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Title: Incipient class II mixed valency in a plutonium solid-state compound

Journal Article · · Nature Chemistry
DOI:https://doi.org/10.1038/nchem.2777· OSTI ID:1535050
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Not provided.

Research Organization:
Florida State Univ., Tallahassee, FL (United States)
Sponsoring Organization:
USDOE Office of Science (SC)
DOE Contract Number:
SC0010677
OSTI ID:
1535050
Journal Information:
Nature Chemistry, Vol. 9, Issue 9; ISSN 1755-4330
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English

References (37)

Heterometallic Europium Disiloxanediolates: Synthesis, Structural Diversity, and Photoluminescence Properties journal October 2014
Uncovering f-element bonding differences and electronic structure in a series of 1 : 3 and 1 : 4 complexes with a diselenophosphinate ligand journal January 2013
Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln 2+ Ions in the [K(2.2.2-cryptand)][(C 5 H 4 SiMe 3 ) 3 Ln] Complexes: The Variable Nature of Dy 2+ and Nd 2+ journal December 2014
Differentiating between Trivalent Lanthanides and Actinides journal June 2012
The oxidation state of cerium in Ce2MoO6 journal June 1994
Isolation of Intermediate-Valent Ce(III)/Ce(IV) Hydrolysis Products in the Preparation of Cerium Iodates:  Electronic and Structural Aspects of Ce 2 (IO 3 ) 6 (OH x ) ( x ≈ 0 and 0.44) journal April 2004
Stabilization of Cerium(IV) in the Presence of an Iodide Ligand:  Remarkable Effects of Lewis Acidity on Valence State journal December 1999
A New Mixed Valent Europium Chloride: Na5Eu7Cl22 journal August 2002
KEu2Cl6 und K1, 6Eu1, 4Cl5: Zwei neue gemischtvalente EuropiumchlorideProfessor Dieter Naumann zum 60. Geburtstag gewidmet journal August 2002
Influence of Impurities on the Luminescence Quantum Efficiency of (La, Ce, Tb)PO[sub 4] journal January 1993
Unusual structure, bonding and properties in a californium borate journal March 2014
Covalency in f-element complexes journal January 2013
Experimental and Theoretical Comparison of Actinide and Lanthanide Bonding in M[N(EPR 2 ) 2 ] 3 Complexes (M = U, Pu, La, Ce; E = S, Se, Te; R = Ph, i Pr, H) journal January 2008
Emergence of californium as the second transitional element in the actinide series journal April 2015
Characterization of berkelium(III) dipicolinate and borate compounds in solution and the solid state journal August 2016
Syntheses, Structures, and Spectroscopic Properties of Plutonium and Americium Phosphites and the Redetermination of the Ionic Radii of Pu(III) and Am(III) journal July 2012
Low-Valent Molecular Plutonium Halide Complexes journal September 2008
Supramolecular Interactions in PuO 2 Cl 4 2– and PuCl 6 2– Complexes with Protonated Pyridines: Synthesis, Crystal Structures, and Raman Spectroscopy journal December 2013
A DFT study of the reactivity of actinidocenes (U, Np and Pu) with pyridine and pyridine N-oxide derivatives journal January 2010
Are 5f Electrons Really Active in Organoactinide Reactivity? Some Insights from DFT Studies journal March 2010
A DFT study of the reactivity of Cp2AnMe2 with pyridine N-oxide: Towards a predicted different reactivity of U/Pu and Np journal June 2010
A systematic analysis of the spectra of trivalent actinide chlorides in D 3 h site symmetry journal June 1992
Analysis of the crystal‐field spectra of the actinide tetrafluorides. I. UF 4 , NpF 4 , and PuF 4 journal November 1991
Optical transitions of symmetrical mixed-valence systems in the Class II–III transition regimeElectronic supplementary information (ESI) is available: derivation of eqn. (39c), table summarizing the relationships between band maxima and band widths predicted by the two-state model and table of spectral properties of mixed-valence ruthenium(II)/(III) bridged by pyrazine and dicyanamide. See http://www.rsc.org/suppdata/cs/b0/b008034i/ journal April 2002
Exploration of Mixed-Valence Chemistry:  Inventing New Analogues of the Creutz-Taube Ion journal November 2000
Ferric garnet matrices for immobilization of actinides journal May 2013
Interaction between the d -Shells in the Transition Metals. II. Ferromagnetic Compounds of Manganese with Perovskite Structure journal May 1951
Density‐functional thermochemistry. III. The role of exact exchange journal April 1993
Accurate and simple analytic representation of the electron-gas correlation energy journal June 1992
Energy‐adjusted pseudopotentials for the actinides. Parameter sets and test calculations for thorium and thorium monoxide journal May 1994
Valence basis sets for relativistic energy-consistent small-core actinide pseudopotentials journal January 2003
Segmented contraction scheme for small-core actinide pseudopotential basis sets journal March 2004
Quasirelativistic energy-consistent 5f-in-core pseudopotentials for divalent and tetravalent actinide elements journal June 2007
Self—Consistent Molecular Orbital Methods. XII. Further Extensions of Gaussian—Type Basis Sets for Use in Molecular Orbital Studies of Organic Molecules journal March 1972
The influence of polarization functions on molecular orbital hydrogenation energies journal January 1973
Self-consistent molecular orbital methods. 21. Small split-valence basis sets for first-row elements journal January 1980
Molecular excitation energies to high-lying bound states from time-dependent density-functional response theory: Characterization and correction of the time-dependent local density approximation ionization threshold journal March 1998

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