Role of Carbon Bridge Length of Organosilicate Precursors on the Atmospheric Plasma Deposition of Transparent Bilayer Protective Coatings on Plastics

Dong, Siming; Han, Jiahao; Zhao, Zhenlin; Dauskardt, Reinhold H.

doi:10.1002/ppap.201600024

Title: Role of Carbon Bridge Length of Organosilicate Precursors on the Atmospheric Plasma Deposition of Transparent Bilayer Protective Coatings on Plastics

Journal Article · Fri Jul 15 00:00:00 EDT 2016 · Plasma Processes and Polymers

DOI:https://doi.org/10.1002/ppap.201600024· OSTI ID:1533210

Dong, Siming ^[1]; Han, Jiahao ^[1]; Zhao, Zhenlin ^[1]; Dauskardt, Reinhold H. ^[1]

Stanford Univ., CA (United States)

Here, we demonstrate the deposition of transparent organosilicate protective bilayer coatings on poly methyl methacrylate (PMMA) substrates with different carbon chain length dipodalsilane precursors using atmospheric plasma deposition in ambient air. The bottom adhesive layer was a hybrid organosilicate coating deposited using either only carbon bridge organosilicate precursor or accompanied with a ring structure 1,5-cyclooctadiene precursor. The top layer was a dense silica coating with high elastic modulus and hardness deposited with only carbon bridge precursor. The adhesion energy of bottom layer increased with increasing carbon bridge length of precursors while the density, hardness, and elastic modulus of top hard layer decreased. The deposited bilayer structure showed ~3 times the adhesion energy and four times the elastic modulus of commercial polysiloxane sol–gel coatings.

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Research Organization:: Stanford Univ., CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: FG02-07ER46391; 119255

OSTI ID:: 1533210

Journal Information:: Plasma Processes and Polymers, Vol. 13, Issue 11; ISSN 1612-8850

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 5 works

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Optically Transparent Protective Coating for Plastics Using Dual Spray and Atmospheric Plasma Deposition Ding, Yichuan; Dong, Siming; Han, Jiahao Advanced Materials Interfaces, Vol. 5, Issue 9 https://doi.org/10.1002/admi.201701433	journal	February 2018
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36 MATERIALS SCIENCE
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atmospheric plasma
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Title: Role of Carbon Bridge Length of Organosilicate Precursors on the Atmospheric Plasma Deposition of Transparent Bilayer Protective Coatings on Plastics

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