Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation

Michan, Alison L.; Parimalam, Bharathy. S.; Leskes, Michal; Kerber, Rachel N.; Yoon, Taeho; Grey, Clare P.; Lucht, Brett L.

doi:10.1021/acs.chemmater.6b02282

Title: Fluoroethylene Carbonate and Vinylene Carbonate Reduction: Understanding Lithium-Ion Battery Electrolyte Additives and Solid Electrolyte Interphase Formation

Journal Article · Mon Oct 17 00:00:00 EDT 2016 · Chemistry of Materials

DOI:https://doi.org/10.1021/acs.chemmater.6b02282· OSTI ID:1534438

Michan, Alison L. ^[1]; Parimalam, Bharathy. S. ^[2]; Leskes, Michal ^[1]; Kerber, Rachel N. ^[1]; Yoon, Taeho ^[2]; Grey, Clare P. ^[1]; Lucht, Brett L. ^[2]

Univ. of Cambridge (United Kingdom)
Univ. of Rhode Island, Kingston, RI (United States)

In this work, we have synthesized the products of fluoroethylene carbonate (FEC) and vinylene carbonate (VC) via lithium naphthalenide reduction. By analyzing the resulting solid precipitates and gas evolution, our results confirm that both FEC and VC decomposition products include HCO₂Li, Li₂C₂O₄, Li₂CO₃, and polymerized VC. For FEC, our experimental data supports a reduction mechanism where FEC reduces to form VC and LiF, followed by subsequent VC reduction. In the FEC reduction product, HCO₂Li, Li₂C₂O₄, and Li₂CO₃ were found in smaller quantities than in the VC reduction product, with no additional fluorine environments being detected by solid-state nuclear magnetic resonance or X-ray photoelectron spectroscopy analysis. With these additives being practically used in higher (FEC) and lower (VC) concentrations in the base electrolytes of lithium-ion batteries, our results suggest that the different relative ratios of the inorganic and organic reduction products formed by their decomposition may be relevant to the chemical composition and morphology of the solid electrolyte interphase formed in their presence.

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Research Organization:: Brown Univ., Providence, RI (United States); Univ. of California, Oakland, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Transportation Office. Vehicle Technologies Office; Schiff Foundation; Weizmann Institute of Science

Grant/Contract Number:: SC0007074; AC02-05CH11231; 7057154

OSTI ID:: 1534438

Journal Information:: Chemistry of Materials, Vol. 28, Issue 22; ISSN 0897-4756

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 262 works

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Selective NMR observation of the SEI–metal interface by dynamic nuclear polarisation from lithium metal Hope, Michael A.; Rinkel, Bernardine L. D.; Gunnarsdóttir, Anna B. Apollo - University of Cambridge Repository https://doi.org/10.17863/cam.69492	text	January 2020
Selective NMR observation of the SEI–metal interface by dynamic nuclear polarisation from lithium metal Hope, Michael A.; Rinkel, Bernardine L. D.; Gunnarsdóttir, Anna B. Nature Communications, Vol. 11, Issue 1 https://doi.org/10.1038/s41467-020-16114-x	journal	May 2020
Fluorinated Electrolytes for Li-Ion Batteries: The Lithium Difluoro(oxalato)borate Additive for Stabilizing the Solid Electrolyte Interphase Xia, Lan; Lee, Saixi; Jiang, Yabei ACS Omega, Vol. 2, Issue 12 https://doi.org/10.1021/acsomega.7b01196	journal	December 2017
Study of the Binder Influence on Expansion/Contraction Behavior of Silicon Alloy Negative Electrodes for Lithium-Ion Batteries Yoon, Dong-Hwan; Marinaro, Mario; Axmann, Peter Electrochemical Society https://doi.org/10.5445/ir/1000128528	text	January 2020

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
36 MATERIALS SCIENCE
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