The Phase Diagram and Exotic Magnetostrictive Behaviors in Spinel Oxide Co(Fe1−xAlx)2O4 System

Zhou, Chao; Zhang, Azhen; Chang, Tieyan; Chen, Yusheng; Zhang, Yin; Tian, Fanghua; Zuo, Wenliang; Ren, Yang; Song, Xiaoping; Yang, Sen

doi:10.3390/ma12101685

Title: The Phase Diagram and Exotic Magnetostrictive Behaviors in Spinel Oxide Co(Fe1−xAlx)2O4 System

Journal Article · Thu May 23 00:00:00 EDT 2019 · Materials

DOI:https://doi.org/10.3390/ma12101685· OSTI ID:1529690

Zhou, Chao; Zhang, Azhen; Chang, Tieyan; Chen, Yusheng; Zhang, Yin; Tian, Fanghua; Zuo, Wenliang; Ren, Yang; Song, Xiaoping; Yang, Sen

We report the magnetic and magnetostrictive behaviors of the pseudobinary ferrimagnetic spinel oxide system (1-x)CoFe₂O₄–xCoAl₂O₄ [Co(Fe_1-xAl_x)₂O₄], with one end-member being the ferrimagnetic CoFe₂O₄ and the other end-member being CoAl₂O₄ that is paramagnetic above 9.8 K. The temperature spectra of magnetization and magnetic susceptibility were employed to detect the magnetic transition temperatures and to determine the phase diagram of this system. Composition dependent and temperature dependent magnetostrictive behaviors reveal an exotic phase boundary that separates two ferrimagnetic states: At room temperature and under small magnetic fields (~500 Oe), Fe-rich compositions exhibit negative magnetostriction while the Al-rich compositions exhibit positive magnetostriction though the values are small (<10 ppm). Moreover, the compositions around this phase boundary at room temperature (x = 0.35, 0.4, 0.45, 0.5) exhibit near-zero magnetostriction and enhanced magnetic susceptibility, which may be promising in the applications for magnetic cores, current sensors, or magnetic shielding materials.

View Journal Article

Cite

Export

Save

Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE; National Natural Science Foundation of China (NSFC); Fundamental Research Funds for the Central Universities; National Science Foundation (NSF)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1529690

Alternate ID(s):: OSTI ID: 1558296

Journal Information:: Materials, Journal Name: Materials Vol. 12 Journal Issue: 10; ISSN 1996-1944

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Switzerland

Language:: English

Citation Metrics:

Cited by: 5 works

Citation information provided by
Web of Science

References (23)

Dependence of the magnetic and magnetoelastic properties of cobalt ferrite on processing parameters Nlebedim, I. C.; Snyder, J. E.; Moses, A. J. Journal of Magnetism and Magnetic Materials, Vol. 322, Issue 24 https://doi.org/10.1016/j.jmmm.2010.08.026	journal	December 2010
Effect of temperature variation on the magnetostrictive properties of CoAlxFe2−xO4 Nlebedim, I. C.; Ranvah, N.; Melikhov, Y. Journal of Applied Physics, Vol. 107, Issue 9 https://doi.org/10.1063/1.3357404	journal	May 2010
Magnetic and magnetostrictive properties of aluminium substituted cobalt ferrite synthesized by citrate-gel method Anantharamaiah, P. N.; Joy, P. A. Journal of Materials Science, Vol. 50, Issue 19 https://doi.org/10.1007/s10853-015-9211-x	journal	July 2015
Magnetic and Magnetomechanical Properties of CoAl$_{\rm x}$Fe$_{2 - {\rm x}}$O$_{4}$for Stress Sensor and Actuator Applications Nlebedim, I. C.; Ranvah, N.; Melikhov, Y. IEEE Transactions on Magnetics, Vol. 45, Issue 10 https://doi.org/10.1109/TMAG.2009.2021846	journal	October 2009
X-ray spectroscopic study of cobalt ferrite Vaingankar, A. S.; Khasbardar, B. V.; Patil, R. N. Journal of Physics F: Metal Physics, Vol. 10, Issue 7 https://doi.org/10.1088/0305-4608/10/7/027	journal	July 1980
The crystallographic, magnetic properties of Al, Ti doped CoFe2O4 powders grown by sol–gel method Chae, Kwang Pyo; Lee, Jae-Gwang; Su Kweon, Hyzzuck Journal of Magnetism and Magnetic Materials, Vol. 283, Issue 1 https://doi.org/10.1016/j.jmmm.2004.05.010	journal	November 2004
Auto-ignition synthesis of CoFe2O4 with Al3+ substitution for high frequency applications Toksha, B. G.; Shirsath, Sagar E.; Mane, M. L. Ceramics International, Vol. 43, Issue 16 https://doi.org/10.1016/j.ceramint.2017.07.191	journal	November 2017
Anisotropy and Magnetostriction of Some Ferrites Bozorth, R. M.; Tilden, Elizabeth F.; Williams, Albert J. Physical Review, Vol. 99, Issue 6 https://doi.org/10.1103/PhysRev.99.1788	journal	September 1955
Multiple electrical phase transitions in nanocrystalline aluminium-substituted cobalt ferrite Supriya, Sweety; Kumar, Sunil; Pradhan, Lagen Kumar International Journal of Modern Physics B, Vol. 32, Issue 32 https://doi.org/10.1142/S0217979218503587	journal	December 2018
Effect of Sintering Conditions and Microstructure on the Magnetostrictive Properties of Cobalt Ferrite Bhame, Shekhar D.; Joy, Pattayil A. Journal of the American Ceramic Society, Vol. 91, Issue 6 https://doi.org/10.1111/j.1551-2916.2008.02367.x	journal	June 2008
Influence of manganese substitution on the microstructure and magnetostrictive properties of Co _1−x Mn _x Fe ₂ O ₄ (x = 0.0–0.4) ferrite Atif, M.; Sato Turtelli, R.; Grossinger, R. Journal of Applied Physics, Vol. 113, Issue 15 https://doi.org/10.1063/1.4802435	journal	April 2013
Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides Shannon, R. D. Acta Crystallographica Section A, Vol. 32, Issue 5, p. 751-767 https://doi.org/10.1107/S0567739476001551	journal	September 1976
Inverse effect of morphotropic phase boundary on the magnetostriction of ferromagnetic Tb $_{1 - x}$ Gd $_{x}$ Co $_{2}$ Zhou, Chao; Ren, Shuai; Bao, Huixin Physical Review B, Vol. 89, Issue 10 https://doi.org/10.1103/PhysRevB.89.100101	journal	March 2014
Compensation effect and magnetostriction in CoCr _{2− x} Fe _x O ₄ Zhang, Hong-guo; Wang, Weng-hong; Liu, En-ke physica status solidi (b), Vol. 250, Issue 7 https://doi.org/10.1002/pssb.201248470	journal	November 2012
Effect of size and site preference of trivalent non-magnetic metal ions (Al ³⁺ , Ga ³⁺ , In ³⁺ ) substituted for Fe ³⁺ on the magnetostrictive properties of sintered CoFe ₂ O ₄ Anantharamaiah, P. N.; Joy, P. A. Journal of Physics D: Applied Physics, Vol. 50, Issue 43 https://doi.org/10.1088/1361-6463/aa8af6	journal	October 2017
Radiolytic synthesis of manganese oxides and their ability to decolorize methylene blue in aqueous solutions Mikac, L.; Marić, I.; Štefanić, G. Applied Surface Science, Vol. 476 https://doi.org/10.1016/j.apsusc.2019.01.212	journal	May 2019
Mössbauer studies on Al−Co ferrites Yousif, A. A.; Elzain, M. E.; Sutherland, H. H. Hyperfine Interactions, Vol. 68, Issue 1-4 https://doi.org/10.1007/BF02396501	journal	April 1992
Synthesis and characterization of CoFe2O4 magnetic nanoparticles prepared by temperature-controlled coprecipitation method Kim, Yeong Il; Kim, Don; Lee, Choong Sub Physica B: Condensed Matter, Vol. 337, Issue 1-4 https://doi.org/10.1016/S0921-4526(03)00322-3	journal	September 2003
Temperature Dependence of Magnetic Properties of CoAl$_{\rm x}$Fe$_{2-{\rm x}}$O$_{4}$ Ranvah, N.; Nlebedim, I. C.; Melikhov, Y. IEEE Transactions on Magnetics, Vol. 45, Issue 10 https://doi.org/10.1109/TMAG.2009.2024767	journal	October 2009
Temperature Dependence of Magnetostriction of ${\rm Co}_{1+x}{\rm Ge}_{x}{\rm Fe}_{2-2x}{\rm O}_{4}$ for Magnetostrictive Sensor and Actuator Applications Ranvah, N.; Nlebedim, I. C.; Melikhov, Y. IEEE Transactions on Magnetics, Vol. 44, Issue 11 https://doi.org/10.1109/TMAG.2008.2004535	journal	November 2008
Magnetic and magnetoelastic properties of Ga-substituted cobalt ferrite Song, S. H.; Lo, C. C. H.; Lee, S. J. Journal of Applied Physics, Vol. 101, Issue 9 https://doi.org/10.1063/1.2712941	journal	May 2007
Effect of aluminum substitution on the structural and magnetic properties of cobalt ferrite synthesized by sol–gel auto combustion process Aghav, P. S.; Dhage, Vinod N.; Mane, Maheshkumar L. Physica B: Condensed Matter, Vol. 406, Issue 23 https://doi.org/10.1016/j.physb.2011.08.066	journal	December 2011
X-ray, infrared and magnetic studies of chromium substituted nickel ferrite Ghatage, A. K.; Choudhari, S. C.; Patil, S. A. Journal of Materials Science Letters, Vol. 15, Issue 17 https://doi.org/10.1007/BF00625019	journal	January 1996

Similar Records

Magnetoelectricity in CoFe₂O₄ nanocrystal-P(VDF-HFP) thin films

Journal Article · Tue Sep 03 00:00:00 EDT 2013 · Nanoscale Research Letters (Online) · OSTI ID:1529690

Liu, Xiaohua; Liu, Shuangyi; Han, Myung-Geun; +6 more

Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb_1-xGd_xFe₂ system

Journal Article · Tue Mar 31 00:00:00 EDT 2015 · Applied Physics Letters · OSTI ID:1529690

Adil, Murtaza; Yang, Sen; Mi, Meng; +8 more

Morphotropic phase boundary and magnetoelastic behaviour in ferromagnetic Tb{sub 1−x}Gd{sub x}Fe{sub 2} system

Journal Article · Mon Mar 30 00:00:00 EDT 2015 · Applied Physics Letters · OSTI ID:1529690

Adil, Murtaza; Yang, Sen; Mi, Meng; +8 more

Related Subjects

36 MATERIALS SCIENCE
magnetostriction
phase boundary
phase diagram
spinel oxide

Title: The Phase Diagram and Exotic Magnetostrictive Behaviors in Spinel Oxide Co(Fe1−xAlx)2O4 System

Citation Formats

References (23)

Similar Records

Related Subjects