High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3

Zheng, Hong; Zhang, Junjie; Wang, Bixia; Phelan, Daniel; Krogstad, Matthew J.; Ren, Yang; Phelan, W. Adam; Chmaissem, Omar; Poudel, Bisham; Mitchell, J. F.

doi:10.3390/cryst9070324

Title: High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3

Journal Article · Wed Jun 26 00:00:00 EDT 2019 · Crystals

DOI:https://doi.org/10.3390/cryst9070324· OSTI ID:1529649

Zheng, Hong;

; Wang, Bixia; Phelan, Daniel; Krogstad, Matthew J.; Ren, Yang; Phelan, W. Adam; Chmaissem, Omar; Poudel, Bisham; Mitchell, J. F.

Single crystals of PrNiO₃ were grown under an oxygen pressure of 295 bar using a unique high-pressure optical-image floating zone furnace. The crystals, with volume in excess of 1 mm³, were characterized structurally using single crystal and powder X-ray diffraction. Resistivity, specific heat, and magnetic susceptibility were measured, all of which evidenced an abrupt, first order metal-insulator transition (MIT) at ~130 K, in agreement with previous literature reports on polycrystalline specimens. Temperature-dependent single crystal diffraction was performed to investigate changes through the MIT. Our study demonstrates the opportunity space for high fugacity, reactive environments for single crystal growth specifically of perovskite nickelates but more generally to correlated electron oxides.

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Research Organization:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22). Materials Sciences & Engineering Division; USDOE Office of Science (SC), Basic Energy Sciences (BES). Scientific User Facilities Division

Grant/Contract Number:: AC05-00OR22725; AC02-06CH11357

OSTI ID:: 1529649

Alternate ID(s):: OSTI ID: 1530072

Journal Information:: Crystals, Journal Name: Crystals Vol. 9 Journal Issue: 7; ISSN 2073-4352

Publisher:: MDPI AGCopyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 8 works

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Cited By (21)

Insulating Pockets in Metallic LaNiO ₃ Li, Bing; Louca, Despina; Yano, Shinichiro Advanced Electronic Materials, Vol. 2, Issue 2 https://doi.org/10.1002/aelm.201500261	journal	November 2015
Sur une série de composés oxygènes du nickel trivalent derivés de la perovskite Demazeau, Gérard; Marbeuf, Alain; Pouchard, Michel Journal of Solid State Chemistry, Vol. 3, Issue 4 https://doi.org/10.1016/0022-4596(71)90105-8	journal	November 1971
Pushing boundaries: High pressure, supercritical optical floating zone materials discovery Phelan, W. Adam; Zahn, Jessica; Kennedy, Zachary Journal of Solid State Chemistry, Vol. 270 https://doi.org/10.1016/j.jssc.2018.12.013	journal	February 2019
Magnetic and orbital ordering in NdNiO3 Scagnoli, V.; Staub, U.; Mulders, A. M. Physica B: Condensed Matter, Vol. 378-380 https://doi.org/10.1016/j.physb.2006.01.525	journal	May 2006
High-Pressure Floating-Zone Growth of Perovskite Nickelate LaNiO ₃ Single Crystals Zhang, Junjie; Zheng, Hong; Ren, Yang Crystal Growth & Design, Vol. 17, Issue 5 https://doi.org/10.1021/acs.cgd.7b00205	journal	April 2017
High-Pressure Preparation, Crystal Structure, Magnetic Properties, and Phase Transitions in GdNiO ₃ and DyNiO ₃ Perovskites Alonso, J. A.; Martínez-Lope, M. J.; Casais, M. T. Chemistry of Materials, Vol. 11, Issue 9 https://doi.org/10.1021/cm991033k	journal	September 1999
Metal−Insulator Transitions, Structural and Microstructural Evolution of RNiO ₃ (R = Sm, Eu, Gd, Dy, Ho, Y) Perovskites: Evidence for Room-Temperature Charge Disproportionation in Monoclinic HoNiO ₃ and YNiO ₃ Alonso, José A.; Martínez-Lope, María J.; Casais, María T. Journal of the American Chemical Society, Vol. 121, Issue 20 https://doi.org/10.1021/ja984015x	journal	May 1999
Ground-state oxygen holes and the metal–insulator transition in the negative charge-transfer rare-earth nickelates Bisogni, Valentina; Catalano, Sara; Green, Robert J. Nature Communications, Vol. 7, Issue 1 https://doi.org/10.1038/ncomms13017	journal	October 2016
Atomic-scale control of competing electronic phases in ultrathin LaNiO3 King, P. D. C.; Wei, H. I.; Nie, Y. F. Nature Nanotechnology, Vol. 9, Issue 6 https://doi.org/10.1038/nnano.2014.59	journal	April 2014
Origins of bad-metal conductivity and the insulator–metal transition in the rare-earth nickelates Jaramillo, R.; Ha, Sieu D.; Silevitch, D. M. Nature Physics, Vol. 10, Issue 4 https://doi.org/10.1038/nphys2907	journal	March 2014
Large orbital polarization in a metallic square-planar nickelate Zhang, Junjie; Botana, A. S.; Freeland, J. W. Nature Physics, Vol. 13, Issue 9 https://doi.org/10.1038/nphys4149	journal	June 2017
Antiferromagnetic correlations in the metallic strongly correlated transition metal oxide LaNiO3 Guo, H.; Li, Z. W.; Zhao, L. Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-017-02524-x	journal	January 2018
Experimental evidence for bipolaron condensation as a mechanism for the metal-insulator transition in rare-earth nickelates Shamblin, Jacob; Heres, Maximilian; Zhou, Haidong Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-017-02561-6	journal	January 2018
Gaps and pseudogaps in perovskite rare earth nickelates Allen, S. James; Hauser, Adam J.; Mikheev, Evgeny APL Materials, Vol. 3, Issue 6 https://doi.org/10.1063/1.4907771	journal	June 2015
Progress in perovskite nickelate research Catalan, G. Phase Transitions, Vol. 81, Issue 7-8 https://doi.org/10.1080/01411590801992463	journal	July 2008
Possible ground states of rare-earth nickelates (RNiO ₃ , R = La, Nd, Pr): a mean-field study Misra, Debolina Phase Transitions, Vol. 87, Issue 4 https://doi.org/10.1080/01411594.2013.853767	journal	August 2013
Crystal growth of NdNiO ₃ perovskite under high oxygen pressure Alonso, J. A.; Muñoz, A.; Largeteau, A. Journal of Physics: Condensed Matter, Vol. 16, Issue 14 https://doi.org/10.1088/0953-8984/16/14/040	journal	March 2004
Magnetic and electronic properties of RNiO ₃ (R = Pr, Nd, Eu, Ho and Y) perovskites studied by resonant soft x-ray magnetic powder diffraction Bodenthin, Y.; Staub, U.; Piamonteze, C. Journal of Physics: Condensed Matter, Vol. 23, Issue 3 https://doi.org/10.1088/0953-8984/23/3/036002	journal	January 2011
Structural, magnetic and electronic properties of perovskites (R = rare earth) Medarde, María Luisa Journal of Physics: Condensed Matter, Vol. 9, Issue 8 https://doi.org/10.1088/0953-8984/9/8/003	journal	February 1997
Rare-earth nickelates R NiO ₃ : thin films and heterostructures Catalano, S.; Gibert, M.; Fowlie, J. Reports on Progress in Physics, Vol. 81, Issue 4 https://doi.org/10.1088/1361-6633/aaa37a	journal	February 2018
Oxygen Deficiency and Electrical Conductivity in LnNiO3-z (Ln=La, Pr) and LaCuO3-z. [ＬｎＮｉＯ３−ｚ（Ｌｎ＝Ｌａ，Ｐｒ）及びＬａＣｕＯ３−ｚの酸素欠損と電気伝導] Takeda, Yasuo; Hashimoto, Hiroshi; Sato, Atsushi Journal of the Japan Society of Powder and Powder Metallurgy, Vol. 39, Issue 5 https://doi.org/10.2497/jjspm.39.345	journal	January 1992

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Title: High pO2 Floating Zone Crystal Growth of the Perovskite Nickelate PrNiO3

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