Temperature and Thickness Dependences of the Anisotropic In-Plane Thermal Conductivity of Black Phosphorus

Smith, Brandon; Vermeersch, Bjorn; Carrete, Jesús; Ou, Eric; Kim, Jaehyun; Mingo, Natalio; Akinwande, Deji; Shi, Li

doi:10.1002/adma.201603756

Temperature and Thickness Dependences of the Anisotropic In-Plane Thermal Conductivity of Black Phosphorus

Journal Article · Thu Nov 24 04:00:00 EST 2016 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201603756· OSTI ID:1533031

Smith, Brandon ^[1]; Vermeersch, Bjorn ^[2]; Carrete, Jesús ^[2]; Ou, Eric ^[3]; Kim, Jaehyun ^[3]; Mingo, Natalio ^[2]; Akinwande, Deji ^[4]; Shi, Li ^[3]

Univ. of Texas, Austin, TX (United States). Dept. of Mechanical Engineering; DOE/OSTI
French Atomic and Alternative Energy Commission, Grenoble (France)
Univ. of Texas, Austin, TX (United States). Dept. of Mechanical Engineering
Univ. of Texas, Austin, TX (United States). Dept. of Electrical and Computing Engineering

The anisotropic basal-plane thermal conductivities of thin black phosphorus obtained from a new four-probe measurement exhibit much higher peak values at low temperatures than previous reports. First principles calculations reveal the important role of crystal defects and weak thickness dependence that is opposite to the case of graphene and graphite due to the absence of reflection symmetry in puckered phosphorene.

View Accepted Manuscript (DOE)

Research Organization:: Univ. of Texas, Austin, TX (United States); French Atomic and Alternative Energy Commission, Grenoble (France)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); Ofﬁce of Naval Research (ONR) (United States); National Science Foundation (NSF) (United States); Air Force Ofﬁce of Scientiﬁc Research (AFOSR) (United States); European Union (EU)

Grant/Contract Number:: FG02-07ER46377

OSTI ID:: 1533031

Journal Information:: Advanced Materials, Journal Name: Advanced Materials Journal Issue: 5 Vol. 29; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Temperature and Thickness Dependences of the Anisotropic In-Plane Thermal Conductivity of Black Phosphorus

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