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Title: Manganese oxide composite electrodes for lithium batteries

Patent ·
OSTI ID:1531649

An activated electrode for a non-aqueous electrochemical cell is disclosed with a precursor thereof a lithium metal oxide with the formula x{zLi2MnO3.(1−z)LiM′O2}.(1−x)LiMn2−yMyO4 for 0 < x < 1; 0 ≦ y ≦ 0.5; and 0 < z < 1, comprised of layered zLi2MnO3.(1−z)LiM′O2 and spinel LiMn2−yMyO4 components, physically mixed or blended with one another or separated from one another in a compartmentalized electrode, in which M is one or more metal ions, and in which M′ is selected from one or more first-row transition metal ions, The electrode is activated by removing lithium and lithia, from the precursor. A cell and battery are also disclosed incorporating the disclosed positive electrode.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357; W-31-109-ENG-38
Assignee:
UChicago Argonne, LLC (Chicago, IL)
Patent Number(s):
7,790,308
Application Number:
12/590,392
OSTI ID:
1531649
Resource Relation:
Patent File Date: 2009-11-05
Country of Publication:
United States
Language:
English

References (2)

Lithium metal oxide electrodes for lithium cells and batteries patent January 2004
Lithium manganese oxide compound patent October 1992

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