Role of grain size on redox induced compositional stresses in Pr doped ceria thin films

Sheth, Jay; Chen, Di; Tuller, Harry L.; Misture, Scott T.; Bishop, Sean R.; Sheldon, Brian W.

doi:10.1039/c7cp00088j

Title: Role of grain size on redox induced compositional stresses in Pr doped ceria thin films

Journal Article · Sun Jan 01 00:00:00 EST 2017 · Physical Chemistry Chemical Physics. PCCP (Print)

DOI:https://doi.org/10.1039/c7cp00088j· OSTI ID:1535187

^[1]; Chen, Di ^[2];

^[3]; Misture, Scott T. ^[4]; Bishop, Sean R. ^[3]; Sheldon, Brian W. ^[1]

School of Engineering; Brown University; Providence; USA
Materials Processing Center and Department of Materials Science and Engineering; Massachusetts Institute of Technology; Cambridge; USA
Materials Processing Center and Department of Materials Science and Engineering; Massachusetts Institute of Technology; Cambridge; USA; International Institute for Carbon Neutral Energy Research (WPI-I2CNER)
Kazuo Inamori School of Engineering; Alfred University; Alfred; USA

In-situwafer curvature and x-ray diffraction measurements were employed to investigate the grain size dependence of stress and strain in Pr doped ceria thin films.

Cite

Export

Save

Research Organization:: Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0002633

OSTI ID:: 1535187

Journal Information:: Physical Chemistry Chemical Physics. PCCP (Print), Vol. 19, Issue 19; ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

References (66)

Ceria-based solid electrolytes Inaba, H. Solid State Ionics, Vol. 83, Issue 1-2 https://doi.org/10.1016/0167-2738(95)00229-4	journal	January 1996
Electrical properties of ceria-based oxides and their application to solid oxide fuel cells Eguchi, K.; Setoguchi, T.; Inoue, T. Solid State Ionics, Vol. 52, Issue 1-3 https://doi.org/10.1016/0167-2738(92)90102-U	journal	May 1992
A micro-solid oxide fuel cell system as battery replacement Bieberle-Hütter, Anja; Beckel, Daniel; Infortuna, Anna Journal of Power Sources, Vol. 177, Issue 1 https://doi.org/10.1016/j.jpowsour.2007.10.092	journal	February 2008
A solid oxide fuel cell with a gadolinia-doped ceria anode: preparation and performance Marina, O. Solid State Ionics, Vol. 123, Issue 1-4 https://doi.org/10.1016/S0167-2738(99)00111-3	journal	August 1999
Development of solid oxide fuel cells based on a Ce(Gd)O2−x electrolyte film for intermediate temperature operation Sahibzada, M.; Steele, B. C. H.; Zheng, K. Catalysis Today, Vol. 38, Issue 4 https://doi.org/10.1016/S0920-5861(97)00055-2	journal	November 1997
Development of Solid-Oxide Fuel Cells That Operate at 500°C Doshi, Rajiv Journal of The Electrochemical Society, Vol. 146, Issue 4 https://doi.org/10.1149/1.1391758	journal	January 1999
Oxygen sensors based on semiconducting metal oxides: an overview Xu, Yulong; Zhou, Xiaohua; Sorensen, O. Toft Sensors and Actuators B: Chemical, Vol. 65, Issue 1-3 https://doi.org/10.1016/S0925-4005(99)00421-9	journal	June 2000
Use of XPS for the study of cerium-vanadium (electrochromic) mixed oxides Salvi, A. M.; Decker, F.; Varsano, F. Surface and Interface Analysis, Vol. 31, Issue 4 https://doi.org/10.1002/sia.986	journal	January 2001
Optical and structural properties of reactive ion beam sputter deposited CeO2 films Kanakaraju, S.; Mohan, S.; Sood, A. K. Thin Solid Films, Vol. 305, Issue 1-2 https://doi.org/10.1016/S0040-6090(97)00081-3	journal	August 1997
Chemical expansion of nonstoichiometric Pr0.1Ce0.9O2−δ: Correlation with defect equilibrium model Bishop, Sean R.; Tuller, Harry L.; Kuru, Yener Journal of the European Ceramic Society, Vol. 31, Issue 13 https://doi.org/10.1016/j.jeurceramsoc.2011.05.034	journal	November 2011
Thermo-Chemical Expansion in Strontium-Doped Lanthanum Cobalt Iron Oxide: Thermo-Chemical Expansion in LSCF Bishop, Sean R.; Duncan, Keith L.; Wachsman, Eric D. Journal of the American Ceramic Society, Vol. 93, Issue 12 https://doi.org/10.1111/j.1551-2916.2010.03991.x	journal	September 2010
Mechanical Properties of Ce Kushi, Takuto; Sato, Kazuhisa; Unemoto, Atsushi 219th ECS Meeting, ECS Transactions https://doi.org/10.1149/1.3570096	conference	January 2011
Oxygen Permeation in Thin, Dense Ce0.9Gd0.1O1.95-δ Membranes II. Experimental Determination Chatzichristodoulou, Christodoulos; So̸gaard, Martin; Glasscock, Julie Journal of The Electrochemical Society, Vol. 158, Issue 5 https://doi.org/10.1149/1.3559189	journal	January 2011
Chemically-induced stresses in gadolinium-doped ceria solid oxide fuel cell electrolytes Atkinson, A. Solid State Ionics, Vol. 95, Issue 3-4 https://doi.org/10.1016/S0167-2738(96)00588-7	journal	March 1997
An electrochemomechanical theory of defects in ionic solids. I. Theory Swaminathan, N.; Qu, J.; Sun, Y. Philosophical Magazine, Vol. 87, Issue 11 https://doi.org/10.1080/14786430601102973	journal	March 2007
Colossal Ionic Conductivity at Interfaces of Epitaxial ZrO2:Y2O3/SrTiO3 Heterostructures Garcia-Barriocanal, J.; Rivera-Calzada, A.; Varela, M. Science, Vol. 321, Issue 5889 https://doi.org/10.1126/science.1156393	journal	August 2008
Elastic strain at interfaces and its influence on ionic conductivity in nanoscaled solid electrolyte thin films—theoretical considerations and experimental studies Schichtel, N.; Korte, C.; Hesse, D. Physical Chemistry Chemical Physics, Vol. 11, Issue 17 https://doi.org/10.1039/b900148d	journal	January 2009
Oxygen ion diffusivity in strained yttria stabilized zirconia: where is the fastest strain? Kushima, Akihiro; Yildiz, Bilge Journal of Materials Chemistry, Vol. 20, Issue 23 https://doi.org/10.1039/c000259c	journal	January 2010
Understanding chemical expansion in perovskite-structured oxides Marrocchelli, Dario; Perry, Nicola H.; Bishop, Sean R. Physical Chemistry Chemical Physics, Vol. 17, Issue 15 https://doi.org/10.1039/C4CP05885B	journal	January 2015
New Insights into the Strain Coupling to Surface Chemistry, Electronic Structure, and Reactivity of La _0.7 Sr _0.3 MnO ₃ Jalili, Helia; Han, Jeong Woo; Kuru, Yener The Journal of Physical Chemistry Letters, Vol. 2, Issue 7 https://doi.org/10.1021/jz200160b	journal	March 2011
Investigation of the stability of ceria-gadolinia electrolytes in solid oxide fuel cell environments Badwal, S. Solid State Ionics, Vol. 121, Issue 1-4 https://doi.org/10.1016/S0167-2738(99)00044-2	journal	June 1999
Role of Point Defects in the Physical Properties of Fluorite Oxides Duncan, Keith L.; Wang, Yanli; Bishop, Sean R. Journal of the American Ceramic Society, Vol. 89, Issue 10 https://doi.org/10.1111/j.1551-2916.2006.01193.x	journal	October 2006
Elasticity of Solids with a Large Concentration of Point Defects Greenberg, M.; Wachtel, E.; Lubomirsky, I. Advanced Functional Materials, Vol. 16, Issue 1 https://doi.org/10.1002/adfm.200500289	journal	January 2006
Nonstoichiometry of Ce[sub 0.8]Gd[sub 0.2]O[sub 1.9 − x] Wang, Shaorong Journal of The Electrochemical Society, Vol. 144, Issue 11 https://doi.org/10.1149/1.1838139	journal	January 1997
Nonstoichiometry of Ce0.9Gd0.1O1.95âˆ’x Wang, S. Solid State Ionics, Vol. 107, Issue 1-2 https://doi.org/10.1016/S0167-2738(97)00519-5	journal	March 1998
Operando reduction of elastic modulus in (Pr, Ce)O2− thin films Swallow, Jessica G.; Kim, Jae Jin; Kabir, Mukul Acta Materialia, Vol. 105 https://doi.org/10.1016/j.actamat.2015.12.007	journal	February 2016
Effect of Microstructure and Composition on Ionic Conductivity of Rare-Earth Oxide-Doped Ceria Hong, Seong Jae Journal of The Electrochemical Society, Vol. 145, Issue 2 https://doi.org/10.1149/1.1838316	journal	January 1998
“Grain boundary effect” on ceria based solid solutions El Adham, K.; Hammou, A. Solid State Ionics, Vol. 9-10 https://doi.org/10.1016/0167-2738(83)90109-1	journal	December 1983
Defect thermodynamics and electrical properties of nanocrystalline oxides: pure and doped CeO2 Chiang, Y. -M.; Lavik, E. B.; Blom, D. A. Nanostructured Materials, Vol. 9, Issue 1-8 https://doi.org/10.1016/S0965-9773(97)00142-6	journal	January 1997
The “grain-boundary effect” in doped ceria solid electrolytes Wang, Da Yu; Nowick, A. S. Journal of Solid State Chemistry, Vol. 35, Issue 3 https://doi.org/10.1016/0022-4596(80)90529-0	journal	December 1980
Grain-Boundary Effect in Ceria Doped with Trivalent Cations: I, Electrical Measurements Gerhardt, R.; Nowick, A. S. Journal of the American Ceramic Society, Vol. 69, Issue 9 https://doi.org/10.1111/j.1151-2916.1986.tb07464.x	journal	September 1986
Grain-Boundary Effect in Ceria Doped with Trivalent Cations: II, Microstructure and Microanalysis Gerhardt, R.; Nowick, A. S.; Mochel, M. E. Journal of the American Ceramic Society, Vol. 69, Issue 9 https://doi.org/10.1111/j.1151-2916.1986.tb07465.x	journal	September 1986
Nonlinear Electrical Properties of Grain Boundaries in an Oxygen-Ion Conductor (CeO2 . Y2O3) Tanaka, Junzo; Baumard, Jean-Francois; Abelard, Pierre Journal of the American Ceramic Society, Vol. 70, Issue 9 https://doi.org/10.1111/j.1151-2916.1987.tb05732.x	journal	September 1987
Microstructure — ionic conductivity relationships in ceria-gadolinia electrolytes Christie, G. Solid State Ionics, Vol. 83, Issue 1-2 https://doi.org/10.1016/0167-2738(95)00155-7	journal	January 1996
Electrical conductivity and defect equilibria of Pr0.1Ce0.9O2−δ Bishop, Sean R.; Stefanik, Todd S.; Tuller, Harry L. Physical Chemistry Chemical Physics, Vol. 13, Issue 21 https://doi.org/10.1039/c0cp02920c	journal	January 2011
Coupling of strain, stress, and oxygen non-stoichiometry in thin film Pr _0.1 Ce _0.9 O _2−δ Sheth, J.; Chen, D.; Kim, J. J. Nanoscale, Vol. 8, Issue 36 https://doi.org/10.1039/C6NR04083G	journal	January 2016
Praseodymium-cerium oxide thin film cathodes: Study of oxygen reduction reaction kinetics Chen, Di; Bishop, Sean R.; Tuller, Harry L. Journal of Electroceramics, Vol. 28, Issue 1 https://doi.org/10.1007/s10832-011-9678-z	journal	January 2012
Defects and transport in Pr _x Ce _{1− x} O _2−δ : Composition trends Bishop, Sean R.; Stefanik, Todd S.; Tuller, Harry L. Journal of Materials Research, Vol. 27, Issue 15 https://doi.org/10.1557/jmr.2012.130	journal	June 2012
Electrical conductivity and grain boundary composition of Gd-doped and Gd/Pr co-doped ceria Bowman, William J.; Zhu, Jiangtao; Sharma, Renu Solid State Ionics, Vol. 272 https://doi.org/10.1016/j.ssi.2014.12.006	journal	April 2015
Design of nanostructured ceria-based solid electrolytes for development of IT-SOFC Mori, Toshiyuki; Buchanan, Richard; Ou, Ding Rong Journal of Solid State Electrochemistry, Vol. 12, Issue 7-8 https://doi.org/10.1007/s10008-007-0444-8	journal	November 2007
Compositional and structural characteristics of nano-sized domains in gadolinium-doped ceria Ye, Fei; Mori, Toshiyuki; Ou, Ding Rong Solid State Ionics, Vol. 179, Issue 21-26 https://doi.org/10.1016/j.ssi.2008.02.034	journal	September 2008
On the Conductivity Mechanism of Nanocrystalline Ceria Kim, Sangtae; Maier, Joachim Journal of The Electrochemical Society, Vol. 149, Issue 10 https://doi.org/10.1149/1.1507597	journal	January 2002
Grain size-dependent electrical conductivity of polycrystalline cerium oxide I. Experiments Tschöpe, A. Solid State Ionics, Vol. 139, Issue 3-4 https://doi.org/10.1016/S0167-2738(01)00678-6	journal	February 2001
Raman Spectroscopy of Nanocrystalline Ceria and Zirconia Thin Films Kosacki, Igor; Petrovsky, Vladimir; Anderson, Harlan U. Journal of the American Ceramic Society, Vol. 85, Issue 11 https://doi.org/10.1111/j.1151-2916.2002.tb00509.x	journal	November 2002
Oxygen nonstoichiometry of nanosized ceria powder Kim, Sangtae; Merkle, Rotraut; Maier, Joachim Surface Science, Vol. 549, Issue 3 https://doi.org/10.1016/j.susc.2003.12.002	journal	February 2004
Interface Defect Chemistry and Effective Conductivity in Polycrystalline Cerium Oxide Tsch�pe, Andreas Journal of Electroceramics, Vol. 14, Issue 1 https://doi.org/10.1007/s10832-005-6580-6	journal	January 2005
In situ oxygen surface exchange coefficient measurements on lanthanum strontium ferrite thin films via the curvature relaxation method Yang, Qing; Burye, Theodore E.; Lunt, Richard R. Solid State Ionics, Vol. 249-250 https://doi.org/10.1016/j.ssi.2013.07.025	journal	November 2013
Compositional Stresses in Polycrystalline Titania Films Bhatia, Sidharth; Sheldon, Brian W. Journal of the American Ceramic Society, Vol. 91, Issue 12 https://doi.org/10.1111/j.1551-2916.2008.02710.x	journal	December 2008
Monitoring Stress in Thin Films During Processing Chason, E.; Sheldon, B. W. Surface Engineering, Vol. 19, Issue 5 https://doi.org/10.1179/026708403225010118	journal	October 2003
Substrate curvature due to thin film mismatch strain in the nonlinear deformation range Freund, L. B. Journal of the Mechanics and Physics of Solids, Vol. 48, Issue 6-7 https://doi.org/10.1016/S0022-5096(99)00070-8	journal	June 2000
Chemomechanical properties and microstructural stability of nanocrystalline Pr-doped ceria: An in situ X-ray diffraction investigation Kuru, Y.; Bishop, S. R.; Kim, J. J. Solid State Ionics, Vol. 193, Issue 1 https://doi.org/10.1016/j.ssi.2011.04.012	journal	June 2011
Improving the Si Impurity Tolerance of Pr _0.1 Ce _0.9 O _2−δ SOFC Electrodes with Reactive Surface Additives Zhao, Liang; Perry, Nicola H.; Daio, Takeshi Chemistry of Materials, Vol. 27, Issue 8 https://doi.org/10.1021/acs.chemmater.5b00501	journal	April 2015
Non-stoichiometry in Oxide Thin Films: A Chemical Capacitance Study of the Praseodymium-Cerium Oxide System Chen, Di; Bishop, Sean R.; Tuller, Harry L. Advanced Functional Materials, Vol. 23, Issue 17 https://doi.org/10.1002/adfm.201202104	journal	November 2012
Grain boundary induced compositional stress in nanocrystalline ceria films Sheldon, Brian W.; Mandowara, Sunil; Rankin, Janet Solid State Ionics, Vol. 233 https://doi.org/10.1016/j.ssi.2012.11.006	journal	February 2013
Segregation Effects at Grain Boundaries in Fluorite-Structured Ceramics Lei, Yuanyuan; Ito, Yasuo; Browning, Nigel D. Journal of the American Ceramic Society, Vol. 85, Issue 9 https://doi.org/10.1111/j.1151-2916.2002.tb00460.x	journal	September 2002
Effect of grain size on elastic modulus and hardness of nanocrystalline ZrO ₂ -3 wt% Y ₂ O ₃ ceramic Chaim, R.; Hefetz, M. Journal of Materials Science, Vol. 39, Issue 9 https://doi.org/10.1023/B:JMSC.0000025832.93840.b0	journal	May 2004
Elastic moduli of grain boundaries in nanocrystalline MgO ceramics Yeheskel, Ori; Chaim, Rachman; Shen, Zhijian Journal of Materials Research, Vol. 20, Issue 3 https://doi.org/10.1557/JMR.2005.0094	journal	March 2005
Ionic conduction in nanocrystalline materials Tuller, H. Solid State Ionics, Vol. 131, Issue 1-2 https://doi.org/10.1016/S0167-2738(00)00629-9	journal	June 2000
The grain boundary effect in heavily doped cerium oxide Tschope, A.; Kilassonia, S.; Birringer, R. Solid State Ionics, Vol. 173, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.07.052	journal	September 2004
The effect of segregated transition metal ions on the grain boundary resistivity of gadolinium doped ceria: Alteration of the space charge potential Avilaparedes, H.; Kim, S. Solid State Ionics, Vol. 177, Issue 35-36 https://doi.org/10.1016/j.ssi.2006.08.017	journal	November 2006
Dopant-concentration dependence of grain-boundary conductivity in ceria: A space-charge analysis Avila-Paredes, Hugo J.; Choi, Kwanghoon; Chen, Chien-Ting Journal of Materials Chemistry, Vol. 19, Issue 27 https://doi.org/10.1039/b904583j	journal	January 2009
Blocking Grain Boundaries in Yttria-Doped and Undoped Ceria Ceramics of High Purity Guo, Xin; Sigle, Wilfried; Maier, Joachim Journal of the American Ceramic Society, Vol. 86, Issue 1 https://doi.org/10.1111/j.1151-2916.2003.tb03281.x	journal	January 2003
Elastic moduli of Ce0.9Gd0.1O2−δ at high temperatures under controlled atmospheres Amezawa, Koji; Kushi, Takuto; Sato, Kazuhisa Solid State Ionics, Vol. 198, Issue 1 https://doi.org/10.1016/j.ssi.2011.07.009	journal	September 2011
The elastic modulus of pure and doped ceria Wachtel, Ellen; Lubomirsky, Igor Scripta Materialia, Vol. 65, Issue 2 https://doi.org/10.1016/j.scriptamat.2010.09.021	journal	July 2011
Defect equilibria and chemical expansion in non-stoichiometric undoped and gadolinium-doped cerium oxide Bishop, S. R.; Duncan, K. L.; Wachsman, E. D. Electrochimica Acta, Vol. 54, Issue 5 https://doi.org/10.1016/j.electacta.2008.09.026	journal	February 2009
Physical Chemistry of Ionic Materials: Ions and Electrons in Solids Maier, Joachim https://doi.org/10.1002/0470020229	book	April 2004

Similar Records

Intrinsic stress in ZrN thin films: Evaluation of grain boundary contribution from in situ wafer curvature and ex situ x-ray diffraction techniques

Journal Article · Tue May 01 00:00:00 EDT 2012 · Journal of Applied Physics · OSTI ID:1535187

Koutsokeras, L E; Abadias, G

Mono-textured nanocrystalline thin films with pronounced stress-gradients: On the role of grain boundaries in the stress evolution

Journal Article · Wed May 28 00:00:00 EDT 2014 · Journal of Applied Physics · OSTI ID:1535187

Mitterer, C.; Jäger, E.; Sartory, B.; +2 more

Thin-film chemical expansion of ceria based solid solutions: laser vibrometry study

Journal Article · Thu Nov 11 00:00:00 EST 2021 · Zeitschrift fuer Physikalische Chemie · OSTI ID:1535187

Wulfmeier, Hendrik; Kohlmann, Dhyan; Defferriere, Thomas; +4 more

Related Subjects

Chemistry
Physics

Title: Role of grain size on redox induced compositional stresses in Pr doped ceria thin films

Citation Formats

References (66)

Similar Records

Related Subjects