Metal-containing ionic liquid-based, uncharged–charged diblock copolymers that form ordered, phase-separated microstructures and reversibly coordinate small protic molecules

Shi, Zhangxing; May, Alyssa W.; Kohno, Yuki; Bailey, Travis S.; Gin, Douglas L.

doi:10.1002/pola.28623

Title: Metal-containing ionic liquid-based, uncharged–charged diblock copolymers that form ordered, phase-separated microstructures and reversibly coordinate small protic molecules

Journal Article · Thu May 04 00:00:00 EDT 2017 · Journal of Polymer Science. Part A, Polymer Chemistry

DOI:https://doi.org/10.1002/pola.28623· OSTI ID:1533206

Shi, Zhangxing ^[1]; May, Alyssa W. ^[2]; Kohno, Yuki ^[1]; Bailey, Travis S. ^[2]; Gin, Douglas L. ^[1]

Univ. of Colorado, Boulder, CO (United States)
Colorado State Univ., Fort Collins, CO (United States)

A metal-containing ionic liquid-based, uncharged-charged block copolymer (BCP) system made via RAFT polymerization is presented. Small-angle X-ray scattering studies show these Co(II) bis(salicylate) anion-containing BCPs can form ordered microstructures (including a gyroid phase) in their neat states. Additionally, these BCPs can reversibly coordinate H₂O or small alcohols with a noticeable color change.

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Research Organization:: Arizona State Univ., Tempe, AZ (United States)

Sponsoring Organization:: USDOE Advanced Research Projects Agency - Energy (ARPA-E)

Grant/Contract Number:: AR0000343; DE‐AR0000343

OSTI ID:: 1533206

Alternate ID(s):: OSTI ID: 1373817

Journal Information:: Journal of Polymer Science. Part A, Polymer Chemistry, Vol. 55, Issue 18; ISSN 0887-624X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
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block copolymer
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reversible coordination

Title: Metal-containing ionic liquid-based, uncharged–charged diblock copolymers that form ordered, phase-separated microstructures and reversibly coordinate small protic molecules

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