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Title: Unraveling the Nature of Sites Active toward Hydrogen Peroxide Reduction in Fe-N-C Catalysts

Journal Article · · Angewandte Chemie (International Edition)
ORCiD logo [1];  [2];  [2]; ORCiD logo [3]; ORCiD logo [4];  [4];  [5];  [6];  [6]; ORCiD logo [7]; ORCiD logo [4]
  1. School of Materials Science and Engineering, Gwangju Institute of Science and Technology, Gwangju 61005 Republic of Korea
  2. Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Strasse 1 40237 Düsseldorf Germany
  3. Université de Montpellier, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon 34095 Montpellier France; Max Planck Institute for Chemical Energy Conversion, Stiftstraße 34-36 45470 Mülheim a.d. Ruhr Germany
  4. Université de Montpellier, Institut Charles Gerhardt Montpellier, 2 place Eugène Bataillon 34095 Montpellier France
  5. Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Strasse 1 40237 Düsseldorf Germany; Department of Chemistry and Chemical Biology, Northeastern University, Boston MA 02115 USA
  6. Department of Chemistry and Chemical Biology, Northeastern University, Boston MA 02115 USA
  7. Max-Planck-Institut für Eisenforschung GmbH, Max-Planck-Strasse 1 40237 Düsseldorf Germany; Helmholtz-Institute Erlangen-Nürnberg for Renewable Energy Forschungszentrum, Jülich Germany; Department of Chemical and Biological Engineering, Friedrich-Alexander-Universität Erlangen-Nürnberg, Egerlandstrasse 3 91058 Erlangen Germany

Not provided.

Research Organization:
Northeastern Univ., Boston, MA (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
DOE Contract Number:
EE0000459
OSTI ID:
1533108
Journal Information:
Angewandte Chemie (International Edition), Vol. 56, Issue 30; ISSN 1433-7851
Publisher:
Wiley
Country of Publication:
United States
Language:
English

References (38)

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N-doped carbon nanomaterials are durable catalysts for oxygen reduction reaction in acidic fuel cells journal February 2015
A class of non-precious metal composite catalysts for fuel cells journal September 2006
Iron-Based Catalysts with Improved Oxygen Reduction Activity in Polymer Electrolyte Fuel Cells journal April 2009
Cross-Laboratory Experimental Study of Non-Noble-Metal Electrocatalysts for the Oxygen Reduction Reaction journal July 2009
High-Performance Electrocatalysts for Oxygen Reduction Derived from Polyaniline, Iron, and Cobalt journal April 2011
Ordered mesoporous porphyrinic carbons with very high electrocatalytic activity for the oxygen reduction reaction journal September 2013
A dual-metal–organic-framework derived electrocatalyst for oxygen reduction journal January 2016
A metal–organic framework-derived bifunctional oxygen electrocatalyst journal January 2016
An Fe–N–C hybrid electrocatalyst derived from a bimetal–organic framework for efficient oxygen reduction journal January 2016
On the Role of Metals in Nitrogen-Doped Carbon Electrocatalysts for Oxygen Reduction journal July 2015
Über die Rolle von Metallen in Elektrokatalysatoren auf Basis von stickstoffdotiertem Kohlenstoff für die Sauerstoffreduktion journal July 2015
Degradation by Hydrogen Peroxide of Metal-Nitrogen-Carbon Catalysts for Oxygen Reduction journal January 2015
Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron-Ligand Coordination Strength journal May 2013
Optimized Synthesis of Fe/N/C Cathode Catalysts for PEM Fuel Cells: A Matter of Iron-Ligand Coordination Strength journal May 2013
Correlations between Mass Activity and Physicochemical Properties of Fe/N/C Catalysts for the ORR in PEM Fuel Cell via 57 Fe Mössbauer Spectroscopy and Other Techniques journal January 2014
Probing active sites in iron-based catalysts for oxygen electro-reduction: A temperature-dependent 57 Fe Mössbauer spectroscopy study journal March 2016
Activity Descriptor Identification for Oxygen Reduction on Nonprecious Electrocatalysts: Linking Surface Science to Coordination Chemistry journal October 2013
Experimental Observation of Redox-Induced Fe–N Switching Behavior as a Determinant Role for Oxygen Reduction Activity journal October 2015
Structural and mechanistic basis for the high activity of Fe–N–C catalysts toward oxygen reduction journal January 2016
Molecular Oxygen Reduction in PEM Fuel Cell Conditions:  ToF-SIMS Analysis of Co-Based Electrocatalysts journal September 2005
Determination of Iron Active Sites in Pyrolyzed Iron-Based Catalysts for the Oxygen Reduction Reaction journal November 2012
Quantifying the density and utilization of active sites in non-precious metal oxygen electroreduction catalysts journal October 2015
Highly active oxygen reduction non-platinum group metal electrocatalyst without direct metal–nitrogen coordination journal June 2015
Identification of catalytic sites for oxygen reduction in iron- and nitrogen-doped graphene materials journal August 2015
Identification of carbon-encapsulated iron nanoparticles as active species in non-precious metal oxygen reduction catalysts journal August 2016
Bifunctional Oxygen Reduction Reaction Mechanism on Non-Platinum Catalysts Derived from Pyrolyzed Porphyrins journal January 2010
A mechanistic study of 4-aminoantipyrine and iron derived non-platinum group metal catalyst on the oxygen reduction reaction journal February 2013
Mechanistic studies of oxygen reduction on Fe-PEI derived non-PGM electrocatalysts journal May 2014
Elucidating Oxygen Reduction Active Sites in Pyrolyzed Metal–Nitrogen Coordinated Non-Precious-Metal Electrocatalyst Systems journal April 2014
Chemistry of Multitudinous Active Sites for Oxygen Reduction Reaction in Transition Metal–Nitrogen–Carbon Electrocatalysts journal November 2015
Stability of Fe-N-C Catalysts in Acidic Medium Studied by Operando Spectroscopy journal August 2015
Stability of Fe-N-C Catalysts in Acidic Medium Studied by Operando Spectroscopy journal August 2015
Minimizing Operando Demetallation of Fe-N-C Electrocatalysts in Acidic Medium journal April 2016
Is iron involved in the lack of stability of Fe/N/C electrocatalysts used to reduce oxygen at the cathode of PEM fuel cells? journal November 2016
On an Easy Way To Prepare Metal–Nitrogen Doped Carbon with Exclusive Presence of MeN 4 -type Sites Active for the ORR journal January 2016
Mechanistic Discussion of the Oxygen Reduction Reaction at Nitrogen-Doped Carbon Nanotubes journal September 2011
Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells journal August 2011

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