Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS 2 Nanosheets: The Dual Interfacial Effect

Zhao, Shuo; Jin, Renxi; Song, Yongbo; Zhang, Hui; House, Stephen D.; Yang, Judith C.; Jin, Rongchao

doi:10.1002/smll.201701519

Title: Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS ₂ Nanosheets: The Dual Interfacial Effect

Journal Article · Mon Jul 24 00:00:00 EDT 2017 · Small

DOI:https://doi.org/10.1002/smll.201701519· OSTI ID:1537628

Zhao, Shuo ^[1]; Jin, Renxi ^[1]; Song, Yongbo ^[1]; Zhang, Hui ^[1]; House, Stephen D. ^[2]; Yang, Judith C. ^[2]; Jin, Rongchao ^[1]

Department of Chemistry, Carnegie Mellon University, Pittsburgh PA 15213 USA
Chemical and Petroleum Engineering, and Physics, University of Pittsburgh, Pittsburgh PA 15261 USA

Not provided.

Cite

Export

Save

Research Organization:: Univ. of Illinois at Urbana-Champaign, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: FG02-03ER15476

OSTI ID:: 1537628

Journal Information:: Small, Vol. 13, Issue 43; ISSN 1613-6810

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (47)

A molecule-like PtAu24(SC6H13)18 nanocluster as an electrocatalyst for hydrogen production Kwak, Kyuju; Choi, Woojun; Tang, Qing Nature Communications, Vol. 8, Issue 1 https://doi.org/10.1038/ncomms14723	journal	March 2017
Sustainable Hydrogen Production Turner, J. A. Science, Vol. 305, Issue 5686 https://doi.org/10.1126/science.1103197	journal	August 2004
A Review of Photocatalysis using Self-organized TiO ₂ Nanotubes and Other Ordered Oxide Nanostructures Paramasivam, Indhumati; Jha, Himendra; Liu, Ning Small, Vol. 8, Issue 20 https://doi.org/10.1002/smll.201200564	journal	September 2012
Gold Nanoclusters Promote Electrocatalytic Water Oxidation at the Nanocluster/CoSe ₂ Interface Zhao, Shuo; Jin, Renxi; Abroshan, Hadi Journal of the American Chemical Society, Vol. 139, Issue 3 https://doi.org/10.1021/jacs.6b12529	journal	January 2017
High-Performance Water Electrolysis System with Double Nanostructured Superaerophobic Electrodes Xu, Wenwen; Lu, Zhiyi; Wan, Pengbo Small, Vol. 12, Issue 18 https://doi.org/10.1002/smll.201600189	journal	March 2016
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution Greeley, Jeff; Jaramillo, Thomas F.; Bonde, Jacob Nature Materials, Vol. 5, Issue 11, p. 909-913 https://doi.org/10.1038/nmat1752	journal	October 2006
Recent progress in alkaline water electrolysis for hydrogen production and applications Zeng, Kai; Zhang, Dongke Progress in Energy and Combustion Science, Vol. 36, Issue 3 https://doi.org/10.1016/j.pecs.2009.11.002	journal	June 2010
Biomimetic Hydrogen Evolution: MoS ₂ Nanoparticles as Catalyst for Hydrogen Evolution Hinnemann, Berit; Moses, Poul Georg; Bonde, Jacob Journal of the American Chemical Society, Vol. 127, Issue 15 https://doi.org/10.1021/ja0504690	journal	April 2005
Identification of Active Edge Sites for Electrochemical H₂ Evolution from MoS₂ Nanocatalysts Jaramillo, T. F.; Jorgensen, K. P.; Bonde, J. Science, Vol. 317, Issue 5834, p. 100-102 https://doi.org/10.1126/science.1141483	journal	July 2007
Enhanced Hydrogen Evolution Catalysis from Chemically Exfoliated Metallic MoS ₂ Nanosheets Lukowski, Mark A.; Daniel, Andrew S.; Meng, Fei Journal of the American Chemical Society, Vol. 135, Issue 28 https://doi.org/10.1021/ja404523s	journal	May 2013
Electrochemical tuning of vertically aligned MoS2 nanofilms and its application in improving hydrogen evolution reaction Wang, H.; Lu, Z.; Xu, S. Proceedings of the National Academy of Sciences, Vol. 110, Issue 49 https://doi.org/10.1073/pnas.1316792110	journal	November 2013
Defect-Rich MoS ₂ Ultrathin Nanosheets with Additional Active Edge Sites for Enhanced Electrocatalytic Hydrogen Evolution Xie, Junfeng; Zhang, Hao; Li, Shuang Advanced Materials, Vol. 25, Issue 40 https://doi.org/10.1002/adma.201302685	journal	August 2013
Ultrathin MoS ₂ Nanoplates with Rich Active Sites as Highly Efficient Catalyst for Hydrogen Evolution Yan, Ya; Xia, BaoYu; Ge, Xiaoming ACS Applied Materials & Interfaces, Vol. 5, Issue 24 https://doi.org/10.1021/am404843b	journal	December 2013
Three-Dimensional Hierarchical Frameworks Based on MoS ₂ Nanosheets Self-Assembled on Graphene Oxide for Efficient Electrocatalytic Hydrogen Evolution Zhou, Weijia; Zhou, Kai; Hou, Dongman ACS Applied Materials & Interfaces, Vol. 6, Issue 23 https://doi.org/10.1021/am506545g	journal	November 2014
Enhanced Electrocatalytic Properties of Transition-Metal Dichalcogenides Sheets by Spontaneous Gold Nanoparticle Decoration Kim, Jaemyung; Byun, Segi; Smith, Alexander J. The Journal of Physical Chemistry Letters, Vol. 4, Issue 8 https://doi.org/10.1021/jz400507t	journal	March 2013
Au Nanoparticle-Modified MoS ₂ Nanosheet-Based Photoelectrochemical Cells for Water Splitting Yin, Zongyou; Chen, Bo; Bosman, Michel Small, Vol. 10, Issue 17 https://doi.org/10.1002/smll.201400124	journal	March 2014
Plasmonic hot electron enhanced MoS ₂ photocatalysis in hydrogen evolution Kang, Yimin; Gong, Yongji; Hu, Zhijian Nanoscale, Vol. 7, Issue 10 https://doi.org/10.1039/C4NR07303G	journal	January 2015
Hot Electron of Au Nanorods Activates the Electrocatalysis of Hydrogen Evolution on MoS ₂ Nanosheets Shi, Yi; Wang, Jiong; Wang, Chen Journal of the American Chemical Society, Vol. 137, Issue 23 https://doi.org/10.1021/jacs.5b01732	journal	June 2015
Pd coated MoS 2 nanoflowers for highly efficient hydrogen evolution reaction under irradiation Li, B. B.; Qiao, S. Z.; Zheng, X. R. Journal of Power Sources, Vol. 284 https://doi.org/10.1016/j.jpowsour.2015.03.021	journal	June 2015
Solution-phase epitaxial growth of noble metal nanostructures on dispersible single-layer molybdenum disulfide nanosheets Huang, Xiao; Zeng, Zhiyuan; Bao, Shuyu Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms2472	journal	February 2013
Epitaxial Growth of Hetero-Nanostructures Based on Ultrathin Two-Dimensional Nanosheets Tan, Chaoliang; Zhang, Hua Journal of the American Chemical Society, Vol. 137, Issue 38 https://doi.org/10.1021/jacs.5b03590	journal	September 2015
Enhanced electrocatalytic activity for hydrogen evolution reaction from self-assembled monodispersed molybdenum sulfidenanoparticles on an Au electrode Wang, Tanyuan; Liu, Lu; Zhu, Zhiwei Energy Environ. Sci., Vol. 6, Issue 2 https://doi.org/10.1039/C2EE23513G	journal	January 2013
Edge-Specific Au/Ag Functionalization-Induced Conductive Paths in Armchair MoS ₂ Nanoribbons Li, Weifeng; Guo, Meng; Zhang, Gang Chemistry of Materials, Vol. 26, Issue 19 https://doi.org/10.1021/cm5021756	journal	September 2014
Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities Jin, Rongchao; Zeng, Chenjie; Zhou, Meng Chemical Reviews, Vol. 116, Issue 18 https://doi.org/10.1021/acs.chemrev.5b00703	journal	September 2016
Atomically precise metal nanoclusters: stable sizes and optical properties Jin, Rongchao Nanoscale, Vol. 7, Issue 5 https://doi.org/10.1039/C4NR05794E	journal	January 2015
Emergence of hierarchical structural complexities in nanoparticles and their assembly Zeng, Chenjie; Chen, Yuxiang; Kirschbaum, Kristin Science, Vol. 354, Issue 6319 https://doi.org/10.1126/science.aak9750	journal	December 2016
Photovoltaic Properties of Glutathione-Protected Gold Clusters Adsorbed on TiO ₂ Electrodes Sakai, Nobuyuki; Tatsuma, Tetsu Advanced Materials, Vol. 22, Issue 29 https://doi.org/10.1002/adma.200904317	journal	June 2010
Selective determination of dopamine using quantum-sized gold nanoparticles protected with charge selective ligands Kwak, Kyuju; Kumar, S. Senthil; Lee, Dongil Nanoscale, Vol. 4, Issue 14 https://doi.org/10.1039/c2nr30481c	journal	January 2012
Oxygen Electroreduction Catalyzed by Gold Nanoclusters: Strong Core Size Effects Chen, Wei; Chen, Shaowei Angewandte Chemie International Edition, Vol. 48, Issue 24, p. 4386-4389 https://doi.org/10.1002/anie.200901185	journal	June 2009
Experimental and Computational Investigation of Au ₂₅ Clusters and CO ₂ : A Unique Interaction and Enhanced Electrocatalytic Activity Kauffman, Douglas R.; Alfonso, Dominic; Matranga, Christopher Journal of the American Chemical Society, Vol. 134, Issue 24 https://doi.org/10.1021/ja303259q	journal	June 2012
Atomically Precise Gold Nanoclusters as New Model Catalysts Li, Gao; Jin, Rongchao Accounts of Chemical Research, Vol. 46, Issue 8 https://doi.org/10.1021/ar300213z	journal	March 2013
Mechanistic insights from atomically precise gold nanocluster-catalyzed reduction of 4-nitrophenol Zhao, Shuo; Das, Anindita; Zhang, Hui Progress in Natural Science: Materials International, Vol. 26, Issue 5 https://doi.org/10.1016/j.pnsc.2016.08.009	journal	October 2016
A Grand Avenue to Au Nanocluster Electrochemiluminescence Hesari, Mahdi; Ding, Zhifeng Accounts of Chemical Research, Vol. 50, Issue 2 https://doi.org/10.1021/acs.accounts.6b00441	journal	January 2017
Near-Infrared Electrogenerated Chemiluminescence from Aqueous Soluble Lipoic Acid Au Nanoclusters Wang, Tanyu; Wang, Dengchao; Padelford, Jonathan W. Journal of the American Chemical Society, Vol. 138, Issue 20 https://doi.org/10.1021/jacs.6b03037	journal	May 2016
Evolution from the plasmon to exciton state in ligand-protected atomically precise gold nanoparticles Zhou, Meng; Zeng, Chenjie; Chen, Yuxiang Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13240	journal	October 2016
The Magic Au ₆₀ Nanocluster: A New Cluster-Assembled Material with Five Au ₁₃ Building Blocks Song, Yongbo; Fu, Fangyu; Zhang, Jun Angewandte Chemie International Edition, Vol. 54, Issue 29 https://doi.org/10.1002/anie.201501830	journal	May 2015
Correlating the Crystal Structure of A Thiol-Protected Au₂₅ Cluster and Optical Properties Zhu, Manzhou; Aikens, Christine M.; Hollander, Frederick J. Journal of the American Chemical Society, Vol. 130, Issue 18, p. 5883-5885 https://doi.org/10.1021/ja801173r	journal	May 2008
Structural patterns at all scales in a nonmetallic chiral Au ₁₃₃ (SR) ₅₂ nanoparticle Zeng, Chenjie; Chen, Yuxiang; Kirschbaum, Kristin Science Advances, Vol. 1, Issue 2 https://doi.org/10.1126/sciadv.1500045	journal	March 2015
Gold Quantum Boxes: On the Periodicities and the Quantum Confinement in the Au ₂₈ , Au ₃₆ , Au ₄₄ , and Au ₅₂ Magic Series Zeng, Chenjie; Chen, Yuxiang; Iida, Kenji Journal of the American Chemical Society, Vol. 138, Issue 12 https://doi.org/10.1021/jacs.5b12747	journal	March 2016
Ultrasmall Fe ₃ O ₄ Nanoparticle/MoS ₂ Nanosheet Composites with Superior Performances for Lithium Ion Batteries Chen, Yu; Song, Bohang; Tang, Xiaosheng Small, Vol. 10, Issue 8 https://doi.org/10.1002/smll.201302879	journal	December 2013
One-pot synthesis of atomically monodisperse, thiol-functionalized Au ₂₅ nanoclusters Wu, Zhikun; Suhan, Joseph; Jin, Rongchao J. Mater. Chem., Vol. 19, Issue 5 https://doi.org/10.1039/B815983A	journal	January 2009
Controllable Growth and Transfer of Monolayer MoS ₂ on Au Foils and Its Potential Application in Hydrogen Evolution Reaction Shi, Jianping; Ma, Donglin; Han, Gao-Feng ACS Nano, Vol. 8, Issue 10 https://doi.org/10.1021/nn503211t	journal	September 2014
Synergistic Catalytic Effect of MoS ₂ Nanoparticles Supported on Gold Nanoparticle Films for a Highly Efficient Oxygen Reduction Reaction Wang, Tanyuan; Zhuo, Junqiao; Chen, Ye ChemCatChem, Vol. 6, Issue 7 https://doi.org/10.1002/cctc.201402038	journal	May 2014
CO oxidation by MoS ₂ -supported Au ₁₉ nanoparticles: effects of vacancy formation and tensile strain Kwon, Soonho; Shin, Kihyun; Bang, Kihoon Physical Chemistry Chemical Physics, Vol. 18, Issue 19 https://doi.org/10.1039/C6CP01100D	journal	January 2016
Crystal structure of Au ₂₅ (SePh) ₁₈ nanoclusters and insights into their electronic, optical and catalytic properties Song, Yongbo; Zhong, Juan; Yang, Sha Nanoscale, Vol. 6, Issue 22 https://doi.org/10.1039/C4NR04631E	journal	January 2014
Conversion of Anionic [Au ₂₅ (SCH ₂ CH ₂ Ph) ₁₈ ] ⁻ Cluster to Charge Neutral Cluster via Air Oxidation Zhu, Manzhou; Eckenhoff, William T.; Pintauer, Tomislav The Journal of Physical Chemistry C, Vol. 112, Issue 37 https://doi.org/10.1021/jp805786p	journal	July 2008
Au25 Clusters as Electron-Transfer Catalysts Induced the Intramolecular Cascade Reaction of 2-nitrobenzonitrile Chong, Hanbao; Li, Peng; Wang, Shuxin Scientific Reports, Vol. 3, Issue 1 https://doi.org/10.1038/srep03214	journal	November 2013

Similar Records

Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS ₂ Nanosheets: The Dual Interfacial Effect

Journal Article · Mon Jul 24 00:00:00 EDT 2017 · Small · OSTI ID:1537628

Zhao, Shuo; Jin, Renxi; Song, Yongbo; +4 more

Gold Nanoclusters Promote Electrocatalytic Water Oxidation at the Nanocluster/CoSe ₂ Interface

Journal Article · Fri Jan 13 00:00:00 EST 2017 · Journal of the American Chemical Society · OSTI ID:1537628

Zhao, Shuo; Jin, Renxi; Abroshan, Hadi; +7 more

Boosting CO₂ Electrochemical Reduction with Atomically Precise Surface Modification on Gold Nanoclusters

Journal Article · Fri Feb 12 00:00:00 EST 2021 · Angewandte Chemie (International Edition) · OSTI ID:1537628

Li, Site; Nagarajan, Anantha Venkataraman; Alfonso, Dominic R.; +4 more

Related Subjects

Chemistry
Science & Technology - Other Topics
Materials Science
Physics

Title: Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS 2 Nanosheets: The Dual Interfacial Effect

Citation Formats

References (47)

Similar Records

Related Subjects

Title: Atomically Precise Gold Nanoclusters Accelerate Hydrogen Evolution over MoS ₂ Nanosheets: The Dual Interfacial Effect