A Robust and Conductive Black Tin Oxide Nanostructure Makes Efficient Lithium-Ion Batteries Possible

Dong, Wujie; Xu, Jijian; Wang, Chao; Lu, Yue; Liu, Xiangye; Wang, Xin; Yuan, Xiaotao; Wang, Zhe; Lin, Tianquan; Sui, Manling; Chen, I-Wei; Huang, Fuqiang

doi:10.1002/adma.201700136

A Robust and Conductive Black Tin Oxide Nanostructure Makes Efficient Lithium-Ion Batteries Possible

Journal Article · Fri Apr 21 00:00:00 EDT 2017 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201700136· OSTI ID:1533039

Dong, Wujie ^[1]; Xu, Jijian ^[2]; Wang, Chao ^[3]; Lu, Yue ^[4]; Liu, Xiangye ^[3]; Wang, Xin ^[3]; Yuan, Xiaotao ^[3]; Wang, Zhe ^[3]; Lin, Tianquan ^[2]; Sui, Manling ^[4]; Chen, I-Wei ^[5]; Huang, Fuqiang ^[6]

Peking Univ., Beijing (China). Beijing National Lab. for Molecular Sciences. State Key Lab. of Rare Earth Materials Chemistry and Applications. College of Chemistry and Molecular Engineering; DOE/OSTI
Chinese Academy of Sciences (CAS), Shanghai (China). State Key Lab. of High Performance Ceramics and Superfine Microstructures. Shanghai Inst. of Ceramics
Peking Univ., Beijing (China). Beijing National Lab. for Molecular Sciences. State Key Lab. of Rare Earth Materials Chemistry and Applications. College of Chemistry and Molecular Engineering
Beijing Univ. of Technology (China). Inst. of Microstructure and Properties of Advanced Materials
Univ. of Pennsylvania, Philadelphia, PA (United States). Dept. of Materials Science and Engineering
Peking Univ., Beijing (China). Beijing National Lab. for Molecular Sciences. State Key Lab. of Rare Earth Materials Chemistry and Applications. College of Chemistry and Molecular Engineering; Chinese Academy of Sciences (CAS), Shanghai (China). State Key Lab. of High Performance Ceramics and Superfine Microstructures. Shanghai Inst. of Ceramics

SnO₂-based lithium-ion batteries have low cost and high energy density, but their capacity fades rapidly during lithiation/delithiation due to phase aggregation and cracking. These problems can be mitigated by using highly conducting black SnO_2-x, which homogenizes the redox reactions and stabilizes fine, fracture-resistant Sn precipitates in the Li₂O matrix. Such fine Sn precipitates and their ample contact with Li₂O proliferate the reversible Sn → Li _xSn → Sn → SnO₂/SnO_2-x cycle during charging/discharging. SnO_2-x electrode has a reversible capacity of 1340 mAh g^-1 and retains 590 mAh g^-1 after 100 cycles. The addition of highly conductive, well-dispersed reduced graphene oxide further stabilizes and improves its performance, allowing 950 mAh g^-1 remaining after 100 cycles at 0.2 A g^-1 with 700 mAh g^-1 at 2.0 A g^-1. Conductivity-directed microstructure development may offer a new approach to form advanced electrodes.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Pennsylvania, Philadelphia, PA (United States); Peking Univ., Beijing (China); Chinese Academy of Sciences (CAS), Shanghai (China)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China; National Science Foundation of China; Science and Technology Commission of Shanghai (China); Key Research Program of Chinese Academy of Sciences

Grant/Contract Number:: SC0007064

OSTI ID:: 1533039

Alternate ID(s):: OSTI ID: 1401538

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 24 Vol. 29; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

References (39)

N-Doped Graphene-SnO2 Sandwich Paper for High-Performance Lithium-Ion Batteries Wang, Xi; Cao, Xinqiang; Bourgeois, Laure Advanced Functional Materials, Vol. 22, Issue 13 https://doi.org/10.1002/adfm.201103110	journal	April 2012
Graphene-Based Mesoporous SnO ₂ with Enhanced Electrochemical Performance for Lithium-Ion Batteries Yang, Sheng; Yue, Wenbo; Zhu, Jia Advanced Functional Materials, Vol. 23, Issue 28 https://doi.org/10.1002/adfm.201203286	journal	February 2013
Highly Reversible Lithium Storage in Porous SnO2 Nanotubes with Coaxially Grown Carbon Nanotube Overlayers Wang, Y.; Zeng, H. C.; Lee, J. Y. Advanced Materials, Vol. 18, Issue 5 https://doi.org/10.1002/adma.200501883	journal	March 2006
Binding SnO ₂ Nanocrystals in Nitrogen-Doped Graphene Sheets as Anode Materials for Lithium-Ion Batteries Zhou, Xiaosi; Wan, Li-Jun; Guo, Yu-Guo Advanced Materials, Vol. 25, Issue 15 https://doi.org/10.1002/adma.201300071	journal	February 2013
SnO ₂ /Graphene Composites with Self-Assembled Alternating Oxide and Amine Layers for High Li-Storage and Excellent Stability Prabakar, S. J. Richard; Hwang, Yun-Hwa; Bae, Eun-Gyoung Advanced Materials, Vol. 25, Issue 24 https://doi.org/10.1002/adma.201301264	journal	May 2013
Three-Dimensional SnO ₂ Nanowire Networks for Multifunctional Applications: From High-Temperature Stretchable Ceramics to Ultraresponsive Sensors Paulowicz, Ingo; Hrkac, Viktor; Kaps, Sören Advanced Electronic Materials, Vol. 1, Issue 8 https://doi.org/10.1002/aelm.201500081	journal	June 2015
Ordered Network of Interconnected SnO ₂ Nanoparticles for Excellent Lithium-Ion Storage Etacheri, Vinodkumar; Seisenbaeva, Gulaim A.; Caruthers, James Advanced Energy Materials, Vol. 5, Issue 5 https://doi.org/10.1002/aenm.201401289	journal	November 2014
Li2SnO3 Derived Secondary Li—Sn Alloy Electrode for Lithium-Ion Batteries. Zhang, D. W.; Zhang, S. Q.; Jin, Y. ChemInform, Vol. 37, Issue 31 https://doi.org/10.1002/chin.200631020	journal	August 2006
SnO2/graphene composite with high lithium storage capability for lithium rechargeable batteries Kim, Haegyeom; Kim, Sung-Wook; Park, Young-Uk Nano Research, Vol. 3, Issue 11 https://doi.org/10.1007/s12274-010-0050-4	journal	October 2010
Gas-sensing characteristics of SnO2—x thin film with added Pt fabricated by the dipping method Lee, Duk-Dong; Chung, Wan-Young Sensors and Actuators, Vol. 20, Issue 3 https://doi.org/10.1016/0250-6874(89)80129-5	journal	December 1989
Surface morphology and gas-sensing characteristics of SnO2−x thin films oxidized from Sn films Yoo, Kwang Soo; Cho, Nam Woong; Song, Han Sang Sensors and Actuators B: Chemical, Vol. 25, Issue 1-3 https://doi.org/10.1016/0925-4005(95)85101-1	journal	April 1995
Plasma-polymerized C60 as a functionalized coating layer on fluorine-doped tin oxides for anode materials of lithium-ion batteries Hudaya, Chairul; Kang, Bongjo; Jung, Hun-Gi Carbon, Vol. 81 https://doi.org/10.1016/j.carbon.2014.09.015	journal	January 2015
Nonaqueous and template-free synthesis of Sb doped SnO2 microspheres and their application to lithium-ion battery anode Wang, Yude; Chen, Ting Electrochimica Acta, Vol. 54, Issue 13 https://doi.org/10.1016/j.electacta.2008.11.039	journal	May 2009
Li2SnO3 derived secondary Li–Sn alloy electrode for lithium-ion batteries Zhang, D. W.; Zhang, S. Q.; Jin, Y. Journal of Alloys and Compounds, Vol. 415, Issue 1-2 https://doi.org/10.1016/j.jallcom.2005.05.053	journal	May 2006
Fluorine-doped nanocrystalline SnO2 powders prepared via a single molecular precursor method as anode materials for Li-ion batteries Ha, Hyung-Wook; Kim, Keon; Borniol, Mervyn de Journal of Solid State Chemistry, Vol. 179, Issue 3 https://doi.org/10.1016/j.jssc.2005.11.022	journal	March 2006
Nanocrystalline SnO2 and In-doped SnO2 as anode materials for lithium batteries Subramanian, V. Solid State Ionics, Vol. 175, Issue 1-4 https://doi.org/10.1016/j.ssi.2004.07.069	journal	November 2004
Al-doped SnO2 hollow sphere as a novel anode material for lithium ion battery Wei, Chengwen; Zhang, Guoxi; Bai, Ying Solid State Ionics, Vol. 272 https://doi.org/10.1016/j.ssi.2015.01.014	journal	April 2015
Scattering mechanism of transparent conducting tin oxide films prepared by magnetron sputtering Kim, I. H.; Ko, J. H.; Kim, D. Thin Solid Films, Vol. 515, Issue 4 https://doi.org/10.1016/j.tsf.2006.07.020	journal	December 2006
Fluorine-Doped SnO ₂ @Graphene Porous Composite for High Capacity Lithium-Ion Batteries Sun, Jinhua; Xiao, Linhong; Jiang, Shidong Chemistry of Materials, Vol. 27, Issue 13 https://doi.org/10.1021/acs.chemmater.5b00885	journal	June 2015
Antimony-Doped SnO ₂ Nanopowders with High Crystallinity for Lithium-Ion Battery Electrode Wang, Yude; Djerdj, Igor; Smarsly, Bernd Chemistry of Materials, Vol. 21, Issue 14 https://doi.org/10.1021/cm9007014	journal	July 2009
Preparation of Graphitic Oxide Hummers, William S.; Offeman, Richard E. Journal of the American Chemical Society, Vol. 80, Issue 6, p. 1339-1339 https://doi.org/10.1021/ja01539a017	journal	March 1958
Localized Excitation of Ti ³⁺ Ions in the Photoabsorption and Photocatalytic Activity of Reduced Rutile TiO ₂ Wang, Zhiqiang; Wen, Bo; Hao, Qunqing Journal of the American Chemical Society, Vol. 137, Issue 28 https://doi.org/10.1021/jacs.5b04483	journal	July 2015
Synthesis of Ultrafine SnO ₂ _- _x Nanocrystals by Pulsed Laser-Induced Reactive Quenching in Liquid Medium Liang, Changhao; Shimizu, Yoshiki; Sasaki, Takeshi The Journal of Physical Chemistry B, Vol. 107, Issue 35 https://doi.org/10.1021/jp0347466	journal	September 2003
CNTs@SnO ₂ @C Coaxial Nanocables with Highly Reversible Lithium Storage Wu, Ping; Du, Ning; Zhang, Hui The Journal of Physical Chemistry C, Vol. 114, Issue 51 https://doi.org/10.1021/jp1102109	journal	December 2010
SnO ₂ –Graphene Composite Synthesized via an Ultrafast and Environmentally Friendly Microwave Autoclave Method and Its Use as a Superior Anode for Lithium-Ion Batteries Zhong, Chao; Wang, Jiazhao; Chen, Zhixin The Journal of Physical Chemistry C, Vol. 115, Issue 50 https://doi.org/10.1021/jp2061128	journal	November 2011
Highly Conductive Coaxial SnO ₂ −In ₂ O ₃ Heterostructured Nanowires for Li Ion Battery Electrodes Kim, Dong-Wan; Hwang, In-Sung; Kwon, S. Joon Nano Letters, Vol. 7, Issue 10 https://doi.org/10.1021/nl0715037	journal	October 2007
Low-Temperature Aluminum Reduction of Graphene Oxide, Electrical Properties, Surface Wettability, and Energy Storage Applications Wan, Dongyun; Yang, Chongyin; Lin, Tianquan ACS Nano, Vol. 6, Issue 10 https://doi.org/10.1021/nn303228r	journal	September 2012
A facile one-pot reduction method for the preparation of a SnO/SnO ₂ /GNS composite for high performance lithium ion batteries Chen, Xiao-Ting; Wang, Kai-Xue; Zhai, Yu-Bo Dalton Trans., Vol. 43, Issue 8 https://doi.org/10.1039/C3DT52661E	journal	January 2014
Mo-doped SnO ₂ mesoporous hollow structured spheres as anode materials for high-performance lithium ion batteries Wang, Xuekun; Li, Zhaoqiang; Zhang, Zhiwei Nanoscale, Vol. 7, Issue 8 https://doi.org/10.1039/C4NR05789A	journal	January 2015
Facile synthesis of SnO ₂ nanocrystals anchored onto graphene nanosheets as anode materials for lithium-ion batteries Zhang, Yanjun; Jiang, Li; Wang, Chunru Physical Chemistry Chemical Physics, Vol. 17, Issue 31 https://doi.org/10.1039/C5CP03305E	journal	January 2015
Spatially-confined lithiation–delithiation in highly dense nanocomposite anodes towards advanced lithium-ion batteries Jiang, Yinzhu; Li, Yong; Sun, Wenping Energy & Environmental Science, Vol. 8, Issue 5 https://doi.org/10.1039/C5EE00314H	journal	January 2015
Dramatically enhanced reversibility of Li ₂ O in SnO ₂ -based electrodes: the effect of nanostructure on high initial reversible capacity Hu, Renzong; Chen, Dongchang; Waller, Gordon Energy & Environmental Science, Vol. 9, Issue 2 https://doi.org/10.1039/C5EE03367E	journal	January 2016
Visible-light photocatalytic, solar thermal and photoelectrochemical properties of aluminium-reduced black titania Wang, Zhou; Yang, Chongyin; Lin, Tianquan Energy & Environmental Science, Vol. 6, Issue 10 https://doi.org/10.1039/c3ee41817k	journal	January 2013
The fast filling of nano-SnO2 in CNTs by vacuum absorption: a new approach to realize cyclic durable anodes for lithium ion batteries Hu, Renzong; Sun, Wei; Liu, Hui Nanoscale, Vol. 5, Issue 23 https://doi.org/10.1039/c3nr03756h	journal	January 2013
Self-supported SnO ₂ nanowire electrodes for high-power lithium-ion batteries Ko, Young-Dae; Kang, Jin-Gu; Park, Jae-Gwan Nanotechnology, Vol. 20, Issue 45 https://doi.org/10.1088/0957-4484/20/45/455701	journal	October 2009
Chemical shifts and optical properties of tin oxide films grown by a reactive ion assisted deposition Choi, Won‐Kook; Jung, Hyung‐Jin; Koh, Seok‐Keun Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 14, Issue 2 https://doi.org/10.1116/1.579901	journal	March 1996
In Situ Observation of the Electrochemical Lithiation of a Single SnO₂ Nanowire Electrode Huang, J. Y.; Zhong, L.; Wang, C. M. Science, Vol. 330, Issue 6010, p. 1515-1520 https://doi.org/10.1126/science.1195628	journal	December 2010
Tin-Based Amorphous Oxide: A High-Capacity Lithium-Ion-Storage Material Idota, Y. Science, Vol. 276, Issue 5317 https://doi.org/10.1126/science.276.5317.1395	journal	May 1997
Electrochemical and In Situ X-Ray Diffraction Studies of the Reaction of Lithium with Tin Oxide Composites Courtney, Ian A.; Dahn, J. R. Journal of The Electrochemical Society, Vol. 144, Issue 6, p. 2045-2052 https://doi.org/10.1149/1.1837740	journal	January 1997

Cited By (34)

Boron Embedded in Metal Iron Matrix as a Novel Anode Material of Excellent Performance Dong, Wujie; Zhao, Yantao; Wang, Xin Advanced Materials, Vol. 30, Issue 35 https://doi.org/10.1002/adma.201801409	journal	July 2018
Robust SnO _{2− x} Nanoparticle-Impregnated Carbon Nanofibers with Outstanding Electrochemical Performance for Advanced Sodium-Ion Batteries Ma, Dingtao; Li, Yongliang; Mi, Hongwei Angewandte Chemie, Vol. 130, Issue 29 https://doi.org/10.1002/ange.201802672	journal	May 2018
Stable Confinement of Black Phosphorus Quantum Dots on Black Tin Oxide Nanotubes: A Robust, Double‐Active Electrocatalyst toward Efficient Nitrogen Fixation Liu, Yi‐Tao; Li, Di; Yu, Jianyong Angewandte Chemie, Vol. 131, Issue 46 https://doi.org/10.1002/ange.201908415	journal	October 2019
A Multi‐Wall Sn/SnO ₂ @Carbon Hollow Nanofiber Anode Material for High‐Rate and Long‐Life Lithium‐Ion Batteries Gao, Songwei; Wang, Nü; Li, Shuai Angewandte Chemie, Vol. 132, Issue 6 https://doi.org/10.1002/ange.201913170	journal	December 2019
Robust SnO _{2− x} Nanoparticle-Impregnated Carbon Nanofibers with Outstanding Electrochemical Performance for Advanced Sodium-Ion Batteries Ma, Dingtao; Li, Yongliang; Mi, Hongwei Angewandte Chemie International Edition, Vol. 57, Issue 29 https://doi.org/10.1002/anie.201802672	journal	May 2018
Stable Confinement of Black Phosphorus Quantum Dots on Black Tin Oxide Nanotubes: A Robust, Double‐Active Electrocatalyst toward Efficient Nitrogen Fixation Liu, Yi‐Tao; Li, Di; Yu, Jianyong Angewandte Chemie International Edition, Vol. 58, Issue 46 https://doi.org/10.1002/anie.201908415	journal	November 2019
A Multi‐Wall Sn/SnO ₂ @Carbon Hollow Nanofiber Anode Material for High‐Rate and Long‐Life Lithium‐Ion Batteries Gao, Songwei; Wang, Nü; Li, Shuai Angewandte Chemie International Edition, Vol. 59, Issue 6 https://doi.org/10.1002/anie.201913170	journal	February 2020
Ultrafine SnO ₂ Nanocrystals Self-Anchored in Carbon for Stable Lithium Storage Fu, Shuting; Wu, Qili; He, Shiman ChemElectroChem, Vol. 5, Issue 17 https://doi.org/10.1002/celc.201800631	journal	June 2018
Ultrafine SnO ₂ Nanocrystals Self-Anchored in Carbon for Stable Lithium Storage Fu, Shuting; Wu, Qili; He, Shiman ChemElectroChem, Vol. 5, Issue 17 https://doi.org/10.1002/celc.201800963	journal	July 2018
Oxygen Vacancy Engineering in Tin(IV) Oxide Based Anode Materials toward Advanced Sodium-Ion Batteries Ma, Dingtao; Li, Yongliang; Zhang, Peixin ChemSusChem, Vol. 11, Issue 21 https://doi.org/10.1002/cssc.201801694	journal	October 2018
Reactivating Li ₂ O with Nano‐Sn to Achieve Ultrahigh Initial Coulombic Efficiency SiO Anodes for Li‐Ion Batteries Fu, Rusheng; Wu, Yongkang; Fan, Chongzhao ChemSusChem, Vol. 12, Issue 14 https://doi.org/10.1002/cssc.201900541	journal	June 2019
A review of rechargeable batteries for portable electronic devices Liang, Yeru; Zhao, Chen‐Zi; Yuan, Hong InfoMat, Vol. 1, Issue 1 https://doi.org/10.1002/inf2.12000	journal	March 2019
Micrometer‐Sized Porous Fe ₂ N/C Bulk for High‐Areal‐Capacity and Stable Lithium Storage Liu, Dongna; Xu, Xiaoming; Tan, Jian Small https://doi.org/10.1002/smll.201803572	journal	December 2018
Ultrafine Co ₃ O ₄ Nanoparticles within Nitrogen‐Doped Carbon Matrix Derived from Metal–Organic Complex for Boosting Lithium Storage and Oxygen Evolution Reaction Zhang, Jingyuan; Qian, Bin; Sun, Shuo Small, Vol. 15, Issue 46 https://doi.org/10.1002/smll.201904260	journal	September 2019
Hydrothermal synthesis of nano-SnO2@SiO2 composites for lithium-ion battery anodes Liu, Xuyan; Han, Yanlin; Zeng, Jiahuan Journal of Materials Science: Materials in Electronics, Vol. 29, Issue 7 https://doi.org/10.1007/s10854-018-8541-2	journal	January 2018
Inhibiting grain coarsening and inducing oxygen vacancies: the roles of Mn in achieving a highly reversible conversion reaction and a long life SnO ₂ –Mn–graphite ternary anode Hu, Renzong; Ouyang, Yunpeng; Liang, Tao Energy & Environmental Science, Vol. 10, Issue 9 https://doi.org/10.1039/c7ee01635b	journal	January 2017
In situ synthesized SnSe nanorods in a SnO _x @CNF membrane toward high-performance freestanding and binder-free lithium-ion batteries Yuan, Haocheng; Jin, Yuqiang; Lan, Jinle Inorganic Chemistry Frontiers, Vol. 5, Issue 4 https://doi.org/10.1039/c7qi00762k	journal	January 2018
Phosphorized SnO ₂ /graphene heterostructures for highly reversible lithium-ion storage with enhanced pseudocapacitance Yang, Ying; Zhao, Xu; Wang, Hong-En Journal of Materials Chemistry A, Vol. 6, Issue 8 https://doi.org/10.1039/c7ta10435a	journal	January 2018
Elaborate synthesis of black tin oxide–black titanium oxide core–shell nanotubes for ultrastable and fast lithium storage Zhou, Zheng-Wei; Pan, Long; Liu, Yi-Tao Chemical Communications, Vol. 54, Issue 38 https://doi.org/10.1039/c8cc02040j	journal	January 2018
Hollow SnO ₂ nanospheres with oxygen vacancies entrapped by a N-doped graphene network as robust anode materials for lithium-ion batteries Wu, Naiteng; Du, Wuzhou; Gao, Xu Nanoscale, Vol. 10, Issue 24 https://doi.org/10.1039/c8nr02290a	journal	January 2018
Excimer ultraviolet-irradiated exfoliated graphite loaded with carbon-coated SnO _x small nanoparticles as advanced anodes for high-rate-capacity lithium-ion batteries Shen, Zhen; Hu, Yi; Chen, Renzhong Nanoscale, Vol. 11, Issue 16 https://doi.org/10.1039/c8nr10379h	journal	January 2019
Growth mechanism of SnC ₂ H ₄ O ₂ nanowires prepared by the polyol process as SnO ₂ precursor nanowires Park, DongKook; Lee, Man Sig RSC Advances, Vol. 9, Issue 6 https://doi.org/10.1039/c8ra09738k	journal	January 2019
A scalable ternary SnO ₂ –Co–C composite as a high initial coulombic efficiency, large capacity and long lifetime anode for lithium ion batteries Liang, Tao; Hu, Renzong; Zhang, Houpo Journal of Materials Chemistry A, Vol. 6, Issue 16 https://doi.org/10.1039/c8ta00957k	journal	January 2018
Reduced expansion and improved full-cell cycling of a SnO _x #C embedded structure for lithium-ion batteries Yang, Lie; Sun, Liu-Yang; Zhang, Rong-Rong Journal of Materials Chemistry A, Vol. 6, Issue 32 https://doi.org/10.1039/c8ta04822c	journal	January 2018
Two-dimensional porous silicon nanosheets as anode materials for high performance lithium-ion batteries Tang, Jingjing; Yin, Qifang; Wang, Qian Nanoscale, Vol. 11, Issue 22 https://doi.org/10.1039/c9nr01440c	journal	January 2019
Fully reversible lithium storage of tin oxide enabled by self-doping and partial amorphization Pang, Yuepeng; Wang, Jing; Yang, Junhe Nanoscale, Vol. 11, Issue 27 https://doi.org/10.1039/c9nr03445e	journal	January 2019
MoS ₂ nanoflowers encapsulated into carbon nanofibers containing amorphous SnO ₂ as an anode for lithium-ion batteries Chen, Huanhui; He, Jiao; Ke, Guanxia Nanoscale, Vol. 11, Issue 35 https://doi.org/10.1039/c9nr05631a	journal	January 2019
Sonochemistry-enabled uniform coupling of SnO ₂ nanocrystals with graphene sheets as anode materials for lithium-ion batteries Han, Xiaoyan; Li, Ran; Qiu, Shengqiang RSC Advances, Vol. 9, Issue 11 https://doi.org/10.1039/c9ra00554d	journal	January 2019
Assembly of high-nuclearity Sn26, Sn34-oxo clusters: solvent strategies and inorganic Sn incorporation Zhu, Yu; Zhang, Lei; Zhang, Jian Chemical Science, Vol. 10, Issue 39 https://doi.org/10.1039/c9sc02503k	journal	January 2019
Heterostructured Sn/SnO _2−x nanotube peapods with a strong plasmonic effect for photoelectrochemical water oxidation Li, Yueying; Wang, Jian-Gan; Hua, Wei Journal of Materials Chemistry A, Vol. 7, Issue 28 https://doi.org/10.1039/c9ta03848e	journal	January 2019
Sulfur-terminated tin oxides for durable, highly reversible storage of large-capacity lithium Dong, Chenlong; Dong, Wujie; Zhang, Qinghua Journal of Materials Chemistry A, Vol. 8, Issue 2 https://doi.org/10.1039/c9ta11330d	journal	January 2020
In situ synthesized SnO ₂ nanorod/reduced graphene oxide low-dimensional structure for enhanced lithium storage Zhang, Wei; Xiao, Xuezhang; Zhang, Yiwen Nanotechnology, Vol. 29, Issue 10 https://doi.org/10.1088/1361-6528/aaa72c	journal	January 2018
Facile Synthesis of Wormhole-Like Mesoporous Tin Oxide via Evaporation-Induced Self-Assembly and the Enhanced Gas-Sensing Properties Li, Xiaoyu; Peng, Kang; Dou, Yewei Nanoscale Research Letters, Vol. 13, Issue 1 https://doi.org/10.1186/s11671-018-2434-4	journal	January 2018
Incorporating N Atoms into SnO2 Nanostructure as an Approach to Enhance Gas Sensing Property for Acetone Guan, Xiangfeng; Wang, Yongjing; Luo, Peihui Nanomaterials, Vol. 9, Issue 3 https://doi.org/10.3390/nano9030445	journal	March 2019

Similar Records

Sn-MOF derived bimodal-distributed SnO2 nanosphere as a high performance anode of sodium ion batteries with high gravimetric and volumetric capacities

Journal Article · Thu Mar 15 00:00:00 EDT 2018 · Materials Research Bulletin · OSTI ID:22805423

Electrochemical and microstructural characterization of magnetron-sputtered ATO thin films as Li–ion storage materials

Journal Article · Wed Jan 14 23:00:00 EST 2015 · Materials Research Bulletin · OSTI ID:22420735

Related Subjects

25 ENERGY STORAGE
conductive tin oxide
lithium-ion batteries (LIBs)
molten-aluminum reduction method
reversible redox reaction

A Robust and Conductive Black Tin Oxide Nanostructure Makes Efficient Lithium-Ion Batteries Possible

Citation Formats

References (39)

Cited By (34)

Similar Records

Related Subjects