Electrochemical device having electrolyte including disiloxane

West, Robert C.; Amine, Khalil; Zhang, Zhengcheng; Wang, Qingzheng; Rossi, Nicholas Agostino Antonio; Vissers, Donald R.

Electrochemical device having electrolyte including disiloxane

Patent · Tue Dec 13 04:00:00 EST 2011

OSTI ID:1531705

West, Robert C.; Amine, Khalil; Zhang, Zhengcheng; Wang, Qingzheng; Rossi, Nicholas Agostino Antonio; Vissers, Donald R.

One example of the disiloxanes include a backbone with a first silicon and a second silicon. The first silicon is linked to a first substituent selected from a group consisting of: a first side chain that includes a cyclic carbonate moiety; a first side chain that includes a poly(alkylene oxide) moiety; and a first cross link links the disiloxane to a second siloxane and that includes a poly(alkylene oxide) moiety. In some instance, the second silicon is linked to a second substituent selected from a group consisting of: a second side chain that includes a cyclic carbonate moiety, and a second side chain that includes a poly(alkylene oxide) moiety.

View Patent

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE

DOE Contract Number:: W-31109-ENG-38

Assignee:: West, Robert C., Madison, WI (United States)

Patent Number(s):: 8,076,031

Application Number:: 11/056,866

OSTI ID:: 1531705

Country of Publication:: United States

Language:: English

References (40)

Alcoholysis of poly(methylhydrogensiloxane) Kohama, Shigemi; Umeki, Yoshihisa Journal of Applied Polymer Science, Vol. 21, Issue 3 https://doi.org/10.1002/app.1977.070210329	journal	March 1977
Conductivity of solid complexes of lithium perchlorate with poly{[ω‐methoxyhexa(oxyethylene)ethoxy]methylsiloxane} Fish, Daryle; Khan, Ishrat M.; Smid, Johannes Die Makromolekulare Chemie, Rapid Communications, Vol. 7, Issue 3, p. 115-120 https://doi.org/10.1002/marc.1986.030070303	journal	March 1986
Polymer electrolyte complexes of LiCIO4 and comb polymers of siloxane with oligo-oxyethylene side chains Fish, Daryle; Khan, Ishrat M.; Wu, E. British Polymer Journal, Vol. 20, Issue 3 https://doi.org/10.1002/pi.4980200320	journal	January 1988
A water-soluble siloxane: Poly(ethylene glycol) comb polymer Bannister, D. J.; Doyle, M.; Macfarlane, D. R. Journal of Polymer Science: Polymer Letters Edition, Vol. 23, Issue 9 https://doi.org/10.1002/pol.1985.130230903	journal	September 1985
Modification of polymethylhydrosiloxane by dehydrocoupling reactions catalyzed by transition metal complexes: Evidence for the preservation of linear siloxane structures Zhang, Ruzhi; Zhang, Zhengcheng; Amine, Khalil Silicon Chemistry, Vol. 2, Issue 5-6 https://doi.org/10.1007/s11201-005-4059-6	journal	May 2005
Conduction of lithium ions in polyvinylidene fluoride and its derivatives—I Tsuchida, Eishun; Ohno, Hiroyuki; Tsunemi, Koichi Electrochimica Acta, Vol. 28, Issue 5 https://doi.org/10.1016/0013-4686(83)85049-X	journal	May 1983
Thermally stable lithium salts for polymer electrolytes Dominey, Larry A.; Koch, Victor R.; Blakley, Tom J. Electrochimica Acta, Vol. 37, Issue 9 https://doi.org/10.1016/0013-4686(92)80109-Y	journal	January 1992
Complexes of alkali metal ions with poly(ethylene oxide) Fenton, D. E.; Parker, J. M.; Wright, P. V. Polymer, Vol. 14, Issue 11 https://doi.org/10.1016/0032-3861(73)90146-8	journal	November 1973
Triblock copolymers and networks incorporating oligo (oxyethylene) chains Alloin, F.; Sanchez, J.; Armand, M. Solid State Ionics, Vol. 60, Issue 1-3 https://doi.org/10.1016/0167-2738(93)90267-7	journal	March 1993
Poly(ethylene oxide) electrolytes for operation at near room temperature Kelly, I. E.; Owen, J. R.; Steele, B. C. H. Journal of Power Sources, Vol. 14, Issue 1-3 https://doi.org/10.1016/0378-7753(85)88004-6	journal	January 1985
Large lithium polymer battery development The immobile solvent concept Gauthier, M.; Bélanger, A.; Bouchard, P. Journal of Power Sources, Vol. 54, Issue 1 https://doi.org/10.1016/0378-7753(94)02060-G	journal	March 1995
Novel interpenetrating polymer network electrolytes Hou, Xinping; Siow, Kok Siong Polymer, Vol. 42, Issue 9 https://doi.org/10.1016/S0032-3861(00)00818-1	journal	April 2001
Studies on comb-like polymer blend with poly(ethylene oxide)—lithium perchlorate salt complex electrolyte Gnanaraj, J. S.; Karekar, R. N.; Skaria, Sunny Polymer, Vol. 38, Issue 14 https://doi.org/10.1016/S0032-3861(97)00069-4	journal	January 1997
Gel electrolytes on the basis of oligo(ethylene glycol)n dimethacrylates—thermal, mechanical and electrochemical properties in relationship to the network structure Reiche, A.; Sandner, R.; Weinkauf, A. Polymer, Vol. 41, Issue 10 https://doi.org/10.1016/S0032-3861(99)00555-8	journal	May 2000
Time resolved luminescence and vibrational spectroscopic studies on complexes of poly(ethylene oxide) oligomers and EuTFSI3 salt Furlani, M. Solid State Ionics, Vol. 113-115, Issue 1-2 https://doi.org/10.1016/S0167-2738(98)00283-5	journal	December 1998
Thermal stability of propylene carbonate and ethylene carbonate–propylene carbonate-based electrolytes for use in Li cells Katayama, Noriko; Kawamura, Tetsuya; Baba, Yasunori Journal of Power Sources, Vol. 109, Issue 2 https://doi.org/10.1016/S0378-7753(02)00075-7	journal	July 2002
Solid polymer electrolytes based on cross-linked polysiloxane-g-oligo(ethylene oxide): ionic conductivity and electrochemical properties Kang, Yongku; Lee, Wonsil; Hack Suh, Dong Journal of Power Sources, Vol. 119-121 https://doi.org/10.1016/S0378-7753(03)00189-7	journal	June 2003
Synthesis and Ionic Conductivity of Cyclosiloxanes with Ethyleneoxy-Containing Substituents Zhang, Zhengcheng; Lyons, Leslie J.; Jin, Jay J. Chemistry of Materials, Vol. 17, Issue 23 https://doi.org/10.1021/cm050742x	journal	November 2005
Highly Conductive PEO-like Polymer Electrolytes Abraham, K. M.; Jiang, Z.; Carroll, B. Chemistry of Materials, Vol. 9, Issue 9 https://doi.org/10.1021/cm970075a	journal	September 1997
Synthesis, characterization, and electrical response of phosphazene polyelectrolytes Ganapathiappan, S.; Chen, Kaimin; Shriver, D. F. Journal of the American Chemical Society, Vol. 111, Issue 11 https://doi.org/10.1021/ja00193a047	journal	May 1989
Investigations of a siloxane-based polymer electrolyte employing carbon-13, silicon-29, lithium-7, and sodium-23 solid-state NMR spectroscopy Spindler, R.; Shriver, D. F. Journal of the American Chemical Society, Vol. 110, Issue 10 https://doi.org/10.1021/ja00218a006	journal	May 1988
Polyphosphazene solid electrolytes Blonsky, Peter M.; Shriver, D. F.; Austin, Paul Journal of the American Chemical Society, Vol. 106, Issue 22 https://doi.org/10.1021/ja00334a071	journal	October 1984
B(C ₆ F ₅ ) ₃ -Catalyzed Silation of Alcohols: A Mild, General Method for Synthesis of Silyl Ethers Blackwell, James M.; Foster, Katherine L.; Beck, Victoria H. The Journal of Organic Chemistry, Vol. 64, Issue 13 https://doi.org/10.1021/jo9903003	journal	June 1999
Solvent-free cation-conducting polysiloxane electrolytes with pendant oligo(oxyethylene) and sulfonate groups Zhou, Guang Bin; Khan, Ishrat M.; Smid, Johannes Macromolecules, Vol. 26, Issue 9 https://doi.org/10.1021/ma00061a010	journal	April 1993
Chloride ion conductivity in a plasticized quaternary ammonium polymer Hardy, L. C.; Shriver, D. F. Macromolecules, Vol. 17, Issue 4 https://doi.org/10.1021/ma00134a077	journal	July 1984
Synthesis, NMR characterization, and electrical properties of siloxane-based polymer electrolytes Spindler, Ralph; Shriver, D. F. Macromolecules, Vol. 21, Issue 3 https://doi.org/10.1021/ma00181a019	journal	May 1988
Highly Conductive Siloxane Polymers Hooper, Richard; Lyons, Leslie J.; Mapes, Marie K. Macromolecules, Vol. 34, Issue 4 https://doi.org/10.1021/ma0018446	journal	February 2001
A new class of cation conductors: polyphosphazene sulfonates Ganapathiappan, S.; Chen, Kaimin; Shriver, D. F. Macromolecules, Vol. 21, Issue 7 https://doi.org/10.1021/ma00185a075	journal	July 1988
Comblike polysiloxanes with oligo(oxyethylene) side chains. Synthesis and properties Khan, Ishrat M.; Yuan, Youxin; Fish, Daryle Macromolecules, Vol. 21, Issue 9 https://doi.org/10.1021/ma00187a006	journal	September 1988
Cross-Linked Network Polymer Electrolytes Based on a Polysiloxane Backbone with Oligo(oxyethylene) Side Chains: Synthesis and Conductivity Zhang, Zhengcheng; Sherlock, David; West, Ryan Macromolecules, Vol. 36, Issue 24, p. 9176-9180 https://doi.org/10.1021/ma0349276	journal	December 2003
Network-Type Ionic Conductors Based on Oligoethyleneoxy-Functionalized Pentamethylcyclopentasiloxanes Zhang, Zhengcheng; Lyons, Leslie J.; Amine, Khalil Macromolecules, Vol. 38, Issue 13 https://doi.org/10.1021/ma050066k	journal	June 2005
Polyphosphazenes Bearing Branched and Linear Oligoethyleneoxy Side Groups as Solid Solvents for Ionic Conduction Allcock, Harry R.; O'Connor, Stephen J. M.; Olmeijer, David L. Macromolecules, Vol. 29, Issue 23 https://doi.org/10.1021/ma960592z	journal	January 1996
A Highly Conductive Solid-State Polymer Electrolyte Based on a Double-Comb Polysiloxane Polymer with Oligo(ethylene oxide) Side Chains Hooper, Richard; Lyons, Leslie J.; Moline, David A. Organometallics, Vol. 18, Issue 17 https://doi.org/10.1021/om990261l	journal	August 1999
BATTERIES: The Battery: Not Yet a Terminal Case Alper, J. Science, Vol. 296, Issue 5571 https://doi.org/10.1126/science.296.5571.1224	journal	May 2002
Weakly Coordinating Anions, and the Exceptional Conductivity of Their Nonaqueous Solutions Xu, Wu; Angell, C. Austen Electrochemical and Solid-State Letters, Vol. 4, Issue 1 https://doi.org/10.1149/1.1344281	journal	January 2001
Thermal, Electrochemical, and Spectroscopic Characterizations of Hyperbranched Polymer Electrolyte Wang, Zhaoxiang Journal of The Electrochemical Society, Vol. 146, Issue 6 https://doi.org/10.1149/1.1391915	journal	June 1999
LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation Xu, Kang; Zhang, Shengshui; Jow, T. Richard Electrochemical and Solid-State Letters, Vol. 5, Issue 1 https://doi.org/10.1149/1.1426042	journal	January 2002
New Interpenetrating Network-Type Siloxane Polymer Electrolyte Oh, Bookeun; Hyung, Yoo-Eup; Vissers, Donald R. Electrochemical and Solid-State Letters, Vol. 5, Issue 11 https://doi.org/10.1149/1.1511342	journal	January 2002
Structures of Orthoborate Anions and Physical Properties of Their Lithium Salt Nonaqueous Solutions Xu, Wu; Shusterman, Alan J.; Videa, Marcelo Journal of The Electrochemical Society, Vol. 150, Issue 1 https://doi.org/10.1149/1.1527939	journal	January 2003
Convenient and Efficient Tosylation of Oligoethylene Glycols and the Related Alcohols in Tetrahydrofuran–Water in the Presence of Sodium Hydroxide Ouchi, Mikio; Inoue, Yoshihisa; Liu, Yu Bulletin of the Chemical Society of Japan, Vol. 63, Issue 4 https://doi.org/10.1246/bcsj.63.1260	journal	April 1990

Similar Records

Electrolyte including silane for use in electrochemical devices

Patent · Tue Oct 10 00:00:00 EDT 2017 · OSTI ID:1532028

Electrolyte including silane for use in electrochemical devices

Patent · Tue Jul 01 00:00:00 EDT 2014 · OSTI ID:1532101

Electrolyte including silane for use in electrochemical devices

Patent · Mon Dec 12 23:00:00 EST 2011 · OSTI ID:1531707

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Electrochemical device having electrolyte including disiloxane

Citation Formats

References (40)

Similar Records

Related Subjects