Semiconductor-Based, Solar-Driven Photochemical Cells for Fuel Generation from Carbon Dioxide in Aqueous Solutions

Yehezkeli, Omer; Bedford, Nicholas M.; Park, Eunsol; Ma, Ke; Cha, Jennifer N.

doi:10.1002/cssc.201601105

Semiconductor-Based, Solar-Driven Photochemical Cells for Fuel Generation from Carbon Dioxide in Aqueous Solutions

Journal Article · Mon Oct 24 00:00:00 EDT 2016 · ChemSusChem

DOI:https://doi.org/10.1002/cssc.201601105· OSTI ID:1533150

Yehezkeli, Omer ^[1]; Bedford, Nicholas M. ^[2]; Park, Eunsol ^[3]; Ma, Ke ^[3]; Cha, Jennifer N. ^[3]

Univ. of Colorado, Boulder, CO (United States); DOE/OSTI
National Inst. of Standards and Technology (NIST), Boulder, CO (United States)
Univ. of Colorado, Boulder, CO (United States)

There has been active interest to identify new methods to reduce CO₂ into usable fuel sources. In this work, we demonstrate two types of photo-electrochemical cells (PECs) that photoreduce CO₂ directly to formate in aqueous solutions both in the presence and absence of external bias or additional electron sources. The photocathodes were either a CuFeO₂/CuO electrode or a bilayer of CdTe on NiO, whereas the photoanode was a bilayer of NiO_x on CdS. The PECs were characterized by using both electrochemistry and spectroscopy, and the products formed from CO₂ reduction were characterized and quantified by using ¹H NMR spectroscopy and ESI-MS. In addition, an organohydride catalyst was tested in conjunction with the PECs, which not only showed a significant gain of 85 times in CO₂ reduction (27 μm formate without the catalyst, 2.3 mm formate with it) compared to the NiO/CdTe photocathode system but could also generate methanol under an external bias (10 μm).

View Accepted Manuscript (DOE)

Research Organization:: Univ. of California, San Diego, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0006398

OSTI ID:: 1533150

Journal Information:: ChemSusChem, Journal Name: ChemSusChem Journal Issue: 22 Vol. 9; ISSN 1864-5631

Publisher:: ChemPubSoc EuropeCopyright Statement

Country of Publication:: United States

Language:: English

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