Skip to main content
U.S. Department of Energy
Office of Scientific and Technical Information

Method of using a germanium layer transfer to Si for photovoltaic applications and heterostructure made thereby

Patent ·
OSTI ID:1531507

Ge/Si and other nonsilicon film heterostructures are formed by hydrogen-induced exfoliation of the Ge film which is wafer bonded to a cheaper substrate, such as Si. A thin, single-crystal layer of Ge is transferred to Si substrate. The bond at the interface of the Ge/Si heterostructures is covalent to ensure good thermal contact, mechanical strength, and to enable the formation of an ohmic contact between the Si substrate and Ge layers. To accomplish this type of bond, hydrophobic wafer bonding is used, because as the invention demonstrates the hydrogen-surface-terminating species that facilitate van der Waals bonding evolves at temperatures above 600° C. into covalent bonding in hydrophobically bound Ge/Si layer transferred systems.

Research Organization:
California Inst. of Technology, Pasadena, CA (United States)
Sponsoring Organization:
USDOE
Assignee:
California Institute of Technology (Pasadena, CA)
Patent Number(s):
7,019,339
Application Number:
10/125,133
OSTI ID:
1531507
Country of Publication:
United States
Language:
English

References (31)

Wafer bonding of different III–V compound semiconductors by atomic hydrogen surface cleaning journal October 2001
Germanium-on-insulator substrates by wafer bonding journal August 2004
Hydrophobic silicon wafer bonding journal January 1994
Strained Si on insulator technology: from materials to devices journal August 2004
Smart-Cut: A New Silicon On Insulator Material Technology Based on Hydrogen Implantation and Wafer Bonding *1 journal March 1997
Integration of Si and SiGe with Al2O3 (sapphire) journal November 2001
Electron mobility enhancement in strained-Si n-MOSFETs fabricated on SiGe-on-insulator (SGOI) substrates journal July 2001
Wafer-scale integration of GaAs optoelectronic devices with standard Si integrated circuits using a low-temperature bonding procedure journal December 2002
Electrical and Structural Characterization of the Interface of Wafer Bonded InP/Si journal January 2003
Controlled surface nanopatterning with buried dislocation arrays journal November 2003
Silicon on insulator material technology journal January 1995
Heterogeneous silicon integration by ultra-high vacuum wafer bonding journal August 2003
Multi-junction solar cells and novel structures for solar cell applications journal April 2002
Ge layer transfer to Si for photovoltaic applications journal February 2002
Strained Si, SiGe, and Ge on-insulator: review of wafer bonding fabrication techniques journal August 2004
Solid‐state reaction‐mediated low‐temperature bonding of GaAs and InP wafers to Si substrates journal February 1994
Electron and hole mobility enhancement in strained SOI by wafer bonding journal September 2002
III-V compounds for solar cell applications journal June 1999
Wafer bonding of silicon wafers covered with various surface layers journal October 2000
Publisher's Note: Donor level of bond-center hydrogen in germanium [Phys. Rev. B 69 , 245207 (2004)] journal August 2004
Ge Layer Transfer To Si For Photovoltaic Applications journal January 2001
Application of hydrogen ion beams to Silicon On Insulator material technology journal February 1996
Semiconductor Wafer Bonding journal August 1998
A “smarter-cut” approach to low temperature silicon layer transfer journal January 1998
Wafer bonding and layer transfer processes for 4-junction high efficiency solar cells conference January 2002
SiGe-on-insulator prepared by wafer bonding and layer transfer for high-performance field-effect transistors journal February 2001
Layer splitting process in hydrogen-implanted Si, Ge, SiC, and diamond substrates journal March 1997
Mechanism of silicon exfoliation induced by hydrogen/helium co-implantation journal December 1998
InGaAs/InP double heterostructures on InP/Si templates fabricated by wafer bonding and hydrogen-induced exfoliation journal December 2003
Smart-Cut® technology: from 300 mm ultrathin SOI production to advanced engineered substrates journal June 2004
Fundamental issues in wafer bonding journal July 1999