skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Steric and Electronic Factors Affecting the Conformation of Bimetallic Cu I Complexes: Effect of the Aliphatic Spacer of Tetracoordinating Schiff-Base Ligands

Journal Article · · Chemistry - A European Journal
 [1];  [1];  [1];  [1];  [1];  [1];  [1];  [2];  [2];  [2]; ORCiD logo [1]
  1. Facultad de Química y Biología, Departamento de Química de los, Materiales, Universidad de Santiago de Chile, Av. Libertador Bernardo O'Higgins 3363, Estación Central Santiago Chile
  2. Department of Chemistry and Biochemistry, University of Notre Dame, 46556-5670 Notre Dame IN USA

Not provided.

Research Organization:
Univ. of Notre Dame, IN (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
FC02-04ER15533
OSTI ID:
1537524
Journal Information:
Chemistry - A European Journal, Vol. 24, Issue 52; ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English

References (52)

Toward Self-Organization and Complex Matter journal March 2002
Dynamic control of chirality and self-assembly of double-stranded helicates with light journal November 2016
Lanthanide Helicates Self-Assembled in Water:  A New Class of Highly Stable and Luminescent Dimetallic Carboxylates journal November 1999
Helices and Helicates: Beautiful Supramolecular Motifs with Emerging Applications journal January 2004
Optically pure, water-stable metallo-helical ‘flexicate’ assemblies with antibiotic activity journal November 2011
Iron(II) supramolecular helicates interfere with the HIV-1 Tat–TAR RNA interaction critical for viral replication journal July 2016
Asymmetric triplex metallohelices with high and selective activity against cancer cells journal August 2014
Anticancer metallohelices: nanomolar potency and high selectivity journal January 2016
Binding of a Designed Anti-Cancer Drug to the Central Cavity of an RNA Three-Way Junction journal August 2013
Binding of a Designed Anti-Cancer Drug to the Central Cavity of an RNA Three-Way Junction journal August 2013
Molecular Recognition of a Three-Way DNA Junction by a Metallosupramolecular Helicate journal February 2006
Molecular Recognition of a Three-Way DNA Junction by a Metallosupramolecular Helicate journal February 2006
DNA structure control by polycationic species: Polyamine, cobalt ammines, and di-metallo transition metal chelates journal January 2000
Intramolecular DNA Coiling Mediated by a Metallo-Supramolecular Cylinder journal March 2001
Intramolecular DNA Coiling Mediated by a Metallo-Supramolecular Cylinder journal March 2001
Intramolecular DNA coiling mediated by metallo-supramolecular cylinders: Differential binding of P and M helical enantiomers journal April 2002
Effect of bridging ligand structure on the thermal stability and DNA binding properties of iron(ii) triple helicates journal January 2009
DNA Three-Way Junction with a Dinuclear Iron(II) Supramolecular Helicate at the Center:  A NMR Structural Study journal August 2007
From Mesocates to Helicates: Structural, Magnetic and Chiro-Optical Studies on Nickel(II) Supramolecular Assemblies Derived from Tetradentate Schiff Bases journal April 2018
How Do They Know? Influencing the Relative Stereochemistry of the Complex Units of Dinuclear Triple-Stranded Helicate-Type Complexes journal October 2000
Dicatechol ligands: novel building-blocks for metallo-supramolecular chemistry journal January 1998
Dynamic Behavior of Anionic Binuclear Helicate- andmeso-Helicate-Type Coordination Compounds journal May 1997
“Let's Twist Again”Double-Stranded, Triple-Stranded, and Circular Helicates journal November 2001
Effect of Ligand Spacer on Metallosupramolecular Architectures: From a Dinuclear Copper(II) Double Helicate to a Tetranuclear Copper(II) Complex journal December 2008
A 3D network of helicates fully assembled by π-stacking interactions journal January 2003
Double-stranded dimetallic helicates: assembling–disassembling driven by the Cu I /Cu II redox change and the principle of homochiral recognition journal January 2014
Spontaneous assembly of double-stranded helicates from oligobipyridine ligands and copper(I) cations: structure of an inorganic double helix. journal May 1987
Molecular helicity in inorganic complexes; bi- and tri-nuclear complexes of 2,2′:6′,2″:6″,2″′:6″′,2″″:6″″,2″″′-sexipyridine and the crystal and molecular structure of bis(µ-2,2′:6′,2″:6″,2″′:6″′,2″″:6″″,2″″′-sexipyridine-κ 3 N,N′,N″:κ 3 N″′,N″″,N″″′) dicadmium hexafluorophosphate–acetonitrile (1/4) journal January 1991
Chasing Weak Forces: Hierarchically Assembled Helicates as a Probe for the Evaluation of the Energetics of Weak Interactions journal November 2017
Steric control of the formation of dinuclear double helicate and dinuclear meso-helicate assemblies journal January 2013
Metal self-recognition: a pathway to control the formation of dihelicates and mesocates journal January 2012
Evaluation of Diimine Ligand Exchange on Cu(I) journal May 2001
Copper(II) and Copper(I) Complexes with an Open-Chain N 4 Schiff Base Ligand Modeling CuZn Superoxide Dismutase:  Structural and Spectroscopic Characterization and Kinetics of Electron Transfer journal July 2000
First assembly of copper(I) naphthyridine-based helicates journal January 2000
Unfolding of the [Cu 2 (1,3-bis(9-methyl-1,10-phenanthrolin-2-yl)propane) 2 ] 2+ Helicate. Coupling of the Chlorocarbon Dehalogenation to the Unfolding Process journal May 2010
Resolution and characterization of helicate dimer and trimer complexes of 1,3-bis(9-methyl-1,10-phenanthrolin-2-yl)propane with copper(i) journal January 2013
Structures and properties of copper(II) and copper(I) complexes containing an ethane-bridged dimeric phenanthroline ligand journal September 1992
Formation of dihelicate and mononuclear complexes from ethane-bridged dimeric bipyridine or phenanthroline ligands with copper(I), cobalt(II), and iron(II) cations journal May 1991
A novel double-stranded dinuclear copper(I) helicate having a photoluminescent CuI2N8 chromophore journal November 2000
Asymmetric Transformation of a Double-Stranded, Dicopper(I) Helicate Containing Achiral Bis(bidentate) Schiff Bases journal February 2006
Synthesis of Open-Chain Schiff-Base Ligand 1,3-Di(pyridine-2-carboxaldimino)propane Incorporating Nitrogen-Donor Atoms and Crystal Structures of Its CoII, CuII and ZnII Complexes. journal January 1998
Density-functional exchange-energy approximation with correct asymptotic behavior journal September 1988
Fully optimized contracted Gaussian basis sets of triple zeta valence quality for atoms Li to Kr journal April 1994
Balanced basis sets of split valence, triple zeta valence and quadruple zeta valence quality for H to Rn: Design and assessment of accuracy journal January 2005
A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu journal April 2010
Charge-transfer absorption and emission of Cu(NN)2+ systems journal December 1987
Structural variation in copper( i ) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ 4 journal January 2007
{μ-Bis[1-(pyridin-2-yl)ethylidene]ethane-1,2-diamine-κ 2 N , N ′}bis[iodo(triphenylphosphine-κ P )copper(I)] acetonitrile disolvate journal October 2006
Dioxygen-Binding Kinetics and Thermodynamics of a Series of Dicopper(I) Complexes with Bis[2-(2-pyridyl)ethyl]amine Tridendate Chelators Forming Side-On Peroxo-Bridged Dicopper(II) Adducts journal December 2000
Software update: the ORCA program system, version 4.0: Software update journal July 2017
Semiempirical hybrid density functional with perturbative second-order correlation journal January 2006
The calculation of small molecular interactions by the differences of separate total energies. Some procedures with reduced errors journal October 1970