Versatile functionalization of aromatic polysulfones via thiol-ene click chemistry

Park, Eun Joo; Lee, Woo-Hyung; Bae, Chulsung

doi:10.1002/pola.28210

Versatile functionalization of aromatic polysulfones via thiol-ene click chemistry

Journal Article · Mon Jun 27 00:00:00 EDT 2016 · Journal of Polymer Science. Part A, Polymer Chemistry

DOI:https://doi.org/10.1002/pola.28210· OSTI ID:1533205

Park, Eun Joo ^[1]; Lee, Woo-Hyung ^[2]; Bae, Chulsung ^[2]

Rensselaer Polytechnic Inst., Troy, NY (United States); DOE/OSTI
Rensselaer Polytechnic Inst., Troy, NY (United States)

A facile, efficient approach for preparation of functionalized aromatic polysulfones by postpolymerization modification with thiol-ene click chemistry is described. The key synthetic strategy is to incorporate a pendant vinyl ether group into polysulfones as a reactive precursor with controlled degrees of functionalization. Synthetic utility of the pendant alkenyl group is demonstrated by generating diverse polymer derivatives using thiol-ene functionalization including glycosylated polysulfone. Finally, the highly reactive alkene platform in the polymer affords convenient, metal-free, and azide-free click transformations to create diverse ranges of new functionalized polysulfones that could be applied in various applications.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Nevada, Reno, NV (United States)

Sponsoring Organization:: National Science Foundation (NSF); Rensselaer Polytechnic Institute; USDOE Office of Science (SC)

Grant/Contract Number:: SC0005062

OSTI ID:: 1533205

Journal Information:: Journal of Polymer Science. Part A, Polymer Chemistry, Journal Name: Journal of Polymer Science. Part A, Polymer Chemistry Journal Issue: 19 Vol. 54; ISSN 0887-624X

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
click chemistry
functionalization of polymers
modification
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polymer science
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postpolymerization modification
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Versatile functionalization of aromatic polysulfones via thiol-ene click chemistry

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References (40)

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