Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs

Chen, Zhijie; Hanna, Sylvia L.; Redfern, Louis R.; Alezi, Dalal; Islamoglu, Timur; Farha, Omar K.

doi:10.1016/j.ccr.2019.01.017

Reticular chemistry in the rational synthesis of functional zirconium cluster-based MOFs

Journal Article · Sat Feb 09 23:00:00 EST 2019 · Coordination Chemistry Reviews

DOI:https://doi.org/10.1016/j.ccr.2019.01.017· OSTI ID:1529902

^[1]; Hanna, Sylvia L. ^[2]; Redfern, Louis R. ^[2]; Alezi, Dalal ^[3]; Islamoglu, Timur ^[2]; Farha, Omar K. ^[2]

Northwestern Univ., Evanston, IL (United States); University of Notre Dame
Northwestern Univ., Evanston, IL (United States)
King Abdulaziz Univ., Jeddah (Saudi Arabia)

In the past two decades, reticular chemistry has developed into a powerful tool for the design and synthesis of porous, crystalline framework materials. The discovery of the first hexanuclear, zirconium cluster-based MOF (i.e. UiO-66; fcu net) led to a vast library of functional Zr-MOFs with various properties. The versatile connectivity of zirconium hexanuclear clusters and the adaptable tunability of organic ligands have resulted in the rational synthesis of a large set of Zr-MOFs based on edge-transitive nets; these nets commonly exists in crystalline network structures as suggested by reticular chemistry. In this review, we summarize recent advances in the synthesis of zirconium cluster-based MOFs in the light of reticular chemistry design principles. Isoreticular tuning of MOF parent structures and post-synthetic modification of Zr-MOFs for targeted applications are also deliberated.

View Accepted Manuscript (DOE)

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Energy Frontier Research Center for Inorganometallic Catalyst Design (ICDC); Univ. of Notre Dame, IN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Workforce Development for Teachers and Scientists (WDTS) (SC-27)

Grant/Contract Number:: NA0003763

OSTI ID:: 1529902

Alternate ID(s):: OSTI ID: 1642258

Journal Information:: Coordination Chemistry Reviews, Journal Name: Coordination Chemistry Reviews Journal Issue: C Vol. 386; ISSN 0010-8545

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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