Chemical Control of Plasmons in Metal Chalcogenide and Metal Oxide Nanostructures

Mattox, Tracy M.; Ye, Xingchen; Manthiram, Karthish; Schuck, P. James; Alivisatos, A. Paul; Urban, Jeffrey J.

doi:10.1002/adma.201502218

Title: Chemical Control of Plasmons in Metal Chalcogenide and Metal Oxide Nanostructures

Journal Article · Tue Jul 14 00:00:00 EDT 2015 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201502218· OSTI ID:1532165

Mattox, Tracy M. ^[1]; Ye, Xingchen ^[2]; Manthiram, Karthish ^[3]; Schuck, P. James ^[1]; Alivisatos, A. Paul ^[2]; Urban, Jeffrey J. ^[1]

Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Univ. of California, Berkeley, CA (United States)

The field of plasmonics has grown to impact a diverse set of scientific disciplines ranging from quantum optics and photovoltaics to metamaterials and medicine. Plasmonics research has traditionally focused on noble metals; however, any material with a sufficiently high carrier density can support surface plasmon modes. Recently, researchers have made great gains in the synthetic (both intrinsic and extrinsic) control over the morphology and doping of nanoscale oxides, pnictides, sulfides, and selenides. These synthetic advances have, collectively, blossomed into a new, emerging class of plasmonic metal chalcogenides that complement traditional metallic materials. Chalcogenide and oxide nanostructures expand plasmonic properties into new spectral domains and also provide a rich suite of chemical controls available to manipulate plasmons, such as particle doping, shape, and composition. As a result, new opportunities in plasmonic chalcogenide nanomaterials are highlighted in this article, showing how they may be used to fundamentally tune the interaction and localization of electromagnetic fields on semiconductor surfaces in a way that enables new horizons in basic research and energy-relevant applications.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)

Sponsoring Organization:: USDOE Office of Science (SC)

Grant/Contract Number:: AC02-05CH11231

OSTI ID:: 1532165

Journal Information:: Advanced Materials, Vol. 27, Issue 38; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 88 works

Citation information provided by
Web of Science

References (52)

Shedding Light on Vacancy-Doped Copper Chalcogenides: Shape-Controlled Synthesis, Optical Properties, and Modeling of Copper Telluride Nanocrystals with Near-Infrared Plasmon Resonances Kriegel, Ilka; Rodríguez-Fernández, Jessica; Wisnet, Andreas ACS Nano, Vol. 7, Issue 5, p. 4367-4377 https://doi.org/10.1021/nn400894d	journal	April 2013
Dynamically Modulating the Surface Plasmon Resonance of Doped Semiconductor Nanocrystals Garcia, Guillermo; Buonsanti, Raffaella; Runnerstrom, Evan L. Nano Letters, Vol. 11, Issue 10, p. 4415-4420 https://doi.org/10.1021/nl202597n	journal	October 2011
The Optical Properties of Metal Nanoparticles: The Influence of Size, Shape, and Dielectric Environment Kelly, K. Lance; Coronado, Eduardo; Zhao, Lin Lin The Journal of Physical Chemistry B, Vol. 107, Issue 3 https://doi.org/10.1021/jp026731y	journal	January 2003
Tunable near-infrared and visible-light transmittance in nanocrystal-in-glass composites Llordés, Anna; Garcia, Guillermo; Gazquez, Jaume Nature, Vol. 500, Issue 7462 https://doi.org/10.1038/nature12398	journal	August 2013
Expanding the Spectral Tunability of Plasmonic Resonances in Doped Metal-Oxide Nanocrystals through Cooperative Cation–Anion Codoping Ye, Xingchen; Fei, Jiayang; Diroll, Benjamin T. Journal of the American Chemical Society, Vol. 136, Issue 33 https://doi.org/10.1021/ja5039903	journal	August 2014
Generalized One-Pot Synthesis of Copper Sulfide, Selenide-Sulfide, and Telluride-Sulfide Nanoparticles Saldanha, Pearl L.; Brescia, Rosaria; Prato, Mirko Chemistry of Materials, Vol. 26, Issue 3 https://doi.org/10.1021/cm4035598	journal	January 2014
Nanoplasmonics: The physics behind the applications Stockman, Mark I. Physics Today, Vol. 64, Issue 2 https://doi.org/10.1063/1.3554315	journal	February 2011
New materials for tunable plasmonic colloidal nanocrystals Comin, Alberto; Manna, Liberato Chem. Soc. Rev., Vol. 43, Issue 11 https://doi.org/10.1039/C3CS60265F	journal	January 2014
Metal Ions To Control the Morphology of Semiconductor Nanoparticles: Copper Selenide Nanocubes Li, Wenhua; Zamani, Reza; Ibáñez, Maria Journal of the American Chemical Society, Vol. 135, Issue 12 https://doi.org/10.1021/ja400472m	journal	March 2013
Gold nanorod-based localized surface plasmon resonance biosensors: A review Cao, Jie; Sun, Tong; Grattan, Kenneth T. V. Sensors and Actuators B: Chemical, Vol. 195 https://doi.org/10.1016/j.snb.2014.01.056	journal	May 2014
Copper Sulfide Nanocrystals with Tunable Composition by Reduction of Covellite Nanocrystals with Cu ⁺ Ions Xie, Yi; Riedinger, Andreas; Prato, Mirko Journal of the American Chemical Society, Vol. 135, Issue 46 https://doi.org/10.1021/ja409754v	journal	November 2013
Localized surface plasmon resonances arising from free carriers in doped quantum dots Luther, Joseph M.; Jain, Prashant K.; Ewers, Trevor Nature Materials, Vol. 10, Issue 5, p. 361-366 https://doi.org/10.1038/nmat3004	journal	April 2011
Shape-Dependent Field Enhancement and Plasmon Resonance of Oxide Nanocrystals Agrawal, Ankit; Kriegel, Ilka; Milliron, Delia J. The Journal of Physical Chemistry C, Vol. 119, Issue 11 https://doi.org/10.1021/acs.jpcc.5b01648	journal	March 2015
Redox Chemistries and Plasmon Energies of Photodoped In ₂ O ₃ and Sn-Doped In ₂ O ₃ (ITO) Nanocrystals Schimpf, Alina M.; Lounis, Sebastien D.; Runnerstrom, Evan L. Journal of the American Chemical Society, Vol. 137, Issue 1 https://doi.org/10.1021/ja5116953	journal	January 2015
Composition-Dependent Crystal Phase, Optical Properties, and Self-Assembly of Cu–Sn–S Colloidal Nanocrystals Liu, Xin; Wang, Xianliang; Swihart, Mark T. Chemistry of Materials, Vol. 27, Issue 4 https://doi.org/10.1021/cm504411a	journal	February 2015
Solid–Solid Phase Transformations Induced through Cation Exchange and Strain in 2D Heterostructured Copper Sulfide Nanocrystals Ha, Don-Hyung; Caldwell, Andrew H.; Ward, Matthew J. Nano Letters, Vol. 14, Issue 12 https://doi.org/10.1021/nl5035607	journal	November 2014
Quantum plasmonics Tame, M. S.; McEnery, K. R.; Özdemir, Ş. K. Nature Physics, Vol. 9, Issue 6 https://doi.org/10.1038/nphys2615	journal	June 2013
Metallic-like Stoichiometric Copper Sulfide Nanocrystals: Phase- and Shape-Selective Synthesis, Near-Infrared Surface Plasmon Resonance Properties, and Their Modeling Xie, Yi; Carbone, Luigi; Nobile, Concetta ACS Nano, Vol. 7, Issue 8 https://doi.org/10.1021/nn403035s	journal	July 2013
Electrochemical Tuning of the Dielectric Function of Au Nanoparticles Brown, Ana M.; Sheldon, Matthew T.; Atwater, Harry A. ACS Photonics, Vol. 2, Issue 4 https://doi.org/10.1021/ph500358q	journal	March 2015
Shape-Dependent Plasmonic Response and Directed Self-Assembly in a New Semiconductor Building Block, Indium-Doped Cadmium Oxide (ICO) Gordon, Thomas R.; Paik, Taejong; Klein, Dahlia R. Nano Letters, Vol. 13, Issue 6, p. 2857-2863 https://doi.org/10.1021/nl4012003	journal	May 2013
Composite for smarter windows Korgel, Brian A. Nature, Vol. 500, Issue 7462 https://doi.org/10.1038/500278a	journal	August 2013
Size-, Shape-, and Composition-Controlled Synthesis and Localized Surface Plasmon Resonance of Copper Tin Selenide Nanocrystals Wang, Xianliang; Liu, Xin; Yin, Deqiang Chemistry of Materials, Vol. 27, Issue 9 https://doi.org/10.1021/acs.chemmater.5b00618	journal	April 2015
Defect Chemistry and Plasmon Physics of Colloidal Metal Oxide Nanocrystals Lounis, Sebastien D.; Runnerstrom, Evan L.; Llordés, Anna The Journal of Physical Chemistry Letters, Vol. 5, Issue 9 https://doi.org/10.1021/jz500440e	journal	April 2014
Surface-Dependent Localized Surface Plasmon Resonances in CuS Nanodisks Wei, Tiaoxing; Liu, Yufeng; Dong, Wenjing ACS Applied Materials & Interfaces, Vol. 5, Issue 21 https://doi.org/10.1021/am4039568	journal	October 2013
Influence of Shape on the Surface Plasmon Resonance of Tungsten Bronze Nanocrystals Mattox, Tracy M.; Bergerud, Amy; Agrawal, Ankit Chemistry of Materials, Vol. 26, Issue 5 https://doi.org/10.1021/cm4030638	journal	February 2014
Tuning the Excitonic and Plasmonic Properties of Copper Chalcogenide Nanocrystals Kriegel, Ilka; Jiang, Chengyang; Rodríguez-Fernández, Jessica Journal of the American Chemical Society, Vol. 134, Issue 3, p. 1583-1590 https://doi.org/10.1021/ja207798q	journal	January 2012
Plasmonics for improved photovoltaic devices Atwater, Harry A.; Polman, Albert Nature Materials, Vol. 9, Issue 3, p. 205-213 https://doi.org/10.1038/nmat2629	journal	February 2010
Graphene-Nanoparticle Composites and Their Applications in Energy, Environmental and Biomedical Science Mondal, Avijit; Jana, Nikhil R. Reviews in Nanoscience and Nanotechnology, Vol. 3, Issue 3 https://doi.org/10.1166/rnn.2014.1051	journal	September 2014
Controlling the Topography and Surface Plasmon Resonance of Gold Nanoshells by a Templated Surfactant-Assisted Seed Growth Method Sanchez-Gaytan, Brenda L.; Qian, Zhaoxia; Hastings, Simon P. The Journal of Physical Chemistry C, Vol. 117, Issue 17 https://doi.org/10.1021/jp401189k	journal	April 2013
Molecular plasmonics for biology and nanomedicine Zheng, Yue Bing; Kiraly, Brian; Weiss, Paul S. Nanomedicine, Vol. 7, Issue 5 https://doi.org/10.2217/nnm.12.30	journal	May 2012
Heavily-doped colloidal semiconductor and metal oxide nanocrystals: an emerging new class of plasmonic nanomaterials Liu, Xin; Swihart, Mark T. Chem. Soc. Rev., Vol. 43, Issue 11 https://doi.org/10.1039/C3CS60417A	journal	January 2014
Plasmonic Cu _{2− x} S Nanocrystals: Optical and Structural Properties of Copper-Deficient Copper(I) Sulfides Zhao, Yixin; Pan, Hongcheng; Lou, Yongbing Journal of the American Chemical Society, Vol. 131, Issue 12 https://doi.org/10.1021/ja805655b	journal	April 2009
Reversible Tunability of the Near-Infrared Valence Band Plasmon Resonance in Cu _{2– x} Se Nanocrystals Dorfs, Dirk; Härtling, Thomas; Miszta, Karol Journal of the American Chemical Society, Vol. 133, Issue 29 https://doi.org/10.1021/ja2016284	journal	July 2011
Doped Nanocrystals as Plasmonic Probes of Redox Chemistry Jain, Prashant K.; Manthiram, Karthish; Engel, Jesse H. Angewandte Chemie International Edition, Vol. 52, Issue 51 https://doi.org/10.1002/anie.201303707	journal	October 2013
Semiconducting and Plasmonic Copper Phosphide Platelets Manna, Goutam; Bose, Riya; Pradhan, Narayan Angewandte Chemie International Edition, Vol. 52, Issue 26 https://doi.org/10.1002/anie.201210277	journal	June 2013
Tunable and Directional Plasmonic Coupling within Semiconductor Nanodisk Assemblies Hsu, Su-Wen; Ngo, Charles; Tao, Andrea R. Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl404777h	journal	April 2014
A Localized Surface Plasmon Resonance-Based Multicolor Electrochromic Device with Electrochemically Size-Controlled Silver Nanoparticles Tsuboi, Ayako; Nakamura, Kazuki; Kobayashi, Norihisa Advanced Materials, Vol. 25, Issue 23 https://doi.org/10.1002/adma.201205214	journal	April 2013
Plasmon Resonances of Semiconductor Nanocrystals: Physical Principles and New Opportunities Faucheaux, Jacob A.; Stanton, Alexandria L. D.; Jain, Prashant K. The Journal of Physical Chemistry Letters, Vol. 5, Issue 6 https://doi.org/10.1021/jz500037k	journal	March 2014
CuTe Nanocrystals: Shape and Size Control, Plasmonic Properties, and Use as SERS Probes and Photothermal Agents Li, Wenhua; Zamani, Reza; Rivera Gil, Pilar Journal of the American Chemical Society, Vol. 135, Issue 19 https://doi.org/10.1021/ja401428e	journal	May 2013
Alloyed Copper Chalcogenide Nanoplatelets via Partial Cation Exchange Reactions Lesnyak, Vladimir; George, Chandramohan; Genovese, Alessandro ACS Nano, Vol. 8, Issue 8 https://doi.org/10.1021/nn502906z	journal	July 2014
Tuning the Localized Surface Plasmon Resonance in Cu _{2– x} Se Nanocrystals by Postsynthetic Ligand Exchange Balitskii, Olexiy A.; Sytnyk, Mykhailo; Stangl, Julian ACS Applied Materials & Interfaces, Vol. 6, Issue 20 https://doi.org/10.1021/am504296y	journal	October 2014
Controlling Carrier Densities in Photochemically Reduced Colloidal ZnO Nanocrystals: Size Dependence and Role of the Hole Quencher Schimpf, Alina M.; Gunthardt, Carolyn E.; Rinehart, Jeffrey D. Journal of the American Chemical Society, Vol. 135, Issue 44 https://doi.org/10.1021/ja408030u	journal	October 2013
Highly Sensitive Plasmonic Silver Nanorods Jakab, Arpad; Rosman, Christina; Khalavka, Yuriy ACS Nano, Vol. 5, Issue 9 https://doi.org/10.1021/nn200877b	journal	August 2011
Room-Temperature Synthesis of Covellite Nanoplatelets with Broadly Tunable Localized Surface Plasmon Resonance Liu, Maixian; Xue, Xiaozheng; Ghosh, Chayanjit Chemistry of Materials, Vol. 27, Issue 7 https://doi.org/10.1021/acs.chemmater.5b00270	journal	March 2015
Plasmonics in heavily-doped semiconductor nanocrystals Scotognella, Francesco; Della Valle, Giuseppe; Srimath Kandada, Ajay Ram The European Physical Journal B, Vol. 86, Issue 4 https://doi.org/10.1140/epjb/e2013-40039-x	journal	April 2013
Surface Plasmons on Metal Nanoparticles: The Influence of Shape and Physical Environment Noguez, Cecilia The Journal of Physical Chemistry C, Vol. 111, Issue 10 https://doi.org/10.1021/jp066539m	journal	March 2007
Effects of Carrier Density and Shape on the Localized Surface Plasmon Resonances of Cu _{2– x} S Nanodisks Hsu, Su-Wen; Bryks, Whitney; Tao, Andrea R. Chemistry of Materials, Vol. 24, Issue 19 https://doi.org/10.1021/cm302363x	journal	September 2012
Cu _{2– x} S _{1– y} Se _y Alloy Nanocrystals with Broadly Tunable Near-Infrared Localized Surface Plasmon Resonance Liu, Xin; Wang, Xianliang; Swihart, Mark T. Chemistry of Materials, Vol. 25, Issue 21 https://doi.org/10.1021/cm402848k	journal	October 2013
Octapod-Shaped Colloidal Nanocrystals of Cadmium Chalcogenides via “One-Pot” Cation Exchange and Seeded Growth Deka, Sasanka; Miszta, Karol; Dorfs, Dirk Nano Letters, Vol. 10, Issue 9 https://doi.org/10.1021/nl102539a	journal	September 2010
Nanostructured electrochromic smart windows: traditional materials and NIR-selective plasmonic nanocrystals Runnerstrom, Evan L.; Llordés, Anna; Lounis, Sebastien D. Chem. Commun., Vol. 50, Issue 73 https://doi.org/10.1039/C4CC03109A	journal	January 2014
The Promise of Plasmonics Atwater, Harry A. Scientific American, Vol. 296, Issue 4 https://doi.org/10.1038/scientificamerican0407-56	journal	April 2007
Tunable Localized Surface Plasmon Resonances in Tungsten Oxide Nanocrystals Manthiram, Karthish; Alivisatos, A. Paul Journal of the American Chemical Society, Vol. 134, Issue 9 https://doi.org/10.1021/ja211363w	journal	February 2012

Cited By (18)

A Visible‐ and NIR‐Light Responsive Photothermal Therapy Agent by Chirality‐Dependent MoO ₃₋ _x Nanoparticles Li, Yiwen; Miao, Ziwei; Shang, Zhengwen Advanced Functional Materials, Vol. 30, Issue 4 https://doi.org/10.1002/adfm.201906311	journal	November 2019
Pulsed Lasers Employing Solution-Processed Plasmonic Cu ₃₋ _x P Colloidal Nanocrystals Liu, Zeke; Mu, Haoran; Xiao, Si Advanced Materials, Vol. 28, Issue 18 https://doi.org/10.1002/adma.201504927	journal	March 2016
Tunable Charge Transport in Hybrid Superlattices of Indium Tin Oxide Nanocrystals and Metal Phthalocyanines-Toward Sensing Applications Samadi Khoshkhoo, Mahdi; Joseph, Yvonne; Maiti, Santanu Advanced Materials Interfaces, Vol. 5, Issue 9 https://doi.org/10.1002/admi.201701623	journal	February 2018
Luminescence, Plasmonic, and Magnetic Properties of Doped Semiconductor Nanocrystals Pradhan, Narayan; Das Adhikari, Samrat; Nag, Angshuman Angewandte Chemie International Edition, Vol. 56, Issue 25 https://doi.org/10.1002/anie.201611526	journal	May 2017
Welch Award in Chemistry:A. P. Alivisatos and C. M. Lieber / Wilhelm Exner Medal:J. M. DeSimone / Ernst Schering Prize:P. Cramer Kueckman, Theresa; Maass, Frank Angewandte Chemie International Edition, Vol. 58, Issue 50, p. 17907-17907 https://doi.org/10.1002/anie.201912789	journal	October 2019
Amorphous Materials for Enhanced Localized Surface Plasmon Resonances Zhu, Chuanhui; Xu, Qun Chemistry - An Asian Journal, Vol. 13, Issue 7 https://doi.org/10.1002/asia.201701722	journal	February 2018
Nanomaterials and their Classification Buzea, Cristina; Pacheco, Ivan Advanced Structured Materials https://doi.org/10.1007/978-81-322-3655-9_1	book	November 2016
Facile fabrication of In:Ge/Cu nano-octahedra film for improving photoelectrochemical properties Yu, Yuan-chun; Liang, Yuling; Liu, Fuqiao Journal of Materials Science: Materials in Electronics, Vol. 29, Issue 18 https://doi.org/10.1007/s10854-018-8881-y	journal	March 2018
Plasmon-enhanced ZnO nanorod/Au NPs/Cu2O structure solar cells: Effects and limitations Yoo, Il-Han; Kalanur, Shankara Sharanappa; Eom, Kiryung Korean Journal of Chemical Engineering, Vol. 34, Issue 12 https://doi.org/10.1007/s11814-017-0222-y	journal	September 2017
Tuning infrared plasmon resonances in doped metal-oxide nanocrystals through cation-exchange reactions Liu, Zeke; Zhong, Yaxu; Shafei, Ibrahim Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-09165-2	journal	March 2019
Impacts of surface depletion on the plasmonic properties of doped semiconductor nanocrystals Zandi, Omid; Agrawal, Ankit; Shearer, Alex B. Nature Materials, Vol. 17, Issue 8 https://doi.org/10.1038/s41563-018-0130-5	journal	July 2018
Synthesis of CuFeS _2−x Se _x – alloyed nanocrystals with localized surface plasmon resonance in the visible spectral range Kowalik, Patrycja; Bujak, Piotr; Penkala, Mateusz Journal of Materials Chemistry C, Vol. 7, Issue 21 https://doi.org/10.1039/c9tc01242g	journal	January 2019
Observation of surface plasmon polaritons in 2D electron gas of surface electron accumulation in InN nanostructures Madapu, Kishore K.; Sivadasan, A. K.; Baral, Madhusmita Nanotechnology, Vol. 29, Issue 27 https://doi.org/10.1088/1361-6528/aabe60	journal	May 2018
Bulk scale fabrication of sodium tungsten bronze nanoparticles for applications in plasmonics Tegg, Levi; Cuskelly, Dylan; Keast, Vicki J. Nanotechnology, Vol. 29, Issue 40 https://doi.org/10.1088/1361-6528/aad34b	journal	July 2018
Tuning the Surface Plasmon Resonance of Lanthanum Hexaboride to Absorb Solar Heat: A Review Mattox, Tracy; Urban, Jeffrey Materials, Vol. 11, Issue 12 https://doi.org/10.3390/ma11122473	journal	December 2018
Observation of surface plasmon polaritons in 2D electron gas of surface electron accumulation in InN nanostructures Madapu, Kishore Kumar; Sivadasan, Alppettiyil Krishnankutty; Baral, Madhusmita arXiv https://doi.org/10.48550/arxiv.1705.07423	text	January 2017
Photothermal Conversion of W₁₈ O₄₉ with a Tunable Oxidation State Fang, Zhenxing; Jiao, Shihui; Kang, Yutang ChemistryOpen, Vol. 6, Issue 2 https://doi.org/10.1002/open.201600149	journal	January 2017
Observation of Majorana Plasmon by Molecular Topological Superconductor and Its Topological SPASER Choi, Kyoung Hwan; Suh, Dong Hack arXiv https://doi.org/10.48550/arxiv.2101.06882	preprint	January 2021

Similar Records

Quantum Mechanical Studies of Large Metal, Metal Oxide, and Metal Chalcogenide Nanoparticles and Clusters

Journal Article · Tue Apr 21 00:00:00 EDT 2015 · Chemical Reviews · OSTI ID:1532165

Fernando, Amendra; Weerawardene, K. L. Dimuthu M.; Karimova, Natalia V.; +1 more

Alkaline-Earth Chalcogenide Nanocrystals: Solution-Phase Synthesis, Surface Chemistry, and Stability

Journal Article · Mon Jul 18 00:00:00 EDT 2022 · ACS Nano · OSTI ID:1532165

Roth, Alison N.; Chen, Yunhua; Adamson, Marquix A. S.; +4 more

Dynamically tunable second-harmonic generation using hybrid nanostructures incorporating phase-change chalcogenides

Journal Article · Tue Apr 26 00:00:00 EDT 2022 · Nanophotonics (Online) · OSTI ID:1532165

Zhu, Muliang; Abdollahramezani, Sajjad; Li, Chentao; +3 more

Related Subjects

36 MATERIALS SCIENCE
chalcogenides
localized surface plasmon resonance (LSPR)
nanocrystals
oxides
plasmons

Title: Chemical Control of Plasmons in Metal Chalcogenide and Metal Oxide Nanostructures

Citation Formats

References (52)

Cited By (18)

Similar Records

Related Subjects