Thermochromic halide perovskite solar cells

Lin, Jia; Lai, Minliang; Dou, Letian; Kley, Christopher S.; Chen, Hong; Peng, Fei; Sun, Junliang; Lu, Dylan; Hawks, Steven A.; Xie, Chenlu; Cui, Fan; Alivisatos, A. Paul; Limmer, David T.; Yang, Peidong

doi:10.1038/s41563-017-0006-0

Thermochromic halide perovskite solar cells

Journal Article · Mon Jan 22 00:00:00 EST 2018 · Nature Materials

DOI:https://doi.org/10.1038/s41563-017-0006-0· OSTI ID:1532301

Lin, Jia ^[1]; Lai, Minliang ^[2]; Dou, Letian ^[3]; Kley, Christopher S. ^[2]; Chen, Hong ^[2]; Peng, Fei ^[4]; Sun, Junliang ^[4]; Lu, Dylan ^[5]; Hawks, Steven A. ^[6]; Xie, Chenlu ^[2]; Cui, Fan ^[2]; Alivisatos, A. Paul ^[7]; Limmer, David T. ^[7]; Yang, Peidong ^[7]

Univ. of California, Berkeley, CA (United States); Shanghai Univ. of Electric Power (China); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Purdue Univ., West Lafayette, IN (United States)
Stockholm Univ. (Sweden)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Lawrence Livermore National Lab. (LLNL), Livermore, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Kavli Energy NanoScience Inst., Berkeley, CA (United States)

Smart photovoltaic windows represent a promising green technology featuring tunable transparency and electrical power generation under external stimuli to control the light transmission and manage the solar energy. Here, we demonstrate a thermochromic solar cell for smart photovoltaic window applications utilizing the structural phase transitions in inorganic halide perovskite caesium lead iodide/bromide. The solar cells undergo thermally-driven, moisture-mediated reversible transitions between a transparent non-perovskite phase (81.7% visible transparency) with low power output and a deeply coloured perovskite phase (35.4% visible transparency) with high power output. The inorganic perovskites exhibit tunable colours and transparencies, a peak device efficiency above 7%, and a phase transition temperature as low as 105 °C. We demonstrate excellent device stability over repeated phase transition cycles without colour fade or performance degradation. The photovoltaic windows showing both photoactivity and thermochromic features represent key stepping-stones for integration with buildings, automobiles, information displays, and potentially many other technologies.

View Accepted Manuscript (DOE)

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Livermore National Laboratory (LLNL), Livermore, CA (United States)

Sponsoring Organization:: USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231; AC52-07NA27344

OSTI ID:: 1532301

Alternate ID(s):: OSTI ID: 1835041

Report Number(s):: LLNL-JRNL--713247; ark:/13030/qt06v5r17g

Journal Information:: Nature Materials, Journal Name: Nature Materials Journal Issue: 3 Vol. 17; ISSN 1476-1122

Publisher:: Springer Nature - Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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