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Title: Bimetallic Cooperativity in Proton Reduction with an Amido-Bridged Cobalt Catalyst

Abstract

Not provided.

Authors:
ORCiD logo [1];  [2];  [3];  [1]; ORCiD logo [3]; ORCiD logo [1]
  1. Department of Chemistry, Wayne State University, 5101 Cass Ave Detroit MI 48202 USA
  2. Department of Chemistry, Wayne State University, 5101 Cass Ave Detroit MI 48202 USA; Current address: Department of Chemistry, Hofstra University, Berliner Hall, Hempstead NY 11549 USA
  3. Department of Chemistry, Marquette University, 535 N. 14th St. Milwaukee WI 53233 USA
Publication Date:
Research Org.:
Wayne State Univ., Detroit, MI (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1533140
DOE Contract Number:  
SC0001907
Resource Type:
Journal Article
Journal Name:
Chemistry - A European Journal
Additional Journal Information:
Journal Volume: 23; Journal Issue: 39; Journal ID: ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English
Subject:
Chemistry

Citation Formats

Kpogo, Kenneth K., Mazumder, Shivnath, Wang, Denan, Schlegel, H. Bernhard, Fiedler, Adam T., and Verani, Cláudio N. Bimetallic Cooperativity in Proton Reduction with an Amido-Bridged Cobalt Catalyst. United States: N. p., 2017. Web. doi:10.1002/chem.201701982.
Kpogo, Kenneth K., Mazumder, Shivnath, Wang, Denan, Schlegel, H. Bernhard, Fiedler, Adam T., & Verani, Cláudio N. Bimetallic Cooperativity in Proton Reduction with an Amido-Bridged Cobalt Catalyst. United States. doi:10.1002/chem.201701982.
Kpogo, Kenneth K., Mazumder, Shivnath, Wang, Denan, Schlegel, H. Bernhard, Fiedler, Adam T., and Verani, Cláudio N. Fri . "Bimetallic Cooperativity in Proton Reduction with an Amido-Bridged Cobalt Catalyst". United States. doi:10.1002/chem.201701982.
@article{osti_1533140,
title = {Bimetallic Cooperativity in Proton Reduction with an Amido-Bridged Cobalt Catalyst},
author = {Kpogo, Kenneth K. and Mazumder, Shivnath and Wang, Denan and Schlegel, H. Bernhard and Fiedler, Adam T. and Verani, Cláudio N.},
abstractNote = {Not provided.},
doi = {10.1002/chem.201701982},
journal = {Chemistry - A European Journal},
issn = {0947-6539},
number = 39,
volume = 23,
place = {United States},
year = {2017},
month = {6}
}

Works referenced in this record:

Sustainable Hydrogen Production
journal, August 2004


Powering the planet: Chemical challenges in solar energy utilization
journal, October 2006

  • Lewis, N. S.; Nocera, D. G.
  • Proceedings of the National Academy of Sciences, Vol. 103, Issue 43, p. 15729-15735
  • DOI: 10.1073/pnas.0603395103

Hydrogen Oxidation and Production Using Nickel-Based Molecular Catalysts with Positioned Proton Relays
journal, January 2006

  • Wilson, Aaron D.; Newell, Rachel H.; McNevin, Michael J.
  • Journal of the American Chemical Society, Vol. 128, Issue 1
  • DOI: 10.1021/ja056442y

Cobalt and nickel diimine-dioxime complexes as molecular electrocatalysts for hydrogen evolution with low overvoltages
journal, November 2009

  • Jacques, P. -A.; Artero, V.; Pecaut, J.
  • Proceedings of the National Academy of Sciences, Vol. 106, Issue 49
  • DOI: 10.1073/pnas.0907775106

Efficient electro/photocatalytic water reduction using a [Ni II (N 2 Py 3 )] 2+ complex
journal, January 2016

  • Kankanamalage, Pavithra H. A.; Mazumder, Shivnath; Tiwari, Vishwas
  • Chemical Communications, Vol. 52, Issue 91
  • DOI: 10.1039/C6CC06629A

Cobalt-catalyzed evolution of molecular hydrogen
journal, July 1986

  • Connolly, Philip; Espenson, James H.
  • Inorganic Chemistry, Vol. 25, Issue 16
  • DOI: 10.1021/ic00236a006

Substituent Effects on Cobalt Diglyoxime Catalysts for Hydrogen Evolution
journal, November 2011

  • Solis, Brian H.; Hammes-Schiffer, Sharon
  • Journal of the American Chemical Society, Vol. 133, Issue 47
  • DOI: 10.1021/ja208091e

Theoretical Analysis of Mechanistic Pathways for Hydrogen Evolution Catalyzed by Cobaloximes
journal, November 2011

  • Solis, Brian H.; Hammes-Schiffer, Sharon
  • Inorganic Chemistry, Vol. 50, Issue 21
  • DOI: 10.1021/ic201842v

Theoretical studies of the mechanism of catalytic hydrogen production by a cobaloxime
journal, January 2011

  • Muckerman, James T.; Fujita, Etsuko
  • Chemical Communications, Vol. 47, Issue 46
  • DOI: 10.1039/c1cc15330g

Effects of Ligand Modification and Protonation on Metal Oxime Hydrogen Evolution Electrocatalysts
journal, May 2013

  • Solis, Brian H.; Yu, Yinxi; Hammes-Schiffer, Sharon
  • Inorganic Chemistry, Vol. 52, Issue 12
  • DOI: 10.1021/ic400490y

Electrocatalytic Hydrogen Evolution at Low Overpotentials by Cobalt Macrocyclic Glyoxime and Tetraimine Complexes
journal, July 2007

  • Hu, Xile; Brunschwig, Bruce S.; Peters, Jonas C.
  • Journal of the American Chemical Society, Vol. 129, Issue 29
  • DOI: 10.1021/ja067876b

Molecular mechanisms of cobalt-catalyzed hydrogen evolution
journal, September 2012

  • Marinescu, S. C.; Winkler, J. R.; Gray, H. B.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 38
  • DOI: 10.1073/pnas.1213442109

Electrochemical Detection of Transient Cobalt Hydride Intermediates of Electrocatalytic Hydrogen Production
journal, June 2016

  • Wiedner, Eric S.; Bullock, R. Morris
  • Journal of the American Chemical Society, Vol. 138, Issue 26
  • DOI: 10.1021/jacs.6b04779

Linear Free Energy Relationships in the Hydrogen Evolution Reaction: Kinetic Analysis of a Cobaloxime Catalyst
journal, April 2016


Protonation Equilibrium and Hydrogen Production by a Dinuclear Cobalt–Hydride Complex Reduced by Cobaltocene with Trifluoroacetic Acid
journal, October 2013

  • Mandal, Sukanta; Shikano, Shinya; Yamada, Yusuke
  • Journal of the American Chemical Society, Vol. 135, Issue 41
  • DOI: 10.1021/ja408080z

Redox rich dicobalt macrocycles as templates for multi-electron transformations
journal, January 2009

  • Szymczak, Nathaniel K.; Berben, Louise A.; Peters, Jonas C.
  • Chemical Communications, Issue 44
  • DOI: 10.1039/b913946j

Electrocatalytic Proton Reduction by a Dicobalt Tetrakis-Schiff Base Macrocycle in Nonaqueous Electrolyte
journal, June 2014

  • Kal, Subhadeep; Filatov, Alexander S.; Dinolfo, Peter H.
  • Inorganic Chemistry, Vol. 53, Issue 14
  • DOI: 10.1021/ic500121f

Heterodinuclear metal complexes of phenol-based compartmental macrocycles
journal, July 1998


Catalytic hydrogen evolution from a covalently linked dicobaloxime
journal, July 2012

  • Valdez, C. N.; Dempsey, J. L.; Brunschwig, B. S.
  • Proceedings of the National Academy of Sciences, Vol. 109, Issue 39
  • DOI: 10.1073/pnas.1118329109

Catalysis of Proton Reduction by a [BO 4 ]-Bridged Dicobalt Glyoxime
journal, November 2014

  • Laga, Stephanie M.; Blakemore, James D.; Henling, Lawrence M.
  • Inorganic Chemistry, Vol. 53, Issue 24
  • DOI: 10.1021/ic501804h

Dinuclear Cobalt Complexes with a Decadentate Ligand Scaffold: Hydrogen Evolution and Oxygen Reduction Catalysis
journal, November 2015

  • Di Giovanni, Carlo; Gimbert-Suriñach, Carolina; Nippe, Michael
  • Chemistry - A European Journal, Vol. 22, Issue 1
  • DOI: 10.1002/chem.201503567

Modulation of electronic and redox properties in phenolate-rich cobalt( iii ) complexes and their implications for catalytic proton reduction
journal, January 2015

  • Basu, Debashis; Allard, Marco M.; Xavier, Fernando R.
  • Dalton Transactions, Vol. 44, Issue 7
  • DOI: 10.1039/C4DT03337J

Ligand Transformations and Efficient Proton/Water Reduction with Cobalt Catalysts Based on Pentadentate Pyridine-Rich Environments
journal, December 2014

  • Basu, Debashis; Mazumder, Shivnath; Shi, Xuetao
  • Angewandte Chemie International Edition, Vol. 54, Issue 7
  • DOI: 10.1002/anie.201409813

Ligand Transformations and Efficient Proton/Water Reduction with Cobalt Catalysts Based on Pentadentate Pyridine-Rich Environments
journal, December 2014

  • Basu, Debashis; Mazumder, Shivnath; Shi, Xuetao
  • Angewandte Chemie, Vol. 127, Issue 7
  • DOI: 10.1002/ange.201409813

Distinct Proton and Water Reduction Behavior with a Cobalt(III) Electrocatalyst Based on Pentadentate Oximes
journal, April 2015

  • Basu, Debashis; Mazumder, Shivnath; Shi, Xuetao
  • Angewandte Chemie International Edition, Vol. 54, Issue 24
  • DOI: 10.1002/anie.201501410

Distinct Proton and Water Reduction Behavior with a Cobalt(III) Electrocatalyst Based on Pentadentate Oximes
journal, April 2015

  • Basu, Debashis; Mazumder, Shivnath; Shi, Xuetao
  • Angewandte Chemie, Vol. 127, Issue 24
  • DOI: 10.1002/ange.201501410

Evaluation of the coordination preferences and catalytic pathways of heteroaxial cobalt oximes towards hydrogen generation
journal, January 2016

  • Basu, Debashis; Mazumder, Shivnath; Niklas, Jens
  • Chemical Science, Vol. 7, Issue 5
  • DOI: 10.1039/C5SC04214C

Bimetallic Complexes Supported by a Redox-Active Ligand with Fused Pincer-Type Coordination Sites
journal, August 2015


Direct Determination of Equilibrium Potentials for Hydrogen Oxidation/Production by Open Circuit Potential Measurements in Acetonitrile
journal, June 2012

  • Roberts, John A. S.; Bullock, R. Morris
  • Inorganic Chemistry, Vol. 52, Issue 7
  • DOI: 10.1021/ic302461q

H 2 Evolution and Molecular Electrocatalysts: Determination of Overpotentials and Effect of Homoconjugation
journal, November 2010

  • Fourmond, Vincent; Jacques, Pierre-André; Fontecave, Marc
  • Inorganic Chemistry, Vol. 49, Issue 22
  • DOI: 10.1021/ic101187v

Molecular and Electronic Structures of Bis(pyridine-2,6-diimine)metal Complexes [ML 2 ](PF 6 ) n ( n = 0, 1, 2, 3; M = Mn, Fe, Co, Ni, Cu, Zn)
journal, June 2000

  • de Bruin, Bas; Bill, Eckhard; Bothe, Eberhard
  • Inorganic Chemistry, Vol. 39, Issue 13
  • DOI: 10.1021/ic000113j

Structural characterization and proton reduction electrocatalysis of thiolate-bridged bimetallic (CoCo and CoFe) complexes
journal, January 2016

  • Tong, Peng; Xie, Wenjie; Yang, Dawei
  • Dalton Transactions, Vol. 45, Issue 46
  • DOI: 10.1039/C6DT03275C

Mechanistic Insight into Peroxydisulfate Reactivity: Oxidation of the cis , cis -[Ru(bpy) 2 (OH 2 )] 2 O 4+ “Blue Dimer”
journal, December 2014

  • Hurst, James K.; Roemeling, Margo D.; Lymar, Sergei V.
  • The Journal of Physical Chemistry B, Vol. 119, Issue 24
  • DOI: 10.1021/acs.jpcb.5b00922

Accurate and simple analytic representation of the electron-gas correlation energy
journal, June 1992


Energy‐adjusted a b i n i t i o pseudopotentials for the first row transition elements
journal, January 1987

  • Dolg, M.; Wedig, U.; Stoll, H.
  • The Journal of Chemical Physics, Vol. 86, Issue 2
  • DOI: 10.1063/1.452288

The influence of polarization functions on molecular orbital hydrogenation energies
journal, January 1973

  • Hariharan, P. C.; Pople, J. A.
  • Theoretica Chimica Acta, Vol. 28, Issue 3
  • DOI: 10.1007/BF00533485

Self‐consistent molecular orbital methods. XXIII. A polarization‐type basis set for second‐row elements
journal, October 1982

  • Francl, Michelle M.; Pietro, William J.; Hehre, Warren J.
  • The Journal of Chemical Physics, Vol. 77, Issue 7, p. 3654-3665
  • DOI: 10.1063/1.444267

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions
journal, May 2009

  • Marenich, Aleksandr V.; Cramer, Christopher J.; Truhlar, Donald G.
  • The Journal of Physical Chemistry B, Vol. 113, Issue 18, p. 6378-6396
  • DOI: 10.1021/jp810292n

Definition of corresponding orbitals and the diradical character in broken symmetry DFT calculations on spin coupled systems
journal, April 2004


Aqueous Solvation Free Energies of Ions and Ion−Water Clusters Based on an Accurate Value for the Absolute Aqueous Solvation Free Energy of the Proton
journal, August 2006

  • Kelly, Casey P.; Cramer, Christopher J.; Truhlar, Donald G.
  • The Journal of Physical Chemistry B, Vol. 110, Issue 32
  • DOI: 10.1021/jp063552y