Beryllium-Free β-Rb2Al2B2O7 as a Possible Deep-Ultraviolet Nonlinear Optical Material Replacement for KBe2BO3F2

Tran, T. Thao; Koocher, Nathan Z.; Rondinelli, James M.; Halasyamani, P. Shiv

doi:10.1002/anie.201612236

Title: Beryllium-Free β-Rb₂Al₂B₂O₇ as a Possible Deep-Ultraviolet Nonlinear Optical Material Replacement for KBe₂BO₃F₂

Journal Article · Tue Jan 31 00:00:00 EST 2017 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201612236· OSTI ID:1533096

Tran, T. Thao ^[1]; Koocher, Nathan Z. ^[2];

^[2];

^[1]

Univ. of Houston, TX (United States)
Northwestern Univ., Evanston, IL (United States)

Abstract A new beryllium‐free deep‐ultraviolet (DUV) nonlinear optical (NLO) material, β‐Rb ₂ Al ₂ B ₂ O ₇ (β‐RABO), has been synthesized and characterized. The chiral nonpolar acentric material shows second‐harmonic generation (SHG) activity at both 1064 and 532 nm with efficiencies of 2×KH ₂ PO ₄ and 0.4×β‐BaB ₂ O ₄ , respectively, and exhibits a short absorption edge below 200 nm. β‐Rb ₂ Al ₂ B ₂ O ₇ has a three‐dimensional structure of corner‐shared Al(BO ₃ ) ₃ O polyhedra. The discovery of β‐RABO shows that through careful synthesis and characterization, replacement of KBe ₂ BO ₃ F ₂ (KBBF) by a Be‐free DUV NLO material is possible.

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Research Organization:: Pennsylvania State Univ., University Park, PA (United States); Argonne National Laboratory (ANL), Argonne, IL (United States). Center for Nanoscale Materials (CNM)

Sponsoring Organization:: USDOE Office of Science (SC); Welch Foundation; National Science Foundation (NSF)

Grant/Contract Number:: SC0012375; AC02-06CH11357; E-1457

OSTI ID:: 1533096

Alternate ID(s):: OSTI ID: 1401050

Journal Information:: Angewandte Chemie (International Edition), Vol. 56, Issue 11; ISSN 1433-7851

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 130 works

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Title: Beryllium-Free β-Rb2Al2B2O7 as a Possible Deep-Ultraviolet Nonlinear Optical Material Replacement for KBe2BO3F2

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Title: Beryllium-Free β-Rb₂Al₂B₂O₇ as a Possible Deep-Ultraviolet Nonlinear Optical Material Replacement for KBe₂BO₃F₂