in Pd0.18Cu15 nanoparticles for selective hydrogenation reactions Boucher, Matthew B.; Zugic, Branko; Cladaras, George Physical Chemistry Chemical Physics, Vol. 15, Issue 29 https://doi.org/10.1039/c3cp51538a	journal	January 2013
Identification of General Linear Relationships between Activation Energies and Enthalpy Changes for Dissociation Reactions at Surfaces Michaelides, Angelos; Liu, Z. -P.; Zhang, C. J. Journal of the American Chemical Society, Vol. 125, Issue 13 https://doi.org/10.1021/ja027366r	journal	April 2003
Isolated Metal Atom Geometries as a Strategy for Selective Heterogeneous Hydrogenations Kyriakou, Georgios; Boucher, Matthew B.; Jewell, April D. Science, Vol. 335, Issue 6073 https://doi.org/10.1126/science.1215864	journal	March 2012
Transient Behavior of Ni@NiO _x Functionalized SrTiO ₃ in Overall Water Splitting Han, Kai; Kreuger, Tomas; Mei, Bastian ACS Catalysis, Vol. 7, Issue 3 https://doi.org/10.1021/acscatal.6b03662	journal	January 2017
Kinetics and mechanism of hydrogenation of furfural on Cu/SiO2 catalysts Sitthisa, Surapas; Sooknoi, Tawan; Ma, Yuguang Journal of Catalysis, Vol. 277, Issue 1 https://doi.org/10.1016/j.jcat.2010.10.005	journal	January 2011
Study of copper-nickel alloy formation on silica supports by the magnetostatic and other methods Robertson, S. Journal of Catalysis, Vol. 39, Issue 2 https://doi.org/10.1016/0021-9517(75)90328-0	journal	August 1975
Pd–Ru/TiO ₂ catalyst – an active and selective catalyst for furfural hydrogenation Aldosari, Obaid F.; Iqbal, Sarwat; Miedziak, Peter J. Catalysis Science & Technology, Vol. 6, Issue 1 https://doi.org/10.1039/C5CY01650A	journal	January 2016
Characterization and performance of platinum-iridium reforming catalysts Rasser, J.; Beindorff, W.; Scholten, J. Journal of Catalysis, Vol. 59, Issue 2 https://doi.org/10.1016/S0021-9517(79)80026-3	journal	October 1979
Catalytic Transfer Hydrogenation/Hydrogenolysis for Reductive Upgrading of Furfural and 5-(Hydroxymethyl)furfural Scholz, David; Aellig, Christof; Hermans, Ive ChemSusChem, Vol. 7, Issue 1 https://doi.org/10.1002/cssc.201300774	journal	November 2013
Efficient catalytic conversion of lignocellulosic biomass into renewable liquid biofuels via furan derivatives Wang, Jianjian; Liu, Xiaohui; Hu, Bicheng RSC Adv., Vol. 4, Issue 59 https://doi.org/10.1039/C4RA04900D	journal	January 2014
A versatile bi-metallic copper–cobalt catalyst for liquid phase hydrogenation of furfural to 2-methylfuran Srivastava, Sanjay; Jadeja, G. C.; Parikh, Jigisha RSC Advances, Vol. 6, Issue 2 https://doi.org/10.1039/C5RA15048E	journal	January 2016
Iron-Promotion of Silica-Supported Copper Catalysts for Furfural Hydrodeoxygenation Sheng, Huibo; Lobo, Raul F. ChemCatChem, Vol. 8, Issue 21 https://doi.org/10.1002/cctc.201600540	journal	September 2016
Furfural: A Promising Platform Compound for Sustainable Production of C ₄ and C ₅ Chemicals Li, Xiaodan; Jia, Pei; Wang, Tiefeng ACS Catalysis, Vol. 6, Issue 11 https://doi.org/10.1021/acscatal.6b01838	journal	October 2016
Bimetallic catalysts for the Fischer–Tropsch reaction Calderone, V. Roberto; Shiju, N. Raveendran; Ferré, Daniel Curulla Green Chemistry, Vol. 13, Issue 8 https://doi.org/10.1039/c0gc00919a	journal	January 2011
Universality in Heterogeneous Catalysis Nørskov, J. K.; Bligaard, T.; Logadottir, A. Journal of Catalysis, Vol. 209, Issue 2 https://doi.org/10.1006/jcat.2002.3615	journal	July 2002
CO-induced Pd segregation and the effect of subsurface Pd on CO adsorption on CuPd surfaces Padama, A. A. B.; Villaos, R. A. B.; Albia, J. R. Journal of Physics: Condensed Matter, Vol. 29, Issue 2 https://doi.org/10.1088/0953-8984/29/2/025005	journal	November 2016
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering Huber, George W.; Iborra, Sara; Corma, Avelino Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098 https://doi.org/10.1021/cr068360d	journal	September 2006
Predictive Structure–Reactivity Models for Rapid Screening of Pt-Based Multimetallic Electrocatalysts for the Oxygen Reduction Reaction Xin, Hongliang; Holewinski, Adam; Linic, Suljo ACS Catalysis, Vol. 2, Issue 1 https://doi.org/10.1021/cs200462f	journal	November 2011
Pd–Au bimetallic catalysts: understanding alloy effects from planar models and (supported) nanoparticles Gao, Feng; Goodman, D. Wayne Chemical Society Reviews, Vol. 41, Issue 24 https://doi.org/10.1039/c2cs35160a	journal	January 2012
Furfuryl alcohol from furfural hydrogenation over copper supported on SBA-15 silica catalysts Vargas-Hernández, D.; Rubio-Caballero, J. M.; Santamaría-González, J. Journal of Molecular Catalysis A: Chemical, Vol. 383-384 https://doi.org/10.1016/j.molcata.2013.11.034	journal	March 2014
Platinum-rhodium synergism in three-way automotive catalysts Oh, S. Journal of Catalysis, Vol. 98, Issue 1 https://doi.org/10.1016/0021-9517(86)90307-6	journal	March 1986
Complete Oxidation of CO, Ethanol, and Ethyl Acetate over Copper Oxide Supported on Titania and Ceria Modified Titania Larsson, Per-Olof; Andersson, Arne Journal of Catalysis, Vol. 179, Issue 1 https://doi.org/10.1006/jcat.1998.2198	journal	October 1998
Alloy catalysts designed from first principles Greeley, Jeff; Mavrikakis, Manos Nature Materials, Vol. 3, Issue 11 https://doi.org/10.1038/nmat1223	journal	October 2004
Selective hydrogenation of furfural and levulinic acid to biofuels on the ecofriendly Cu–Fe catalyst Yan, Kai; Chen, Aicheng Fuel, Vol. 115 https://doi.org/10.1016/j.fuel.2013.06.042	journal	January 2014
Hydrogen production by water–gas shift reaction over bimetallic Cu–Ni catalysts supported on La-doped mesoporous ceria Lin, Jiann-Horng; Biswas, Prakash; Guliants, Vadim V. Applied Catalysis A: General, Vol. 387, Issue 1-2 https://doi.org/10.1016/j.apcata.2010.08.003	journal	October 2010
The stability of Pt–M (M=first row transition metal) alloy catalysts and its effect on the activity in low temperature fuel cells Antolini, Ermete; Salgado, Jose R. C.; Gonzalez, Ernesto R. Journal of Power Sources, Vol. 160, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.03.006	journal	October 2006
Efficient and versatile CuNi alloy nanocatalysts for the highly selective hydrogenation of furfural Wu, Jun; Gao, Guang; Li, Jinlei Applied Catalysis B: Environmental, Vol. 203 https://doi.org/10.1016/j.apcatb.2016.10.038	journal	April 2017
Enhanced Photocatalytic Degradation and Mineralization of Furfural Using UVC/TiO ₂ /GAC Composite in Aqueous Solution Ghasemi, Bahram; Anvaripour, Bagher; Jorfi, Sahand International Journal of Photoenergy, Vol. 2016 https://doi.org/10.1155/2016/2782607	journal	January 2016
Support Induced Control of Surface Composition in Cu–Ni/TiO ₂ Catalysts Enables High Yield Co-Conversion of HMF and Furfural to Methylated Furans Seemala, Bhogeswararao; Cai, Charles M.; Wyman, Charles E. ACS Catalysis, Vol. 7, Issue 6 https://doi.org/10.1021/acscatal.7b01095	journal	May 2017
Coupling metal halides with a co-solvent to produce furfural and 5-HMF at high yields directly from lignocellulosic biomass as an integrated biofuels strategy Cai, Charles M.; Nagane, Nikhil; Kumar, Rajeev Green Chem., Vol. 16, Issue 8 https://doi.org/10.1039/C4GC00747F	journal	January 2014
Fouling of a platinum-rhenium reforming catalyst using model reforming reactions Jossens, L. Journal of Catalysis, Vol. 76, Issue 2 https://doi.org/10.1016/0021-9517(82)90257-3	journal	August 1982
Synthesis of Diesel or Jet Fuel Range Cycloalkanes with 2-Methylfuran and Cyclopentanone from Lignocellulose Li, Guangyi; Li, Ning; Wang, Xinkui Energy & Fuels, Vol. 28, Issue 8 https://doi.org/10.1021/ef500676z	journal	July 2014
Insights into the activity, selectivity and stability of heterogeneous catalysts in the continuous flow hydroconversion of furfural Garcia-Olmo, Antonio J.; Yepez, Alfonso; Balu, Alina M. Catalysis Science & Technology, Vol. 6, Issue 13 https://doi.org/10.1039/C6CY00249H	journal	January 2016
Selectivity in catalysis by alloys Clarke, J. K. A. Chemical Reviews, Vol. 75, Issue 3 https://doi.org/10.1021/cr60295a002	journal	June 1975
Promotion of the long-term stability of reforming Ni catalysts by surface alloying Nikolla, E.; Schwank, J.; Linic, S. Journal of Catalysis, Vol. 250, Issue 1 https://doi.org/10.1016/j.jcat.2007.04.020	journal	August 2007

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Direct synthesis of furfuryl alcohol from furfural: catalytic performance of monometallic and bimetallic Mo and Ru phosphides Bonita, Yolanda; Jain, Varsha; Geng, Feiyang Catalysis Science & Technology, Vol. 9, Issue 14 https://doi.org/10.1039/c9cy00705a	journal	January 2019
Controlling catalytic activity and selectivity for partial hydrogenation by tuning the environment around active sites in iridium complexes bonded to supports Babucci, Melike; Fang, Chia-Yu; Perez-Aguilar, Jorge E. Chemical Science, Vol. 10, Issue 9 https://doi.org/10.1039/c8sc05287e	journal	January 2019
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Metal Phosphide:A Highly Efficient Catalyst for the Selective Hydrodeoxygenation of Furfural to 2‐Methylfuran Wang, Yazhou; Liu, Fei; Han, Han ChemistrySelect, Vol. 3, Issue 27 https://doi.org/10.1002/slct.201800929	journal	July 2018
Mechanistic insights into hydrodeoxygenation of phenol on bimetallic phosphide catalysts Jain, Varsha; Bonita, Yolanda; Brown, Alicia Catalysis Science & Technology, Vol. 8, Issue 16 https://doi.org/10.1039/c8cy00977e	journal	January 2018

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