Modification and intercalation of layered zirconium phosphates: a solid-state NMR monitoring

Bakhmutov, Vladimir I.; Kan, Yuwei; Sheikh, Javeed Ahmad; González-Villegas, Julissa; Colón, Jorge L.; Clearfield, Abraham

doi:10.1002/mrc.4568

Modification and intercalation of layered zirconium phosphates: a solid-state NMR monitoring

Journal Article · Wed Dec 14 00:00:00 EST 2016 · Magnetic Resonance in Chemistry

DOI:https://doi.org/10.1002/mrc.4568· OSTI ID:1533192

Bakhmutov, Vladimir I. ^[1]; Kan, Yuwei ^[2]; Sheikh, Javeed Ahmad ^[2]; González-Villegas, Julissa ^[3]; Colón, Jorge L. ^[3]; Clearfield, Abraham ^[2]

Texas A & M Univ., College Station, TX (United States); DOE/OSTI
Texas A & M Univ., College Station, TX (United States)
Univ. of Puerto Rico, Rio Piedras, PR (United States)

Several layered zirconium phosphates treated with Zr(IV) ions, modified by monomethoxy-polyethyleneglycol-monophosphate and intercalated with doxorubicin hydrochloride have been studied by solid-state MAS NMR techniques. The organic components of the phosphates have been characterized by the ¹³C{¹H} CP MAS NMR spectra compared with those of initial compounds. The multinuclear NMR monitoring has provided to establish structure and covalent attachment of organic/inorganic moieties to the surface and interlayer spaces of the phosphates. Finally, the MAS NMR experiments including kinetics of proton-phosphorus cross polarization have resulted in an unusual structure of zirconium phosphate 6 combining decoration of the phosphate surface by polymer units and their partial intercalation into the interlayer space.

View Accepted Manuscript (DOE)

Research Organization:: Texas A & M Univ., College Station, TX (United States)

Sponsoring Organization:: National Science Foundation (NSF); Robert A. Welch Foundation; USDOE Office of Nuclear Energy (NE)

Grant/Contract Number:: NE0000746

OSTI ID:: 1533192

Journal Information:: Magnetic Resonance in Chemistry, Journal Name: Magnetic Resonance in Chemistry Journal Issue: 7 Vol. 55; ISSN 0749-1581

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited By (3)

2D Sandwich‐Like α‐Zirconium Phosphate/Polypyrrole: Moderate Catalytic Activity and True Sulfur Confinement for High‐Performance Lithium–Sulfur Batteries Liu, Ye; Yan, Wenjun; Zhang, Wei ChemSusChem, Vol. 12, Issue 23 https://doi.org/10.1002/cssc.201902227	journal	November 2019
Modification of α-Zirconium Phosphate Synthesis - Effects of Crystallinity and Acidity on Eu(III) and Am(III) Ion Exchange Wiikinkoski, Elmo W.; Xu, Junhua; Zhang, Wenzhong ChemistrySelect, Vol. 3, Issue 33 https://doi.org/10.1002/slct.201801601	journal	September 2018
Combination of intercalation and surface modification in layered zirconium phosphates: investigation of surface stability and reactivity Cruz, Eduardo; Broker, Edward J.; Mosby, Brian M. Dalton Transactions, Vol. 49, Issue 12 https://doi.org/10.1039/c9dt03992a	journal	January 2020

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
chemistry
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intercalation
solid-state NMR
spectroscopy
zirconium phosphates

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