skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Cu-Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low-Pressure CO 2 Hydrogenation to Methanol

Journal Article · · Advanced Materials Interfaces
 [1];  [1];  [1];  [1];  [1];  [1]
  1. Department of Materials Science and Engineering and Institute of Materials Science, University of Connecticut, Storrs CT 06269-3136 USA

Not provided.

Research Organization:
Univ. of Connecticut, Storrs, CT (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
EE0006854
OSTI ID:
1537384
Journal Information:
Advanced Materials Interfaces, Vol. 5, Issue 3; ISSN 2196-7350
Publisher:
Wiley-VCH
Country of Publication:
United States
Language:
English

References (80)

Worldwide innovations in the development of carbon capture technologies and the utilization of CO2 journal January 2012
Effects of oxide carriers on surface functionality and process performance of the Cu–ZnO system in the synthesis of methanol via CO2 hydrogenation journal April 2013
Photocatalytic CO2 conversion to methanol by Cu2O/graphene/TNA heterostructure catalyst in a visible-light-driven dual-chamber reactor journal September 2016
Perovskite-based nanocubes with simultaneously improved visible-light absorption and charge separation enabling efficient photocatalytic CO2 reduction journal December 2016
An overview of current status of carbon dioxide capture and storage technologies journal November 2014
The Potential Applications of Nanoporous Materials for the Adsorption, Separation, and Catalytic Conversion of Carbon Dioxide journal March 2014
Catalytic valorization of CO2 via methanol synthesis with Ga-promoted Cu–ZnO–ZrO2 catalysts journal October 2013
Gas Conversion to Liquid Fuels and Chemicals: The Methanol Route‐Catalysis and Processes Development journal January 2009
Beyond Oil and Gas: The Methanol Economy journal April 2005
Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol journal March 2014
Thermodynamic investigation of methanol and dimethyl ether synthesis from CO2 Hydrogenation journal March 2000
Catalytic performance for CO2 conversion to methanol of gallium-promoted copper-based catalysts: influence of metallic precursors journal November 2001
Correlations between synthesis, precursor, and catalyst structure and activity of a large set of CuO/ZnO/Al2O3 catalysts for methanol synthesis journal September 2008
Mechanism of Methanol Synthesis on Cu through CO 2 and CO Hydrogenation journal February 2011
Mechanism of the hydrogenation of CO2 to methanol on a Cu(100) surface: dipped adcluster model study journal November 1999
In situ DRIFT study of low-temperature methanol synthesis mechanism on Cu/ZnO catalysts from CO-containing syngas using ethanol promoter journal November 2004
Hydrogenation of CO2 to methanol and CO on Cu/ZnO/Al2O3: Is there a common intermediate or not? journal August 2015
Controlled assembly of Cu nanoparticles on pyridinic-N rich graphene for electrochemical reduction of CO2 to ethylene journal June 2016
In Situ Investigations of Structural Changes in Cu/ZnO Catalysts journal September 2000
Atom-Resolved Imaging of Dynamic Shape Changes in Supported Copper Nanocrystals journal March 2002
Methanol Synthesis and Reverse Water–Gas Shift Kinetics over Cu(110) Model Catalysts: Structural Sensitivity journal July 1996
The role of copper and zinc oxide in methanol synthesis catalysts journal January 1990
The Active Site of Methanol Synthesis over Cu/ZnO/Al2O3 Industrial Catalysts journal April 2012
Role of Lattice Strain and Defects in Copper Particles on the Activity of Cu/ZnO/Al2O3 Catalysts for Methanol Synthesis journal September 2007
Quantifying the promotion of Cu catalysts by ZnO for methanol synthesis journal May 2016
Synthesis, characterization and activity pattern of Cu–ZnO/ZrO2 catalysts in the hydrogenation of carbon dioxide to methanol journal July 2007
Methanol synthesis reactions over a CuZr based catalyst investigated using periodic variations of reactant concentrations journal August 2001
Influence of ZrO 2 Structure and Copper Electronic State on Activity of Cu/ZrO 2 Catalysts in Methanol Synthesis from CO 2 journal September 2014
Highly effective conversion of CO2 to methanol over supported and promoted copper-based catalysts: influence of support and promoter journal February 2001
Active sites for CO 2 hydrogenation to methanol on Cu/ZnO catalysts journal March 2017
The Role of the Oxide Component in the Development of Copper Composite Catalysts for Methanol Synthesis journal May 2013
Formation of a ZnO Overlayer in Industrial Cu/ZnO/Al 2 O 3 Catalysts Induced by Strong Metal-Support Interactions journal February 2015
Fe-Doped CoP Nanoarray: A Monolithic Multifunctional Catalyst for Highly Efficient Hydrogen Generation journal October 2016
High-Performance Electrolytic Oxygen Evolution in Neutral Media Catalyzed by a Cobalt Phosphate Nanoarray journal December 2016
Scalable Integration of Highly Uniform Mn x Co 3− x O 4 Nanosheet Array onto Ceramic Monolithic Substrates for Low-Temperature Propane Oxidation journal October 2017
Robust 3-D configurated metal oxide nano-array based monolithic catalysts with ultrahigh materials usage efficiency and catalytic performance tunability journal September 2013
Nanostructured Zinc Oxide Nanorods with Copper Nanoparticles as a Microreformation Catalyst journal September 2009
Zinc oxide nanorods based catalysts for hydrogen production by steam reforming of methanol journal April 2012
Selective Electroreduction of CO 2 toward Ethylene on Nano Dendritic Copper Catalysts at High Current Density journal January 2017
Understanding low temperature oxidation activity of nanoarray-based monolithic catalysts: from performance observation to structural and chemical insights journal December 2016
ZnO/perovskite core–shell nanorod array based monolithic catalysts with enhanced propane oxidation and material utilization efficiency at low temperature journal December 2015
Nanowire Array Structures for Photocatalytic Energy Conversion and Utilization: A Review of Design Concepts, Assembly and Integration, and Function Enabling journal August 2016
Nano-array based monolithic catalysts: Concept, rational materials design and tunable catalytic performance journal December 2015
Nano-array integrated monolithic devices: toward rational materials design and multi-functional performance by scalable nanostructures assembly journal January 2016
Transient behavior of Cu/ZnO-based methanol synthesis catalysts journal February 2009
In Situ Electron Energy Loss Spectroscopy Studies of Gas-Dependent Metal−Support Interactions in Cu/ZnO Catalysts journal August 2003
Hydrogenation of CO2 to value-added products—A review and potential future developments journal March 2014
Intermetallic GaPd 2 Nanoparticles on SiO 2 for Low-Pressure CO 2 Hydrogenation to Methanol: Catalytic Performance and In Situ Characterization journal September 2015
Hydrogenation of CO2 to methanol over In2O3 catalyst journal December 2015
Development of an active Ga2O3 supported palladium catalyst for the synthesis of methanol from carbon dioxide and hydrogen journal May 1995
Nanocrystalline zirconia as catalyst support in methanol synthesis journal January 2005
Development of highly stable catalyst for methanol synthesis from carbon dioxide journal January 2014
Surface active structure of ultra-fine Cu/ZrO2 catalysts used for the CO2+H2 to methanol reaction journal September 2001
Methanol synthesis from CO2 and H2 over gallium promoted copper-based supported catalysts. Effect of hydrocarbon impurities in the CO2/H2 source journal October 2001
Comparative study of hydrotalcite-derived supported Pd2Ga and PdZn intermetallic nanoparticles as methanol synthesis and methanol steam reforming catalysts journal September 2012
Bimetallic Pd–Cu catalysts for selective CO2 hydrogenation to methanol journal July 2015
The changing nature of the active site of Cu-Zn-Zr catalysts for the CO2 hydrogenation reaction to methanol journal June 2014
Effect of pressure on the mechanisms of the CO2/H2 reaction on a CO-precipitated CuO/ZnO/Al2O3 catalyst journal April 2011
Impact of K and Ba promoters on CO 2 hydrogenation over Cu/Al 2 O 3 catalysts at high pressure journal January 2013
High Efficiency Cu-ZnO Hydrogenation Catalyst: The Tailoring of Cu-ZnO Interface Sites by Molecular Layer Deposition journal August 2015
The chemical modification seen in the Cu/ZnO methanol synthesis catalysts journal January 2000
Catalytic synthesis of methanol from CO/H2I. Phase composition, electronic properties, and activities of the Cu/ZnO/M2O3 catalysts journal March 1979
Enhanced photoresponse of ZnO nanorods-based self-powered photodetector by piezotronic interface engineering journal October 2014
Facile synthesis of ZnO nanopencil arrays for photoelectrochemical water splitting journal July 2014
Fabrication and photoresponse of ZnO nanowires/CuO coaxial heterojunction journal January 2013
Atomic-scale studies of metallic nanocluster catalysts by in situ high-resolution transmission electron microscopy journal January 2006
In situ XRD and HRTEM studies on the evolution of the Cu/ZnO methanol synthesis catalyst during its reduction and re-oxidation journal January 2004
Yttria-Stabilized Zirconia Supported Copper Oxide Catalyst journal May 1996
The role of metal oxides in promoting a copper catalyst for methanol synthesis journal January 1994
Hydrogenation of CO2 to methanol over CuCeTiO catalysts journal June 2017
The role of copper particle size in low pressure methanol synthesis via CO 2 hydrogenation over Cu/ZnO catalysts journal January 2015
Preparation of a coprecipitated Cu/ZnO catalyst for the methanol synthesis from CO2 — effects of the calcination and reduction conditions on the catalytic performance journal February 2001
CO2 hydrogenation to methanol over Cu/ZnO/ZrO2 catalysts prepared by precipitation-reduction method journal August 2016
Highly active copper-ceria and copper-ceria-titania catalysts for methanol synthesis from CO2 journal July 2014
Fundamental studies of methanol synthesis from CO2 hydrogenation on Cu(111), Cu clusters, and Cu/ZnO(0001̄) journal January 2010
Scalable continuous flow synthesis of ZnO nanorod arrays in 3-D ceramic honeycomb substrates for low-temperature desulfurization journal January 2017
Methanol technology developments for the new millennium journal November 2001
An improved N2O-method for measuring Cu-dispersion journal July 2004
Dispersion and surface states of copper catalysts by temperature-programmed-reduction of oxidized surfaces (s-TPR) journal March 2005
Construction of Cu/ZrO2/Al2O3 composites for ethanol synthesis: Synergies of ternary sites for cascade reaction journal May 2015

Similar Records

Cu‐Decorated ZnO Nanorod Array Integrated Structured Catalysts for Low‐Pressure CO 2 Hydrogenation to Methanol
Journal Article · Fri Dec 01 00:00:00 EST 2017 · Advanced Materials Interfaces · OSTI ID:1537384

Optimization and understanding of ZnO nanoarray supported Cu-ZnO-Al2O3 catalyst for enhanced CO2 -methanol conversion at low temperature and pressure
Journal Article · Thu Feb 02 00:00:00 EST 2023 · Chemical Engineering Journal · OSTI ID:1537384

Hydrogenation of CO2 on ZnO/Cu(100) and ZnO/Cu(111) Catalysts: Role of Copper Structure and Metal–Oxide Interface in Methanol Synthesis
Journal Article · Mon Aug 21 00:00:00 EDT 2017 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry · OSTI ID:1537384

Related Subjects