One-Pot Hydrothermal Synthesis of Tb III 13 (GeO 4 ) 6 O 7 (OH) and K 2 Tb IV Ge 2 O 7 : Preparation of a Stable Terbium(4+) Complex

Fulle, Kyle; Sanjeewa, Liurukara D.; McMillen, Colin D.; Wen, Yimei; Rajamanthrilage, Apeksha C.; Anker, Jeffrey N.; Chumanov, George; Kolis, Joseph W.

doi:10.1021/acs.inorgchem.7b00821

One-Pot Hydrothermal Synthesis of Tb ^III ₁₃ (GeO ₄ ) ₆ O ₇ (OH) and K ₂ Tb ^IV Ge ₂ O ₇ : Preparation of a Stable Terbium(4+) Complex

Journal Article · Wed May 24 00:00:00 EDT 2017 · Inorganic Chemistry

DOI:https://doi.org/10.1021/acs.inorgchem.7b00821· OSTI ID:1534542

Fulle, Kyle ^[1]; Sanjeewa, Liurukara D. ^[2]; ^[2]; Wen, Yimei ^[2]; Rajamanthrilage, Apeksha C. ^[2]; Anker, Jeffrey N. ^[2]; Chumanov, George ^[2]; Kolis, Joseph W. ^[2]

Department of Chemistry and Center for Optical Materials Science and Engineering Technologies, Clemson University, Clemson, South Carolina 29634-0973, United States; DOE/OSTI
Department of Chemistry and Center for Optical Materials Science and Engineering Technologies, Clemson University, Clemson, South Carolina 29634-0973, United States

Not provided.

Research Organization:: Clemson Univ., SC (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

DOE Contract Number:: SC0014271

OSTI ID:: 1534542

Journal Information:: Inorganic Chemistry, Journal Name: Inorganic Chemistry Journal Issue: 11 Vol. 56; ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

References (33)

Hydrothermal synthesis of new compounds Demianets, L. N. Progress in Crystal Growth and Characterization of Materials, Vol. 21, Issue 1-4 https://doi.org/10.1016/0960-8974(91)90016-6	journal	January 1991
Terbium Oxides. III. X-Ray Diffraction Studies of Several Stable Phases Baenziger, N. C.; Eick, H. A.; Schuldt, H. S. Journal of the American Chemical Society, Vol. 83, Issue 10 https://doi.org/10.1021/ja01471a001	journal	May 1961
Synthesis, Characterization, and X-Ray Powder Structure of K2ZrGe2O7 Pertierra, Pilar; Salvado, Miguel A.; Garcia-Granda, Santiago Journal of Solid State Chemistry, Vol. 148, Issue 1 https://doi.org/10.1006/jssc.1999.8332	journal	November 1999
Hydrothermal synthesis and characterization of a new layered compound Li2VGeO5 Emirdag-Eanes, Mehtap; Kolis, Joseph W. Journal of Alloys and Compounds, Vol. 370, Issue 1-2 https://doi.org/10.1016/j.jallcom.2003.09.027	journal	May 2004
Study on the crystal and magnetic structures of and by powder neutron diffraction Tezuka, Keitaro; Hinatsu, Yukio; Shimojo, Yutaka Journal of Physics: Condensed Matter, Vol. 10, Issue 50 https://doi.org/10.1088/0953-8984/10/50/009	journal	December 1998
Magnetic and calorimetric studies on 6H-perovskite Ba3TbRu2O9 Doi, Yoshihiro; Wakeshima, Makoto; Hinatsu, Yukio Journal of Alloys and Compounds, Vol. 344, Issue 1-2 https://doi.org/10.1016/S0925-8388(02)00333-X	journal	October 2002
Neue Vertreter des K2Li14[Pb3O14]-Typs Cs2Li14[Tb3O14] und K2Li14[Zr3O14] [1, 2] Voigt, S.; Werthmann, R.; Hoppe, R. Zeitschrift für anorganische und allgemeine Chemie, Vol. 574, Issue 1 https://doi.org/10.1002/zaac.655740107	journal	July 1989
Stabilization of praseodymium(IV) and terbium(IV) in aqueous carbonate solution Hobart, D. E.; Samhoun, K.; Young, J. P. Inorganic and Nuclear Chemistry Letters, Vol. 16, Issue 5 https://doi.org/10.1016/0020-1650(80)80069-9	journal	January 1980
Rare-Earth Germanates Demianets, Ludmila N.; Lobachev, Anatoly N.; Emelchenko, Gennadi A. Organic Crystals, Germanates, Semiconductors https://doi.org/10.1007/978-3-642-67764-9_2	book	January 1980
Systematic prediction of new ferroelectrics in space group R 3. I Abrahams, S. C. Acta Crystallographica Section B Structural Science, Vol. 62, Issue 1 https://doi.org/10.1107/S0108768105040577	journal	January 2006
Synthesis, crystal structure, magnetic and luminescence properties of KEuGe2O6: a europium cyclogermanate containing infinite chains of edge-sharing Eu–O polyhedra Chen, Pei-Lin; Chiang, Pei-Yun; Yeh, Han-Ching Dalton Transactions, Issue 13 https://doi.org/10.1039/b716654k	journal	January 2008
Synthesis and Crystal Structure of a New Mixed-Valence Terbium Fluoride, KTbIIITbIV2F12, and Related KLnIIIMIV2F12Compounds (MIV=Tb, Zr, Hf;LnIII=Ce–Lu) Largeau, Eric; El-Ghozzi, Malika; Avignant, Daniel Journal of Solid State Chemistry, Vol. 139, Issue 2 https://doi.org/10.1006/jssc.1998.7837	journal	September 1998
Synthesis and crystal structures of new mixed-valence terbium (III/IV) fluorides with a random distribution between Tb3+ and Tb4+ Josse, M.; Dubois, M.; El-Ghozzi, M. Journal of Alloys and Compounds, Vol. 374, Issue 1-2 https://doi.org/10.1016/j.jallcom.2003.11.140	journal	July 2004
An Open-Framework Germanate with Polycubane-Like Topology Li, Hailian; Eddaoudi, Mohamed; Yaghi, Omar M. Angewandte Chemie International Edition, Vol. 38, Issue 5 https://doi.org/10.1002/(SICI)1521-3773(19990301)38:5<653::AID-ANIE653>3.3.CO;2-3	journal	March 1999
Studies on the stabilization of terbium(IV) in aqueous tetrametaphosphate solution Li, Xiaojing; Dong, Wenji; Qi, Yulang Polyhedron, Vol. 10, Issue 13 https://doi.org/10.1016/S0277-5387(00)86069-6	journal	January 1991
Phases and structural relations of the rare earth germanates RE2Ge2O7, RE ≡ La-Lu Becker, U. W.; Felsche, J. Journal of the Less Common Metals, Vol. 128 https://doi.org/10.1016/0022-5088(87)90215-3	journal	February 1987
Hydrothermal crystallization in the KOH-ZrO2-GeO2-H2O system under 0.1 GPa pressure at 500°C: Phase relationships for Zr germanates and modeling of K2ZrGe2O7 crystal structure Ilyushin, G. D. Crystallography Reports, Vol. 50, Issue 3 https://doi.org/10.1134/1.1927617	journal	May 2005
A comprehensive comparison of transition-metal and actinyl polyoxometalates Nyman, May; Burns, Peter C. Chemical Society Reviews, Vol. 41, Issue 22 https://doi.org/10.1039/c2cs35136f	journal	January 2012
Inorganic Lanthanide Compounds with Complex Anions Wickleder, Mathias S. Chemical Reviews, Vol. 102, Issue 6 https://doi.org/10.1021/cr010308o	journal	June 2002
Terbium Tetrafluoride: Preparation and Properties ¹ Cunningham, B. B.; Feay, D. C.; Rollier, M. A. Journal of the American Chemical Society, Vol. 76, Issue 13 https://doi.org/10.1021/ja01642a001	journal	July 1954
On the nature of tetravalent terbium in carbonate-hydroxide solutions Varlashkin, P. G.; Begun, G. M.; Peterson, J. R. Journal of the Less Common Metals, Vol. 109, Issue 1 https://doi.org/10.1016/0022-5088(85)90112-2	journal	July 1985
Hydrothermal crystal synthesis in the Ho2O3(Yb2O3)GeO2KFH2O systems Emelchenko, G. A.; Demyanets, L. N.; Lobachev, A. N. Journal of Solid State Chemistry, Vol. 14, Issue 2 https://doi.org/10.1016/0022-4596(75)90013-4	journal	June 1975
Crystal chemistry and magnetic structures of Tb(IV) fluorides El-Ghozzi, M.; Avignant, D. Journal of Fluorine Chemistry, Vol. 107, Issue 2 https://doi.org/10.1016/S0022-1139(00)00363-8	journal	February 2001
Na3Hx(H2PO4)x[(GeO)4(GeO4)3].cntdot.4H2O: A rhombohedrally-distorted germanium pharmacosiderite analog with anion/cation exchange capabilities Nenoff, Tina M.; Harrison, William T. A.; Stucky, Galen D. Chemistry of Materials, Vol. 6, Issue 4 https://doi.org/10.1021/cm00040a030	journal	April 1994
Preparation and Low‐Temperature Magnetic Properties of the Terbium Oxides MacChesney, J. B.; Williams, H. J.; Sherwood, R. C. The Journal of Chemical Physics, Vol. 44, Issue 2 https://doi.org/10.1063/1.1726730	journal	January 1966
�ber Na2PrO3 und Na2TbO3 Wolf, R.; Hoppe, R. Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 556, Issue 1 https://doi.org/10.1002/zaac.19885560110	journal	January 1988
Crystal growth, structures, magnetic and photoluminescent properties of NaLnGeO4 (Ln = Sm, Eu, Gd, Tb) Yeon, Jeongho; Hardaway, John B.; Sefat, Athena S. Solid State Sciences, Vol. 34 https://doi.org/10.1016/j.solidstatesciences.2014.05.002	journal	August 2014
Synthesis, structural characterization, and magnetic properties of NaRE9(GeO4)6O2 (RE = Nd, Pr) Emirdag-Eanes, Mehtap; Pennington, William T.; Kolis, Joseph W. Journal of Alloys and Compounds, Vol. 366, Issue 1-2 https://doi.org/10.1016/S0925-8388(03)00725-4	journal	March 2004
Flux Synthesis, Crystal Structure, and Photoluminescence of a Heterometallic Uranyl-Europium Germanate with U═O–Eu Linkage: K ₄ [(UO ₂ )Eu ₂ (Ge ₂ O ₇ ) ₂ ] Liu, Shih-Pu; Chen, Meng-Ling; Chang, Bor-Chen Inorganic Chemistry, Vol. 52, Issue 7 https://doi.org/10.1021/ic302826u	journal	June 2012
High-Pressure Framework Silicates Hazen, R. M.; Downs, R. T.; Finger, L. W. Science, Vol. 272, Issue 5269 https://doi.org/10.1126/science.272.5269.1769	journal	June 1996
Structure and magnetic properties of the two-dimensional antiferromagnet Na ₂ TbO ₃ Doi, Yoshihiro; Ninomiya, Kensuke; Hinatsu, Yukio Journal of Physics: Condensed Matter, Vol. 17, Issue 27 https://doi.org/10.1088/0953-8984/17/27/014	journal	June 2005
Hydrothermal synthesis, characterization and magnetic properties of NaVGe2O6 and LiVGe2O6 Emirdag-Eanes, Mehtap; Kolis, Joseph W. Materials Research Bulletin, Vol. 39, Issue 10 https://doi.org/10.1016/j.materresbull.2004.04.001	journal	August 2004
Crystal chemistry of six-coordinated silicon: a key to understanding the earth's deep interior Finger, L. W.; Hazen, R. M. Acta Crystallographica Section B Structural Science, Vol. 47, Issue 5 https://doi.org/10.1107/S0108768191004214	journal	October 1991

Cited By (2)

Utilizing an In Situ Reduction in the Synthesis of BaMoOF5 Felder, Justin B.; Smith, Mark D.; zur Loye, Hans-Conrad Journal of Chemical Crystallography, Vol. 49, Issue 1 https://doi.org/10.1007/s10870-018-00767-0	journal	January 2019
Hydrothermal synthesis and structural characterization of several complex rare earth tantalates: Ln ₂ TaO ₅ (OH) (Ln = La, Pr) and Ln ₃ Ta ₂ O ₉ (OH) (Ln = Pr, Nd) Sanjeewa, Liurukara D.; Fulle, Kyle; McMillen, Colin D. Dalton Transactions, Vol. 48, Issue 22 https://doi.org/10.1039/c9dt00059c	journal	January 2019

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CCDC 1550788: Experimental Crystal Structure Determination Fulle, Kyle; Sanjeewa, Liurukara. D.; McMillen, Colin D. https://doi.org/10.5517/ccdc.csd.cc1p1qfw The current record is supplemented by this dataset	dataset	January 2017
CCDC 1550787: Experimental Crystal Structure Determination Fulle, Kyle; Sanjeewa, Liurukara. D.; McMillen, Colin D. https://doi.org/10.5517/ccdc.csd.cc1p1qdv The current record is supplemented by this dataset	dataset	January 2017