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Title: Hafnium(IV) complexation with oxalate at variable temperatures

Abstract

Abstract Appropriate management of fission products in the reprocessing of spent nuclear fuel (SNF) is crucial in developing advanced reprocessing schemes. The addition of aqueous phase complexing agents can prevent the co-extraction of these fission products. A solvent extraction technique was used to study the complexation of Hf(IV) – an analog to fission product Zr(IV) – with oxalate at 15, 25, and 35°C in 1 M HClO

Authors:
;
Publication Date:
Research Org.:
Washington State Univ., Pullman, WA (United States)
Sponsoring Org.:
USDOE Office of Nuclear Energy (NE)
OSTI Identifier:
1537098
DOE Contract Number:  
NE0000674
Resource Type:
Journal Article
Journal Name:
Radiochimica Acta
Additional Journal Information:
Journal Volume: 105; Journal Issue: 5; Journal ID: ISSN 0033-8230
Publisher:
de Gruyter
Country of Publication:
United States
Language:
English
Subject:
Chemistry; Nuclear Science & Technology

Citation Formats

Friend, Mitchell T., and Wall, Nathalie A. Hafnium(IV) complexation with oxalate at variable temperatures. United States: N. p., 2017. Web. doi:10.1515/ract-2016-2686.
Friend, Mitchell T., & Wall, Nathalie A. Hafnium(IV) complexation with oxalate at variable temperatures. United States. doi:10.1515/ract-2016-2686.
Friend, Mitchell T., and Wall, Nathalie A. Sun . "Hafnium(IV) complexation with oxalate at variable temperatures". United States. doi:10.1515/ract-2016-2686.
@article{osti_1537098,
title = {Hafnium(IV) complexation with oxalate at variable temperatures},
author = {Friend, Mitchell T. and Wall, Nathalie A.},
abstractNote = {Abstract Appropriate management of fission products in the reprocessing of spent nuclear fuel (SNF) is crucial in developing advanced reprocessing schemes. The addition of aqueous phase complexing agents can prevent the co-extraction of these fission products. A solvent extraction technique was used to study the complexation of Hf(IV) – an analog to fission product Zr(IV) – with oxalate at 15, 25, and 35°C in 1 M HClO},
doi = {10.1515/ract-2016-2686},
journal = {Radiochimica Acta},
issn = {0033-8230},
number = 5,
volume = 105,
place = {United States},
year = {2017},
month = {1}
}