The Influence of Water on the Alkyl Region Structure in Variable Chain Length Imidazolium-Based Ionic Liquid/Water Mixtures

Thomaz, Joseph E.; Lawler, Christian M.; Fayer, Michael D.

doi:10.1021/acs.jpcb.6b07853

Title: The Influence of Water on the Alkyl Region Structure in Variable Chain Length Imidazolium-Based Ionic Liquid/Water Mixtures

Journal Article · Tue Sep 27 00:00:00 EDT 2016 · Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry

DOI:https://doi.org/10.1021/acs.jpcb.6b07853· OSTI ID:1534614

Thomaz, Joseph E. ^[1]; Lawler, Christian M. ^[1]; Fayer, Michael D. ^[1]

Department of Chemistry, Stanford University, Stanford, California 94305, United States

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Research Organization:: Stanford Univ., CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: FG03-84ER13251

OSTI ID:: 1534614

Journal Information:: Journal of Physical Chemistry. B, Condensed Matter, Materials, Surfaces, Interfaces and Biophysical Chemistry, Vol. 120, Issue 39; ISSN 1520-6106

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

References (56)

Structure and Nanostructure in Ionic Liquids Hayes, Robert; Warr, Gregory G.; Atkin, Rob Chemical Reviews, Vol. 115, Issue 13 https://doi.org/10.1021/cr500411q	journal	June 2015
Applications of ionic liquids in the chemical industry Plechkova, Natalia V.; Seddon, Kenneth R. Chem. Soc. Rev., Vol. 37, Issue 1 https://doi.org/10.1039/B006677J	journal	January 2008
Characterization of the Lithium Surface in N-Methyl-N-alkylpyrrolidinium Bis(trifluoromethanesulfonyl)amide Room-Temperature Ionic Liquid Electrolytes Howlett, P. C.; Brack, N.; Hollenkamp, A. F. Journal of The Electrochemical Society, Vol. 153, Issue 3 https://doi.org/10.1149/1.2164726	journal	January 2006
Ionic Liquid Redox Catholyte for High Energy Efficiency, Low-Cost Energy Storage Xue, Leigang; Tucker, Telpriore G.; Angell, C. Austen Advanced Energy Materials, Vol. 5, Issue 12 https://doi.org/10.1002/aenm.201500271	journal	April 2015
An ultrafast rechargeable aluminium-ion battery Lin, Meng-Chang; Gong, Ming; Lu, Bingan Nature, Vol. 520, Issue 7547 https://doi.org/10.1038/nature14340	journal	April 2015
Ionic Liquids in Separations Han, Xinxin; Armstrong, Daniel W. Accounts of Chemical Research, Vol. 40, Issue 11 https://doi.org/10.1021/ar700044y	journal	November 2007
Ionic liquid/water mixtures: from hostility to conciliation Kohno, Yuki; Ohno, Hiroyuki Chemical Communications, Vol. 48, Issue 57 https://doi.org/10.1039/c2cc31638b	journal	January 2012
Room-Temperature Ionic Liquids. Solvents for Synthesis and Catalysis Welton, Thomas Chemical Reviews, Vol. 99, Issue 8, p. 2071-2084 https://doi.org/10.1021/cr980032t	journal	August 1999
The Cosolvent-Directed Diels–Alder Reaction in Ionic Liquids Khupse, Nageshwar D.; Kumar, Anil The Journal of Physical Chemistry A, Vol. 115, Issue 36 https://doi.org/10.1021/jp205181e	journal	September 2011
Ionic liquids in the synthesis and modification of polymers Kubisa, Przemysław Journal of Polymer Science Part A: Polymer Chemistry, Vol. 43, Issue 20 https://doi.org/10.1002/pola.20971	journal	January 2005
Unique Spatial Heterogeneity in Ionic Liquids Wang, Yanting; Voth, Gregory A. Journal of the American Chemical Society, Vol. 127, Issue 35 https://doi.org/10.1021/ja053796g	journal	September 2005
Computational study of imidazolium-based ionic solvents with alkyl substituents of different lengths Margulis *, C. J. Molecular Physics, Vol. 102, Issue 9-10 https://doi.org/10.1080/00268970410001683843	journal	May 2004
Nanostructural Organization in Ionic Liquids Canongia Lopes, José N. A.; Pádua, Agílio A. H. The Journal of Physical Chemistry B, Vol. 110, Issue 7 https://doi.org/10.1021/jp056006y	journal	February 2006
Nanoscale Segregation in Room Temperature Ionic Liquids ^† Triolo, Alessandro; Russina, Olga; Bleif, Hans-Jurgen The Journal of Physical Chemistry B, Vol. 111, Issue 18 https://doi.org/10.1021/jp067705t	journal	May 2007
Morphology and intermolecular dynamics of 1-alkyl-3-methylimidazolium bis{(trifluoromethane)sulfonyl}amide ionic liquids: structural and dynamic evidence of nanoscale segregation Russina, Olga; Triolo, Alessandro; Gontrani, Lorenzo Journal of Physics: Condensed Matter, Vol. 21, Issue 42 https://doi.org/10.1088/0953-8984/21/42/424121	journal	September 2009
The Smallest Amphiphiles: Nanostructure in Protic Room-Temperature Ionic Liquids with Short Alkyl Groups Atkin, Rob; Warr, Gregory G. The Journal of Physical Chemistry B, Vol. 112, Issue 14 https://doi.org/10.1021/jp801190u	journal	April 2008
Nanostructural Organization of Ionic Liquids: Theoretical and Experimental Evidences of the Presence of Well Defined Local Structures in Ionic Liquids Chiappe, Cinzia Monatshefte für Chemie - Chemical Monthly, Vol. 138, Issue 11 https://doi.org/10.1007/s00706-007-0726-y	journal	October 2007
NMR study on relationships between reorientational dynamics and phase behaviour of room-temperature ionic liquids: 1-alkyl-3-methylimidazolium cations Imanari, Mamoru; Uchida, Kei-ichi; Miyano, Kozue Physical Chemistry Chemical Physics, Vol. 12, Issue 12 https://doi.org/10.1039/b922931k	journal	January 2010
Dielectric permittivity of room temperature ionic liquids: A relation to the polar and nonpolar domain structures Mizoshiri, Makoto; Nagao, Takena; Mizoguchi, Yuri The Journal of Chemical Physics, Vol. 132, Issue 16 https://doi.org/10.1063/1.3419906	journal	April 2010
Dynamics of Imidazolium Ionic Liquids from a Combined Dielectric Relaxation and Optical Kerr Effect Study: Evidence for Mesoscopic Aggregation Turton, David A.; Hunger, Johannes; Stoppa, Alexander Journal of the American Chemical Society, Vol. 131, Issue 31 https://doi.org/10.1021/ja903315v	journal	August 2009
Room Temperature Ionic Liquid−Lithium Salt Mixtures: Optical Kerr Effect Dynamical Measurements Nicolau, Bruno G.; Sturlaugson, Adam; Fruchey, Kendall The Journal of Physical Chemistry B, Vol. 114, Issue 25 https://doi.org/10.1021/jp103810r	journal	July 2010
Orientational Dynamics of Room Temperature Ionic Liquid/Water Mixtures: Water-Induced Structure Sturlaugson, Adam L.; Fruchey, Kendall S.; Fayer, Michael D. The Journal of Physical Chemistry B, Vol. 116, Issue 6 https://doi.org/10.1021/jp209942r	journal	February 2012
Nanostructural Organization and Anion Effects on the Temperature Dependence of the Optical Kerr Effect Spectra of Ionic Liquids ^† Xiao, Dong; Rajian, Justin Rajesh; Cady, Amanda The Journal of Physical Chemistry B, Vol. 111, Issue 18 https://doi.org/10.1021/jp066481b	journal	May 2007
Nanostructural Organization and Anion Effects in the Optical Kerr Effect Spectra of Binary Ionic Liquid Mixtures Xiao, Dong; Rajian, Justin Rajesh; Hines, Larry G. The Journal of Physical Chemistry B, Vol. 112, Issue 42 https://doi.org/10.1021/jp804417t	journal	October 2008
Nanostructural organization in carbon disulfide/ionic liquid mixtures: Molecular dynamics simulations and optical Kerr effect spectroscopy Yang, Peng; Voth, Gregory A.; Xiao, Dong The Journal of Chemical Physics, Vol. 135, Issue 3 https://doi.org/10.1063/1.3601752	journal	July 2011
The Influence of Lithium Cations on Dynamics and Structure of Room Temperature Ionic Liquids Lawler, Christian; Fayer, Michael D. The Journal of Physical Chemistry B, Vol. 117, Issue 33 https://doi.org/10.1021/jp405752q	journal	August 2013
S1-lifetimes of triphenylmethane and indigo dyes determined by the two-photon-fluorescence technique Wirth, P.; Schneider, S.; Dörr, F. Optics Communications, Vol. 20, Issue 1 https://doi.org/10.1016/0030-4018(77)90183-3	journal	January 1977
Carbon dioxide in an ionic liquid: Structural and rotational dynamics Giammanco, Chiara H.; Kramer, Patrick L.; Yamada, Steven A. The Journal of Chemical Physics, Vol. 144, Issue 10 https://doi.org/10.1063/1.4943390	journal	March 2016
Dynamics of water, methanol, and ethanol in a room temperature ionic liquid Kramer, Patrick L.; Giammanco, Chiara H.; Fayer, Michael D. The Journal of Chemical Physics, Vol. 142, Issue 21 https://doi.org/10.1063/1.4914156	journal	June 2015
Ionic Liquid Dynamics Measured with 2D IR and IR Pump–Probe Experiments on a Linear Anion and the Influence of Potassium Cations Tamimi, Amr; Fayer, Michael D. The Journal of Physical Chemistry B, Vol. 120, Issue 26 https://doi.org/10.1021/acs.jpcb.6b00409	journal	February 2016
Absorption of Water by Room-Temperature Ionic Liquids: Effect of Anions on Concentration and State of Water Tran, Chieu D.; De Paoli Lacerda, Silvia H.; Oliveira, Daniel Applied Spectroscopy, Vol. 57, Issue 2 https://doi.org/10.1366/000370203321535051	journal	February 2003
Delineating Solute−Solvent Interactions in Binary Mixtures of Ionic Liquids in Molecular Solvents and Preferential Solvation Approach Khupse, Nageshwar D.; Kumar, Anil The Journal of Physical Chemistry B, Vol. 115, Issue 4 https://doi.org/10.1021/jp110040a	journal	February 2011
Evidence of change in the molecular organization of 1-n-butyl-3-methylimidazolium tetrafluoroborate ionic liquid solutions with the addition of water Ries, L. A. S.; do Amaral, F. A.; Matos, K. Polyhedron, Vol. 27, Issue 15 https://doi.org/10.1016/j.poly.2008.07.029	journal	October 2008
Ionic Liquids as Performance Additives for Electroenzymatic Syntheses Kohlmann, Christina; Greiner, Lasse; Leitner, Walter Chemistry - A European Journal, Vol. 15, Issue 43 https://doi.org/10.1002/chem.200901046	journal	September 2009
Conductivity, Spectroscopic, and Computational Investigation of H ₃ O ⁺ Solvation in Ionic Liquid BMIBF ₄ Yu, Lei; Clifford, Jeremy; Pham, Toan T. The Journal of Physical Chemistry B, Vol. 117, Issue 23 https://doi.org/10.1021/jp402582r	journal	May 2013
Intermolecular Vibrational Motions of Solute Molecules Confined in Nonpolar Domains of Ionic Liquids Xiao, Dong; Hines, Larry G.; Bartsch, Richard A. The Journal of Physical Chemistry B, Vol. 113, Issue 14 https://doi.org/10.1021/jp811293n	journal	April 2009
Phase Equilibria in Ionic Liquid−Aromatic Compound Mixtures, Including Benzene Fluorination Effects Blesic, Marijana; Lopes, José N. Canongia; Pádua, Agílio A. H. The Journal of Physical Chemistry B, Vol. 113, Issue 21 https://doi.org/10.1021/jp902178g	journal	May 2009
Clusters of Imidazolium-Based Ionic Liquid in Benzene Solutions Shimomura, Takuya; Takamuku, Toshiyuki; Yamaguchi, Toshio The Journal of Physical Chemistry B, Vol. 115, Issue 26 https://doi.org/10.1021/jp203422z	journal	July 2011
Time-resolved fluorescence anisotropy of perylene Christensen, Ronald L.; Drake, Rodney C.; Phillips, David The Journal of Physical Chemistry, Vol. 90, Issue 22 https://doi.org/10.1021/j100280a100	journal	October 1986
Rotational Diffusion Dynamics of Perylene in n-Alkanes. Observation of a Solvent Length-Dependent Change of Boundary Condition Jiang, Y.; Blanchard, G. J. The Journal of Physical Chemistry, Vol. 98, Issue 26 https://doi.org/10.1021/j100077a003	journal	June 1994
The large scale synthesis of pure imidazolium and pyrrolidinium ionic liquids Burrell, Anthony K.; Sesto, Rico E. Del; Baker, Sheila N. Green Chemistry, Vol. 9, Issue 5 https://doi.org/10.1039/b615950h	journal	January 2007
Decolorization of Ionic Liquids for Spectroscopy Earle, Martyn J.; Gordon, Charles M.; Plechkova, Natalia V. Analytical Chemistry, Vol. 79, Issue 2 https://doi.org/10.1021/ac061481t	journal	January 2007
Fluorescence decay studies of anisotropic rotations of small molecules Barkley, Mary D.; Kowalczyk, Andrzej A.; Brand, Ludwig The Journal of Chemical Physics, Vol. 75, Issue 7 https://doi.org/10.1063/1.442468	journal	October 1981
Theory of Fluorescence Depolarization by Anisotropic Rotational Diffusion Chuang, T. J.; Eisenthal, K. B. The Journal of Chemical Physics, Vol. 57, Issue 12 https://doi.org/10.1063/1.1678194	journal	December 1972
Femtosecond Fluorescence Upconversion Study of the Rotations of Perylene and Tetracene in Hexadecane Xu, Jianhua; Shen, Xiaohua; Knutson, Jay R. The Journal of Physical Chemistry A, Vol. 107, Issue 41 https://doi.org/10.1021/jp030113f	journal	October 2003
Proton Transfer in Ionic and Neutral Reverse Micelles Lawler, Christian; Fayer, Michael D. The Journal of Physical Chemistry B, Vol. 119, Issue 19 https://doi.org/10.1021/acs.jpcb.5b02753	journal	April 2015
Rotation of Aromatic Hydrocarbons in Viscous Alkanes. 1. Methylcyclohexane Brocklehurst, Brian; Young, Ronald N. The Journal of Physical Chemistry A, Vol. 103, Issue 20 https://doi.org/10.1021/jp984308c	journal	April 1999
Effect of librational motion on fluorescence depolarization and nuclear magnetic resonance relaxation in macromolecules and membranes Lipari, G.; Szabo, A. Biophysical Journal, Vol. 30, Issue 3 https://doi.org/10.1016/S0006-3495(80)85109-5	journal	June 1980
Time‐correlation functions for restricted rotational diffusion Wang, C. C.; Pecora, R. The Journal of Chemical Physics, Vol. 72, Issue 10 https://doi.org/10.1063/1.439024	journal	May 1980
Rotational friction coefficients for ellipsoids and chemical molecules with the slip boundary condition Youngren, G. K.; Acrivos, A. The Journal of Chemical Physics, Vol. 63, Issue 9 https://doi.org/10.1063/1.431879	journal	January 1975
Comment on: Rotational friction coefficients for ellipsoids and chemical molecules with slip boundary conditions Sension, Roseanne J.; Hochstrasser, Robin M. The Journal of Chemical Physics, Vol. 98, Issue 3 https://doi.org/10.1063/1.465075	journal	February 1993
Interaction of Water with the Model Ionic Liquid [bmim][BF ₄ ]: Molecular Dynamics Simulations and Comparison with NMR Data Moreno, Margherita; Castiglione, Franca; Mele, Andrea The Journal of Physical Chemistry B, Vol. 112, Issue 26 https://doi.org/10.1021/jp800383g	journal	July 2008
Molecular dynamics simulations of imidazolium-based ionic liquid/water mixtures: Alkyl side chain length and anion effects Feng, Shulu; Voth, Gregory A. Fluid Phase Equilibria, Vol. 294, Issue 1-2 https://doi.org/10.1016/j.fluid.2010.02.034	journal	July 2010
Orientational and Translational Dynamics of Polyether/Water Solutions Sturlaugson, Adam L.; Fruchey, Kendall S.; Lynch, Stephen R. The Journal of Physical Chemistry B, Vol. 114, Issue 16 https://doi.org/10.1021/jp101369e	journal	April 2010
Orientational dynamics of the ionic organic liquid 1-ethyl-3-methylimidazolium nitrate Cang, Hu; Li, Jie; Fayer, M. D. The Journal of Chemical Physics, Vol. 119, Issue 24 https://doi.org/10.1063/1.1628668	journal	December 2003
Nearly Logarithmic Decay of Correlations in Glass-Forming Liquids Götze, W.; Sperl, M. Physical Review Letters, Vol. 92, Issue 10 https://doi.org/10.1103/PhysRevLett.92.105701	journal	March 2004

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“Solvent-in-salt” systems for design of new materials in chemistry, biology and energy research Azov, Vladimir A.; Egorova, Ksenia S.; Seitkalieva, Marina M. Chemical Society Reviews, Vol. 47, Issue 4 https://doi.org/10.1039/c7cs00547d	journal	January 2018
The influence of hydrophilicity on the orientational dynamics and structures of imidazolium-based ionic liquid/water binary mixtures Bailey, Heather E.; Wang, Yong-Lei; Fayer, Michael D. The Journal of Chemical Physics, Vol. 149, Issue 4 https://doi.org/10.1063/1.5038563	journal	July 2018
Are Ionic Liquids Good Boundary Lubricants? A Molecular Perspective Lhermerout, Romain; Diederichs, Christophe; Perkin, Susan Lubricants, Vol. 6, Issue 1 https://doi.org/10.3390/lubricants6010009	journal	January 2018

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